(5aR,10bS)-5a,10b-二氢-2-(2,4,6-三甲基苯基)-4H， 6H-茚并[2,1-b]-1,2,4-三唑并[4,3-d]-1， 4-恶嗪氯化物一水合物

有货

关闭

关闭

货号 (SKU)	包装规格	是否现货	价格	数量
A466993-100mg	100mg	期货
A466993-250mg	250mg	期货

基本描述

英文别名	Bode Catalyst 2
规格或纯度	93%
英文名称	(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate
产品介绍	Description It is anN-mesityl-substituted chiral triazoliumN-heterocyclic carbene (NHC) compound. It was developed as an organocatalyst by the Bode group, for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates.(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as a catalyst:In the preparation of dihydropyridinones by reacting enals or α′-hydroxyenones with vinylogous amides via aza-Claisen annulations.In the oxidative coupling reactions of di(hetero)arylmethanes with enals to yield benzimidazole fused lactams.In the synthesis of organosilanes by reacting enals with β-silyl enones.

IUPAC Name	(1S,9R)-4-(2,4,6-trimethylphenyl)-8-oxa-4,5-diaza-2-azoniatetracyclo[7.7.0.02,6.011,16]hexadeca-2,5,11,13,15-pentaene;chloride;hydrate
INCHI	InChI=1S/C21H22N3O.ClH.H2O/c1-13-8-14(2)20(15(3)9-13)24-12-23-19(22-24)11-25-18-10-16-6-4-5-7-17(16)21(18)23;;/h4-9,12,18,21H,10-11H2,1-3H3;1H;1H2/q+1;;/p-1/t18-,21+;;/m1../s1
InChi Key	DFFDIRURHBNRTR-UITHODHBSA-M
Canonical SMILES	CC1=CC(=C(C(=C1)C)N2C=[N+]3C4C(CC5=CC=CC=C45)OCC3=N2)C.O.[Cl-]
Isomeric SMILES	CC1=CC(=C(C(=C1)C)N2C=[N+]3[C@@H]4[C@@H](CC5=CC=CC=C45)OCC3=N2)C.O.[Cl-]
PubChem CID	54669739
分子量	367.88
Reaxy-Rn	10505362