概述规格名称和识别符技术文档高级数据系统学分类三维结构质检证书（CoA,COO,BSE/TSE 和分析图谱) 化学和物理性质安全和危险性（GHS）此产品的引用文献技术文档和文章引用文献溶液计算器

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为什么选择此级别

提供 ≥98% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。

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储存与运输

室温。。请查阅批次 COA 获取详细规格。

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质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 116 篇同行评审文献引用。

概述

应用

氯化铪 (IV) 能有效地催化羧酸与醇的直接酯化缩合反应。

Application

Hafnium (IV) chloride can be used to catalyze the direct ester condensation of carboxylic acids with alcohols effectively.

规格

英文别名

规格或纯度

≥98%

英文名称

Hafnium(IV) chloride

储存条件

室温

纯度

≥98%

名称和识别符

PubChem SID

528771086

EC号

236-826-5

分子类型

小分子

IUPAC Name

tetrachlorohafnium

INCHI

1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4

InChi Key

PDPJQWYGJJBYLF-UHFFFAOYSA-J

Smiles

Cl[Hf](Cl)(Cl)Cl

Isomeric SMILES

Cl[Hf](Cl)(Cl)Cl

UN Number

3260

分子量

320.30

Reaxy-Rn

3903219

Reaxys-RN link address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3903219&ln=

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

下载 SDS →

✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

查询 COA →

📊 产品数据表

产品规格和应用的快速参考摘要。

查看数据表 →

🔬 规格说明书

该级别的完整质量属性和验收标准。

查看规格说明 →

高级数据

系统学分类

分类树（Taxonomy Tree）

界（kingdom) 无机化合物
- 超类（Superclass) 混合金属/非金属化合物
  - 类（Class) 过渡金属盐
    - 亚类（Subclass）过渡金属氯化物

界（kingdom)	无机化合物
超类（Superclass)	混合金属/非金属化合物
类（Class)	过渡金属盐
亚类（Subclass）	过渡金属氯化物
中间层级节点（Intermediate Tree Nodes）	暂无
直接上位类(Direct Parent)	过渡金属氯化物
其他上位类（Alternative Parents）	无机氯化物盐
分子骨架（Molecular Framework)	暂无
取代基（Substituents）	无机氯化物 - 无机盐 - 铬酸盐
描述（Description）	该化合物属于过渡金属氯化物类无机化合物。此类化合物中最大卤素原子为氯，最重金属原子为过渡金属。
外部描述符（External Descriptors）	暂无

三维结构

交互式化学结构模型

球棍
棍棒
线框模型
空间填充
显示氢气
动画

化学和物理性质

溶解性

H2O：分解（升）

敏感性

对湿度敏感

分子量

320.300 g/mol

XLogP3

氢键供体数Hydrogen Bond Donor Count

氢键受体数Hydrogen Bond Acceptor Count

可旋转键计数Rotatable Bond Count

精确质量Exact Mass

321.819 Da

单同位素质量Monoisotopic Mass

319.822 Da

拓扑极表面积Topological Polar Surface Area

0.000 Å²

重原子数Heavy Atom Count

形式电荷Formal Charge

复杂度Complexity

19.100

同位素原子数Isotope Atom Count

定义的原子立体中心计数Defined Atom Stereocenter Count

未定义的原子立体中心计数Undefined Atom Stereocenter Count

定义的键立体中心计数Defined Bond Stereocenter Count

未定义的键立体中心计数Undefined Bond Stereocenter Count

所有立体化学键的总数The total count of all stereochemical bonds

共价键合单元计数Covalently-Bonded Unit Count

安全和危险性（GHS）

象形图

GHS05, GHS07

信号词

危险

危险声明

H314: 造成严重的皮肤灼伤和眼睛损伤

H317: 可能引起皮肤过敏反应

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P272: 被污染的工作服不允许离开工作场所

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理（请参阅此标签上的...）。

P363: 再次使用之前，请清洗受污染的衣物。

P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。

P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。

P316: 立即寻求紧急医疗救助。

Merck Index

14,4588

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！

找到11个结果

批号(Lot Number)	证书类型	货号
J2326142	分析证书	H431977
J2326143	分析证书	H431977
F2629143	分析证书	H431977
E2619379	分析证书	H431977
E2619381	分析证书	H431977
L2508419	分析证书	H431977
L2508421	分析证书	H431977
I2511450	分析证书	H431977
F2513426	分析证书	H431977
F2513427	分析证书	H431977
L2404085	分析证书	H431977

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技术文档和文章

CVD和ALD前驱体

目录：技术文章

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有机反应工具箱化学气相沉积 CVD CVD前驱体 ALD前驱体氢化物金属卤化物原子层沉积 ALD

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High-Refractive-Index vs Low-Refractive-Index Coating Materials: From AR/Waveguide Principles to a Formulation & Material-Selection Map (Including Product Category Tables A/B/C)

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Refractive index

读懂 ALD 前驱体化学：元素地图、配体分类、典型组合与排错（附共反应物/前驱体清单）

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ALD前驱体 ALD

Understanding ALD Precursor Chemistry: Element Map, Ligand-Based Taxonomy, Typical Pairings, and Troubleshooting (with a Co-Reactant/Precursor List)

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ALD 与 CVD 入门全解：机理、工艺分支、应用场景与选型决策树

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化学气相沉积 CVD 原子层沉积 ALD

ALD and CVD Beginner’s Complete Guide: Mechanisms, Process Branches, Application Scenarios, and a Selection Decision Tree

目录：技术文章

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Chemical vapor deposition CVD ALD Atomic layer deposition

过渡金属盐/前驱体选型导览：同金属不同盐的起点差异与复现要点（含选型导航及产品表1–表5）

目录：技术文章

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过渡金属盐金属盐

Transition-Metal Salts/Precursor Selection Guide: How “Different Salts of the Same Metal” Start from Different Chemical Realities—and How to Reproduce Results (including a Selection Navigator and Product Tables 1–5)

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Self-Assembled Nanodielectrics（SANDs）：面向低电压薄膜晶体管的自组装纳米介电层（附产品选型导航）

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Self-Assembled Nanodielectrics SANDs 低电压薄膜晶体管

Self-Assembled Nanodielectrics (SANDs): Self-Assembled Nanodielectric Layers for Low-Voltage Thin-Film Transistors (with Product Selection Guide)

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CVD and ALD Precursors

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Organic Reaction Toolbox Chemical vapor deposition CVD ALD CVD precursors ALD precursors Metal halides Hydrides Atomic layer deposition

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站? 引用文献检索

引用文献

1. Zixuan Huang, Jinju Zheng, Hui Fu, Jialiang Jiang, Zilong Li, Chunhong Gu, Zhentao Du, Yang Yang, Weiyou Yang, Jialong Zhao. (2023) Bi3+/Sb3+ co-doped Cs2HfCl6 vacancy-ordered double perovskites for multifunctional optoelectronic applications. Journal of Materials Chemistry C, 12 (6): (2053-2062). [10.1039/D3TC04071B]
2. Yali Ma, Haitang Wang, Hailong Wang, Jiani Wang, Shuaiyu Jiang, Qiang Zheng, Songyan Jia, Xue Li, Tianyi Ma. (2023) A stable ultra-microporous hafnium-based metal–organic framework with high performance for CO2 adsorption and separation. CRYSTENGCOMM, 25 (46): (6489-6495). [10.1039/D3CE01022H]
3. Dingxin Liu, Fei Cao, Zhifeng Xu, Chunhua Zhao, Zekun Liu, Jiadong Pang, Ze-Xian Liu, Mahdieh Moghiseh, Anthony Butler, Shaoxia Liang, Weijun Fan, Jiang Yang. (2023) Selective Organ-Targeting Hafnium Oxide Nanoparticles with Multienzyme-Mimetic Activities Attenuate Radiation-Induced Tissue Damage. ADVANCED MATERIALS, [PMID:37777858] [10.1002/adma.202308098]
4. Jiajun Yu, Xiao Wang, Yan Wang, Xiaofeng Xie, Haijiao Xie, Nat Vorayos, Jing Sun. (2023) Heating-induced adsorption promoting the efficient removal of toluene by the metal-organic framework UiO-66 (Zr) under visible light. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:37804616] [10.1016/j.jcis.2023.09.164]
5. Hailing Yang, Ji Zou, Zhimin Xiong, Jingjing Liu, Weimin Wang, Zhengyi Fu. (2023) Thermodynamics aided design of hBN-capsulated diboride powders from novel nitrate precursors for high entropy ceramics. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, [10.1016/j.jmst.2023.08.034]
6. Pengju Chen, Tian Tian, Chenzhuo Zhang, Xian Tang, Zhuan Li. (2023) Effect of Ce-doping on the phase composition and aqueous stability of Gd2Hf2O7 ceramic as nuclear waste forms. CERAMICS INTERNATIONAL, [10.1016/j.ceramint.2023.09.188]
7. Ming Fang, Zhenfei Yang, Yang Guo, Xinnian Xia, Shuaijun Pan. (2023) Piezoelectric effect achieves efficient carriers’ spatial separation and enhanced photocatalytic H2 evolution of UiO-66-NH2@CdS by transforming charge transfer mechanism. SEPARATION AND PURIFICATION TECHNOLOGY, [10.1016/j.seppur.2023.125069]
8. Ni Jing, Shi Zhaoping, Wang Yibo, Yang Jiahao, Wu Hongxiang, Wang Pengbo, Li Kai, Xiao Meiling, Liu Changpeng, Xing Wei. (2023) Suppressing the lattice oxygen diffusion via high-entropy oxide construction towards stabilized acidic water oxidation. Nano Research, [10.1007/s12274-023-5913-6]
9. Jianhong Zheng, Xi Chen, Xiaoxiao Yin, Kai Chen, Aili Liu, Xiaochun Yu, Shun Wang, Zhongwei Chen. (2023) Zr-MOF catalyzed selective oxidation of anilines to azoxybenzenes in aqueous H2O2 solution. Molecular Catalysis, [10.1016/j.mcat.2023.113420]
10. Xian Shi, Xinyi Xing, Mengya Ruan, Qichun Wei, Ying Guan, Hui Gao, Siquan Xu. (2023) Efficient conversion of cellulose into 5-hydroxymethylfurfural by inexpensive SO42-/HfO2 catalyst in a green water-tetrahydrofuran monophasic system. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2023.145001]
11. Wang Junlian, Liu Hui, Xu Wen, Chang Ziyong, Wang Peilong, Wang Huajun. (2023) Selective Extraction of Hafnium over Zirconium with Dialkylphosphinic Acids from H2SO4 Media. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 34 (7): (1003-1012). [10.21577/0103-5053.20230014]
12. Ziqi Ren, Lu Fang, Miao Cui, Tianming Lv, Huifang Wu, Ziyi Feng, Zhaochi Feng, Changgong Meng, Limin Ren. (2023) Acid Treatment for Regulating Hf Sites of the Hierarchical Hf-B-BEA Zeolite, Thereby Boosting Its MPV Reaction Performance. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, [10.1021/acs.iecr.3c01104]
13. Feiyi Chen, Yue Wang, Junhua Zhang, Huai Liu, Lincai Peng. (2023) Construction of HfO2 nanoparticles with rich hydroxyl group for the efficient catalytic transfer hydrogenation of furfural. RENEWABLE ENERGY, [10.1016/j.renene.2023.118916]
14. Zhen Huang, Liangri Ying, Fengchun Gong, Shule Liu, Weilong Wang, Jing Ding. (2023) MOF-derived bimetallic coordination polymer@cobalt-aluminum layered double hydroxide for highly selective CO2 adsorption: Experiments, mechanisms. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:37172488] [10.1016/j.jcis.2023.05.039]
15. Jing Wang, Yakun Teng, Shushu Jia, Wenyan Li, Tianyi Yang, Ya Cheng, Hao Zhang, Xiang Li, Lijuan Li, Ce Wang. (2023) Highly efficient removal of salicylic acid from pharmaceutical wastewater using a flexible composite nanofiber membrane modified with UiO-66(Hf) MOFs. APPLIED SURFACE SCIENCE, [10.1016/j.apsusc.2023.157183]
16. Long Chen, Yixuan Liu, Heng Zhang, Yuncong Li, Songdang Zhang, Yulin Hu, Hu Li, Song Yang. (2023) “Domino” synthesis of bio-derived anethole over facile-prepared hafnium phosphonate frameworks with efficient bifunctional acid sites. Reaction Chemistry & Engineering, 8 (6): (1464-1475). [10.1039/D3RE00096F]
17. Qian Yang, Cuiyan Li, Haibo Ouyang, Ruinan Gao, Tianzhan Shen, Jianfeng Huang. (2023) Dual-Porosity (Ta0.2Nb0.2Ti0.2Zr0.2Hf0.2)C High-Entropy Ceramics with High Compressive Strength and Low Thermal Conductivity Prepared by Pressureless Sintering. Materials, 16 (6): (2495). [PMID:36984375] [10.3390/ma16062495]
18. Yao Yang, Jianqiang Bi, Xicheng Gao, Kangning Sun, Linjing Qiao, Guandong Liang, Hongyi Wang. (2023) Facile synthesis of nanocrystalline high-entropy diboride powders by a simple sol-gel method and their performance in supercapacitor. CERAMICS INTERNATIONAL, [10.1016/j.ceramint.2023.02.170]
19. Xinquan Zhou, Kai Han, Yexin Wang, Jiance Jin, Shangda Jiang, Qinyuan Zhang, Zhiguo Xia. (2023) Energy-Trapping Management in X-Ray Storage Phosphors for Flexible 3D Imaging. ADVANCED MATERIALS, 35 (16): (2212022). [PMID:36807928] [10.1002/adma.202212022]
20. Bin Du, Xingming Huang, Anzhe Wang, Yiran Liu, Yuan Cheng. (2023) Structure evolutions of the polymer derived medium-/high-entropy metal carbides. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2023.168737]
21. Yuncong Li, Kaixun Zhu, Yiyuan Jiang, Long Chen, Heng Zhang, Hu Li, Song Yang. (2022) Biomass-derived hydrophobic metal-organic frameworks solid acid for green efficient catalytic esterification of oleic acid at low temperatures. FUEL PROCESSING TECHNOLOGY, [10.1016/j.fuproc.2022.107558]
22. Xinyi Xing, Xian Shi, Rui Hu, Ying Guan, Hui Gao, Siquan Xu. (2022) Hf-β zeolites as highly efficient catalysts for the production of 5-hydroxymethylfurfural from cellulose in biphasic system. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, [PMID:36244534] [10.1016/j.ijbiomac.2022.10.076]
23. Zhu Peide, Zhao Xuelin, Zhang Yuqi, Liu Yinping, Zhao Ziyi, Yang Ziji, Liu Xinzhu, Zhang Weiye, Guo Zixuan, Wang Xiao, Niu Yingchun, Xu Meng. (2022) Mn3+/Mn4+ ion-doped carbon dots as fenton-like catalysts for fluorescence dual-signal detection of dopamine. Frontiers in Bioengineering and Biotechnology, [PMID:36159685] [10.3389/fbioe.2022.964814]
24. Wang Junlian, Liu Hui, Zhao Hongru, Wang Huajun. (2022) Selective extraction of Hf over Zr by a novel extractant (n-octyl)(2,4,4′-trimethylpentyl)phosphinic acid (INET-1) from sulfuric acid media. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 332 (7): (2473-2485). [10.1007/s10967-022-08463-2]
25. Chunlei Zhang, Guangyu Chu, Zesong Ruan, Ning Tang, Cunfeng Song, Qichao Li, Wenjie Zhou, Jiale Jin, Hossam Haick, Yunfeng Chen, Daxiang Cui. (2022) Biomimetic Self-Assembling Metal–Organic Architectures with Non-Iridescent Structural Coloration for Synergetic Antibacterial and Osteogenic Activity of Implants. ACS Nano, [PMID:36001338] [10.1021/acsnano.2c06030]
26. Yingjian Ma, Jing Mao, Haojie Qin, Pan Liang, Wenpeng Huang, Chenchen Liu, Jianbo Gao. (2022) Nano-Metal–Organic Framework Decorated With Pt Nanoparticles as an Efficient Theranostic Nanoprobe for CT/MRI/PAI Imaging-Guided Radio-Photothermal Synergistic Cancer Therapy. Frontiers in Bioengineering and Biotechnology, [PMID:35875484] [10.3389/fbioe.2022.927461]
27. Yanan Sun, Li Ye, Yongqing Zhang, Fenghua Chen, Weijian Han, Wenfeng Qiu, Tong Zhao. (2022) Synthesis of high entropy carbide ceramics via polymer precursor route. CERAMICS INTERNATIONAL, [10.1016/j.ceramint.2022.02.135]
28. Wei Li, Yanan Sun, Li Ye, Weijian Han, Fenghua Chen, Jianling Zhang, Tong Zhao. (2022) Preparation of high entropy nitride ceramic nanofibers from liquid precursor for CO2 photocatalytic reduction. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 105 (6): (3729-3734). [10.1111/jace.18384]
29. Siping Liu, Bin Yang, Junsheng Chen, Daoyuan Zheng, Zhe Tang, Weiqiao Deng, Keli Han. (2021) Colloidal Synthesis and Tunable Multicolor Emission of Vacancy-Ordered Cs2HfCl6 Perovskite Nanocrystals. Laser & Photonics Reviews, 16 (2): (2100439). [10.1002/lpor.202100439]
30. Le Fu, Fuqing Jiang, Bo Li, Yongxin Cheng, Guofu Xu, Jiwu Huang, Håkan Engqvist, Wei Xia. (2021) Doping of tantalum, niobium, and hafnium in a translucent ZrO2-SiO2 nanocrystalline glass-ceramic. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, [10.1016/j.jeurceramsoc.2021.12.019]
31. Guo Qiu, Biaohua Chen, Ning Liu, Chongpin Huang. (2021) Hafnium-tin composite oxides as effective synergistic catalysts for the conversion of glucose into 5-hydroxymethylfurfural. FUEL, [10.1016/j.fuel.2021.122628]
32. Ruxin Liu, Jing Yang, Di Zhao, Wenjing Liu, Guojing Li, Wenbo Yan, Wenjun Zhang. (2021) Efficient Broadband Yellow-Green Emission of Vacancy Halide Double Perovskites Through the Ion-Exchanged Strategy. INORGANIC CHEMISTRY, [PMID:34784481] [10.1021/acs.inorgchem.1c02473]
33. Lyu Yang, Du Baihe, Chen Guiqing, Zhao Guangdong, Cheng Yuan, Zhou Shanbao, Lv Qingrong, Zhang Xinghong, Han Wenbo. (2021) Microstructural regulation, oxidation resistance, and mechanical properties of Cf/SiC/SiHfBOC composites prepared by chemical vapor infiltration with precursor infiltration pyrolysis. Journal of Advanced Ceramics, 11 (1): (120-135). [10.1007/s40145-021-0521-y]
34. Zhi Dong, Zongqing Ma, Yongchang Liu. (2021) Accelerated sintering of high-performance oxide dispersion strengthened alloy at low temperature. ACTA MATERIALIA, [10.1016/j.actamat.2021.117309]
35. Na Wang, Siyang Liu, Zhongqiao Sun, Yide Han, Junli Xu, Yan Xu, Junbiao Wu, Hao Meng, Bingsen Zhang, Xia Zhang. (2021) Synergistic adsorption and photocatalytic degradation of persist synthetic dyes by capsule-like porphyrin-based MOFs. NANOTECHNOLOGY, 32 (46): (465705). [PMID:34284373] [10.1088/1361-6528/ac162e]
36. Rulu Huang, Yao Liu, Junhua Zhang, Junnan Wei, Lincai Peng, Xing Tang. (2021) Catalytic transfer hydrogenation of levulinic acid to γ-valerolactone over an acids-base trifunctional Hf-bagasse coordination complex derived catalyst. FUEL, [10.1016/j.fuel.2021.121557]
37. Ruxin Liu, Wenjun Zhang, Wenjing Liu, Guojing Li. (2021) Synthesis of a Bi3+-Doped Cs2HfCl6 Double Perovskite with Highly Efficient Blue Light Emission at Room Temperature. INORGANIC CHEMISTRY, [PMID:34176258] [10.1021/acs.inorgchem.1c01054]
38. Miao Zhang, Yongqiao Zhu, Dawei Li, Peizhong Feng, Cheng Xu. (2021) An innovative method for preparation of sol–gel HfO2 films with high laser-induced damage threshold after high-temperature annealing. APPLIED SURFACE SCIENCE, [10.1016/j.apsusc.2021.149615]
39. Yue Zhang, Lin Liu, Wei-Guo Xu, Zheng-Bo Han. (2021) MOF@POP core–shell architecture as synergetic catalyst for high-efficient CO2 fixation without cocatalyst under mild conditions. Journal of CO2 Utilization, [10.1016/j.jcou.2021.101463]
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