JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
·
2016
·Vol. 310
·期 2
·547-557
·
IF 0.983
Zhang Zhi-bin,Qiu Yan-fang,Dai Ying,Wang Pan-feng,Gao Bao,Dong Zhi-ming,Cao Xiao-hong,Liu Yun-hai,Le Zhang-gao
In this article, we report a facile one-pot method to prepare sulfonated graphene oxide (GOS) via vapor–solid transfer reaction of graphene oxide (GO). The synthesized GOS were characterized and investigated as an adsorbent for the adsorption of U(VI) from aqueous solutions. The results indicated that the adsorption of U(VI) was strongly dependent on pH and independent of ionic strength. The adsorption process followed the pseudo-second-order kinetics and the adsorption isotherm agreed well with the Langmuir model, having a maximum adsorption capacity of 309.09 mg g −1 . Thermodynamic parameters indicated that the adsorption reaction was an endothermic and spontaneous process.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2016
·Vol. 51
·期 17
·7966-7976
·
IF 2.302
Zhang Jiawei,Zhang Guoping,Gao Yongju,Sun Rong,Wong C. P.
A novel bridged organosilane precursor with star-shaped construction, [hexfluoropropane-2,2-diyl)dibenzyl-bridged organosilane (HFPDBO)], is prepared by facile organic synthesis method. The resultant HFPDBO precursor is mixed with porogen and acid catalyst to prepare periodic mesoporous organosilica (PMO) thin film via evaporation-induced self-assembly after spin-coating procedure. All the as-prepared HFPDB-based PMO thin film has been characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectrum, scanning electron microscopy,
transmission electron microscope, and small-angle X-ray diffraction, respectively. Thereinto, the HFPDB-based PMO thin film with weight ratio of porogen to precursor (0.75:1) possesses excellent dielectric property (1.58@1 MHz of dielectric constants), high mechanical property (5.54 ± 0.11 GPa of Young’s modulus) and hydrophobic property (90.1° of water contact angle) simultaneously. These low dielectric constant, high mechanical strength, and the hydrophobicity suggest potential application of the HFPDB-based PMO thin films as low-k materials in microelectronics.
✓ 已验证
产品关联
DOI
高影响因子
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
·
2016
·Vol. 408
·期 19
·5319-5328
·
IF 3.125
Ji Wenhua,Zhang Mingming,Gao Qianshan,Cui Li,Chen Lizong,Wang Xiao
Hydrophilic molecularly imprinted polymers (H-MIP) with molecular recognition ability for iridoid glycosides (IGs) have been obtained via bulk polymerization combined with hydrolysis of ester groups. H-MIP were characterized by Fourier transform infrared spectroscopy (FT-IR). The hydrophilcity was measured by the contact angle measurement and the water dispersion stability. The obtained H-MIP demonstrated high selectivity and specific binding ability to five IGs in aqueous media. The group extraction efficiency of molecular imprinted solid-phase extraction (MISPE) for five IGs was investigated, including loading sample, breakthrough volume, washing solvent, and elution solvent. Compared with non-imprinted solid-phase extraction (NISPE), the higher average recovery (95.5 %) of five IGs with lower relative standard deviations values (below 6.1 %) using MISPE combined with high-performance liquid chromatography (HPLC) were achieved at three spiked levels in three blank samples. Under the optimum MISPE conditions, the wide linear range with the correlation coefficient of R
2 ≥ 0.9950 for five IGs with low limits of detection (LOD) and quantification (LOQ) (0.01–0.08 and 0.03–0.27 μg mL −1 , respectively) were obtained. Chromatograms obtained using MISPE columns demonstrated that the matrix interference has been minimized and great interferences around IGs were also eliminated efficiently. These results indicated that the developed MISPE-HPLC method was selective, accurate, and applicable for the determination of IGs in water media.
Preparation of hydrophilic molecularly imprinted polymers via bulk polymerization combined with hydrolysis of ester groups
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF NANOPARTICLE RESEARCH
·
2016
·Vol. 18
·期 5
·1-9
·
IF 2.101
Chen Jiucun,Li Junzhi,Liu Jianhua,Weng Bo,Xu Liqun
Abstract A novel well-defined four-armed star poly(ethylene brassylate)- b -poly(poly(ethylene glycol)methyl ether methacrylate) (s-PEB- b -P(PEGMA)) was synthesized and self-assembled via the combination of ring-opening polymerization and reversible addition-fragmentation chain transfer polymerization (RAFT) in this work. It proceeded firstly with the synthesis of hydrophobic four-armed star homopolymer of ethylene brassylate (EB) via ROP with organic catalyst, followed by the esterification reaction of s-PEB with chain transfer agent. Afterward, RAFT polymerization of PEGMA monomer was initialed using PEB-based macro-RAFT agent, resulting in the target amphiphilic four-armed star copolymer. The obtained s-PEB- b -P(PEGMA) can assemble into micelles with PEB segments as core and P(PEGMA) segments as shell in aqueous solution. The self-assembly behavior was studied by dynamic light scattering and transmission electron microscope. The micelles of s-PEB- b -P(PEGMA) exhibited higher loading capacity of the anticancer drug doxorubicin (DOX). The investigation of DOX release from the micelles demonstrated that the release rate of the hydrophobic drug could be effectively controlled. Graphical Abstract
✓ 已验证
产品关联
DOI
高影响因子
NEUROCHEMICAL RESEARCH
·
2016
·Vol. 41
·期 9
·2311-2323
·
IF 2.472
Liu Jie,Su Hua,Qu Qiu-Min
Beta-amyloid (Aβ), the hallmark protein in Alzheimer’s disease (AD), induces neurotoxicity that involves oxidative stress and mitochondrial dysfunction, leading to cell death. Carnosic acid (CA), a polyphenolic diterpene isolated from the herb rosemary ( Rosemarinus officinalis ), was investigated in our study to assess its neuroprotective effect and underlying mechanism against Aβ-induced injury in human neuroblastoma SH-SY5Y cells. We found that CA pretreatment alleviated the Aβ 25–35 -induced loss of cell viability, inhibited both Aβ 1–42 accumulation and tau hyperphosphorylation, reduced reactive oxygen species generation, and maintained the mitochondrial membrane potential. Moreover, CA increased the microtubule-associated protein light chain 3 (LC3)-II/I ratio and decreased SQSTM1(p62), indicating that CA could induce autophagy. Autophagy inhibitor 3-methyladenine (3-MA) attenuated the neuroprotective effect of CA, suggesting that autophagy was involved in the neuroprotection of CA. It was also observed that CA activated AMP-activated protein kinase (AMPK) but inhibited mammalian target of rapamycin (mTOR). Furthermore, blocking AMPK with si-AMPKα successfully inhibited the upregulation of LC3-II/I, prevented the downregulation of phosphorylation of mTOR and SQSTM1(p62), indicating that CA induced autophagy in SH-SY5Y cells via the activation of AMPK. These results suggested that CA might be a potential agent for preventing AD.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
MICROCHIMICA ACTA
·
2017
·Vol. 184
·期 12
·4679-4684
·
IF 4.58
Zhu Shu,Lin Xia,Ran Peiyao,Mo Fangjing,Xia Qiao,Fu Yingzi
This paper describes an electrochemiluminescent (ECL) based method for chiral recognition and detection of both glutamate (Glu) enantiomers. The luminophore luminol (Lum) was used as both the reductant and stabilizer of Ag nanoparticles (AgNP-Lum) which were combined with carbon quantum dots (C-dots) and placed on a glassy carbon electrode (GCE) along with the enzyme glutamate oxidase (GluOx). The use of these materials is found to result in strong amplification of ECL. The nanomaterials used were characterized by transmission electron microscopy (TEM) and Fourier transform infrared (FTIR). The stepwise fabrication of the electrode was verified by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Under optimized conditions and by applying a typical potential of 0.6 V, the ECL increases linearly in the 5.0 μM to 5.0 mM Glu concentration range, with a 1.6 μM lower detection limit and satisfactory selectivity. A Glu logic gate idea has been designed that is based on this enzymatic biosensor.
Schematic presentation of the electrochemiluminescent (ECL) biosensor. A glassy carbon electrode (GCE) was modified with C-dots and silver nanoparticles which were deoxidized by luminol (AgNP-Lum) for enzymatic specific detection.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2017
·Vol. 28
·期 23
·17772-17777
·
IF 2.019
Li Jiajia,Han Xiuxun,Zhao Yun,Li Jian,Wang Min,Dong Chen,Hao Zhaomin
A novel Cu 3 BiS 3 nanorods film was prepared by a facile dip-coating method and its compositional, structural and optoelectronic properties were systematically characterized. A possible reaction mechanism of Cu 3 BiS 3 was also discussed briefly. Optical absorption investigation revealed that Cu 3 BiS 3 nanorods film has a direct band gap of 1.46 eV. Photoelectrochemistry of hydrazine free unannealed film displays a strong p-type photoresponse, as high as ∼1.0 × 10 −4 A/cm −2 at an applied potential of −0.5 V versus Ag/AgCl under the visible light irradiation. The photocurrent response measurement on the Cu 3 BiS 3 nanorods film sheds light on the potential application as a low-cost, high-reproducibility and high-yield nanorods preparing approach towards efficient Cu 3 BiS 3 photoelectricity and photovoltaic materials.
✓ 已验证
产品关联
DOI
高影响因子
CHINESE JOURNAL OF POLYMER SCIENCE
·
2017
·Vol. 35
·期 12
·1463-1473
·
IF 1.692
Yang Zhen,Li Ning,Yang Xiao-xue,Zhang Xiao-a,Jiang Sheng-ling,Lyu Ya-fei
o -Carborane-containing poly(hydroxy ethers) ( P1 , P2 and P3 ) were synthesized via “advancement reaction” of o -carborane-containing bisphenol ( 4 ) and diglycidyl ether of bisphenols (DGEBA and 1 ). FTIR and 1 H-, 13 C-, and 11 B-NMR were utilized to characterize the obtained polymers. TGA test was conducted under nitrogen and air. It is found that the shielding effect of carborane moiety on its adjacent aromatic structures contributes to high initial decomposition temperatures, while oxygen in air has an adverse effect on the initial decomposition temperature. The oxygen can combine with polymer chain to form peroxide and hydroperoxide groups, which are more reactive during the degradation process. Besides, o -carborane-containing poly(hydroxy ethers) have high char yield at elevated temperatures. The boron atom combines with oxygen from the polymer structure or/and from air, thus to form a three-dimensional network linked with B—O—B and B—C bonds, and retain the polymer weight to a large extent.
✓ 已验证
产品关联
DOI
高影响因子
Frontiers of Materials Science
·
2017
·Vol. 11
·期 3
·223-232
·
IF 1.471
Wei Lulu,Lu Beibei,Li Lei,Wu Jianning,Liu Zhiyong,Guo Xuhong
A novel β-cyclodextrin-poly(2-(2-methoxyethoxy)ethyl methacrylate)- co -poly(ethylene glycol) methacrylate (abbreviated as: β-CD-(P(MEO 2 MA- co -PEGMA)) 21 ) was prepared by using the one-step strategy, and then the star-shaped copolymers were used in the atom transfer radical polymerization (ATRP). The structure of star-shaped β-CD-(P(MEO 2 MA- co -PEGMA)) 21 copolymers were studied by FTIR, 1 H NMR and gel permeation chromatography (GPC). The star-shaped copolymers could self-assembled into micelles in aqueous solution owing to the outer amphiphilic β-CD as a core and the hydrophilic P(MEO 2 MA- co -PEGMA) segments as a shell. These thermo-responsive starshaped copolymers micelles exhibited lower critical solution temperature (LCST) in water, which could be finely tuned by changing the feed ratio of MEO 2 MA to PEGMA. The LCST of star-shaped β-CD-(P(MEO 2 MA- co -PEGMA)) 21 copolymer micelles were increased from 35°C to 58°C with the increasing content of PEGMA. The results were investigated by DLS and TEM. When the temperature was higher than corresponding LCSTs, the micelles started to associate and form spherical nanoparticles. Therefore, β-CD-(P(MEO 2 MA- co -PEGMA)) 21 star-shaped copolymer micelles could be potentially applied in nano-carrier, nano-reactor, smart materials and biomedical fields.
✓ 已验证
产品关联
DOI
高影响因子
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
·
2017
·Vol. 123
·期 9
·1-9
·
IF 1.455
Leng Yumin,He Junbao,Li Bo,Xing Xiaojing,Guo Yongming,Ye Liqun,Lu Zhiwen
The different sized and shaped Au NPs have intrigued considerable attention, because they possess different surface plasma resonance (SPR) absorption bands and thus result in many colorimetric Au NP-based detection applications. In this article, four different sized and shaped Au NPs of nanodots/rods were prepared and characterized. The as-prepared Au NPs were modified by the negatively charged anions of [SCH 2 CO 2 ] 2− to investigate both the size and shape effects of modified Au NPs on colorimetric detection of Co 2+ and the corresponding SPR absorption properties. The different-shaped Au NPs possess different SPR absorption properties. The Au nanorods appeared to be colorimetric sensitive for Co 2+ sensing.
✓ 已验证
产品关联
DOI
高影响因子
MICROCHIMICA ACTA
·
2017
·Vol. 184
·期 11
·4359-4365
·
IF 4.58
Zhou Yunlei,Li Bingchen,Wang Minghui,Wang Jun,Yin Huanshun,Ai Shiyun
The authors describe a fluorometric assay for microRNA. It is based on two-step amplification involving (a) strand displacement replication and (b) rolling circle amplification. The strand displacement amplification system is making use of template DNA (containing a sequence that is complementary to microRNA-21) and nicking enzyme sites. After hybridization, the microRNA strand becomes extended by DNA polymerase chain reaction and then cleaved by the nicking enzyme. The DNA thus produced acts as a primer in rolling circle amplification. Then, the DNA probe SYBR Green II is added to bind to ssDNA to generate a fluorescent signal which increases with increasing concentration of microRNA. The method has a wide detection range that covers the10 f. to 0.1 nM microRNA concentration range and has a detection limit as low as 1.0 fM. The method was successfully applied to the determination of microRNA-21 in the serum of healthy and breast cancer patients.
Schematic of a fluorometric microRNA assay based on two-step amplification involving strand displacement replication and rolling circle amplification. DNA probe SYBR Green II is then bound to ssDNA to generate a fluorescent signal which increases with increasing concentration of microRNA.
✓ 已验证
产品关联
DOI
高影响因子
Scientific Reports
·
2017
·Vol. 7
·期 1
·1-8
·
IF 4.259
Su Yanbin,Ma Xiaowei,Su Yanwen,Mu Tongxing,Li Yanhe,Jiang Ning,Su Yuyun,Zhang Qi
Inappropriate use of ethanol (EtOH) had led to noticeable health problems, but a beneficial phenomenon was found that EtOH displayed unique influences for toxic trans-crotonaldehyde (TCA) derived from mitochondrial lipid peroxidation. The influences of EtOH on the structure of TCA were systematically probed by UV-vis & Raman spectroscopy in the absence and presence of mitochondria, respectively. The maximum UV-vis peak at 301 nm of TCA was red shifted by hydroxyl (-OH) and methyl (-CH 3 ) of EtOH, respectively. Raman stretching band of aldehyde (-CH=O) of TCA (TCA-CH=O) was split by the -CH 3 of EtOH. The -CH 3 increased TCA-CH=O stretching frequency while the -OH induced it. The more exposed -OH, the less stretching frequency. The ectopic -CH 3 red shifted the UV-vis peak at 301 nm and Raman band of TCA-CH=O. In mitochondria, EtOH red shifted Raman stretching band of TCA-CH=O. Raman stretching bands of C-H, C-O and C-C of EtOH were red shifted, while Raman stretching bands of -CH 2 and C-C-O of EtOH disappeared. The paper unearths the influences of EtOH to trap and transform the structure of TCA-CH=O. This discovery has an important contribution to eliminate TCA in order to protect and repair mtDNA by means of the decrease of 8-oxoG.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）