| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| M106900-25g |
25g |
现货  |
| |
| M106900-100g |
100g |
现货 |
| |
| M106900-500g |
500g |
现货 |
|
| 别名 | 溴乙酸甲酯 | 2-溴乙酸甲酯 |
|---|---|
| 英文别名 | 2-bromoacetic acid methyl ester | 2-bromo-acetic acid methyl ester | AKOS009158462 | BCP06456 | BrCH2COOCH3 | FT-0628707 | methylbromo-acetate | UN 2643 | Methyl bromoacetate | methyl -bromoacetate | methyl bromo-acetate | F2190-0277 | monobromo acetic ac |
| 规格或纯度 | ≥97% |
| 英文名称 | Methyl bromoacetate |
| 应用 | Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
溶于甲醇、乙醚、丙酮和苯，实际上不溶于水。 Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes |
| PubChem SID | 488183414 |
|---|---|
| EC号 | 202-499-2 |
| IUPAC Name | methyl 2-bromoacetate |
| INCHI | InChI=1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3 |
| InChi Key | YDCHPLOFQATIDS-UHFFFAOYSA-N |
| Canonical SMILES | COC(=O)CBr |
| Isomeric SMILES | COC(=O)CBr |
| WGK Germany | 3 |
| RTECS | AF6300000 |
| UN Number | 2643 |
| Packing Group | II |
| 分子量 | 152.97 |
| Beilstein号 | 506256 |
| Reaxy-Rn | 506256 |
| Reaxys-RN link address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=506256&ln= |
| 溶解性 | Soluble in water (very slightly), methanol, ether, and acetone |
|---|---|
| 密度 | 1.66 |
| 敏感性 | 对光&空气敏感 |
| 折光率 | 1.458 |
| 闪点(℉) | 147.2 °F |
| 闪点(℃) | 62℃ |
| 沸点 | 51-52°C |
| 分子量 | 152.970 g/mol |
| XLogP3 | 0.900 |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 2 |
| 可旋转键计数Rotatable Bond Count | 2 |
| 精确质量Exact Mass | 151.947 Da |
| 单同位素质量Monoisotopic Mass | 151.947 Da |
| 拓扑极表面积Topological Polar Surface Area | 26.300 Ų |
| 重原子数Heavy Atom Count | 6 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 52.800 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 1 |
| 一般危化品 | 一般危化品 |
|---|---|
| 象形图 | GHS06, GHS05, GHS07 |
| 信号词 | Danger |
| 危险声明 |
H335: 可能引起呼吸道刺激 H301: 吞咽会中毒 H311: 皮肤接触有毒 H331: 吸入会中毒 H314: 造成严重的皮肤灼伤和眼睛损伤 H317: 可能引起皮肤过敏反应 |
| 预防措施声明 |
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P272: 被污染的工作服不允许离开工作场所 P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P330: 漱口 P361+P364: 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P301+P316: 如果吞咽：立即寻求紧急医疗救助。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。 P319: 如果你感到不适，请寻求医疗帮助。 |
| WGK Germany | 3 |
| RTECS | AF6300000 |
| Reaxy-Rn | 506256 |
| Reaxys-RN link address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=506256&ln= |
| Class | 6.1 |
| 个人防护装备 | Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter |
| Density (20°C) | 1.651-1.664 |
|---|---|
| Purity(GC) | 97-100（%） |
| Refractive index n20/D | 1.455-1.459 |
| Appearance（M106900) | Colorless to pale brown liquid |
| Proton NMR spectrum | Conforms to Structure |
通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！
| 批号(Lot Number) | 证书类型 | 日期 | 货号 |
|---|---|---|---|
 J2314066 |
分析证书 | 25-07-21 | M106900 |
| I2322123 |
分析证书 | 25-06-10 | M106900 |
| C2526072 |
分析证书 | 25-03-28 | M106900 |
| B2515027 |
分析证书 | 25-02-19 | M106900 |
| B2307056 |
分析证书 | 24-11-15 | M106900 |
| B2307063 |
分析证书 | 24-11-15 | M106900 |
| J2227410 |
分析证书 | 24-08-22 | M106900 |
| J2227466 |
分析证书 | 24-08-22 | M106900 |
| D2509608 |
分析证书 | 24-07-05 | M106900 |
| D2509621 |
分析证书 | 24-07-05 | M106900 |
| I2202171 |
分析证书 | 24-06-25 | M106900 |
| A2207910 |
分析证书 | 23-10-11 | M106900 |
| J2314065 |
分析证书 | 23-09-26 | M106900 |
| H2104239 |
分析证书 | 23-05-10 | M106900 |
| H2104241 |
分析证书 | 23-05-10 | M106900 |
| H2104242 |
分析证书 | 23-05-10 | M106900 |
| J2228632 |
分析证书 | 22-10-13 | M106900 |
| K2020216 |
分析证书 | 22-09-16 | M106900 |
| J2227413 |
分析证书 | 22-09-16 | M106900 |
¥12,571.90
¥340.90
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| 2. Kaibo Pan, Zhicheng Zhu, Chongming Liu, Songyuan Tao, Xiaoduo Tang, Xiaoyu Wei, Bai Yang. (2023) Flexible Transparent Hydrophobic Coating Films with Excellent Scratch Resistance Using Si-Doped Carbonized Polymer Dots as Building Blocks. ACS Applied Materials & Interfaces, 15 (21): (26060–26068). [PMID:37209113] [10.1021/acsami.3c05078] |
| 3. Yunlong Yang, Yuanlong Guo, Chengtao Gao, Michael North, Jili Yuan, Haibo Xie, Qiang Zheng. (2023) Fabrication of Carboxylic Acid and Imidazolium Ionic Liquid Functionalized Porous Cellulosic Materials for the Efficient Conversion of Carbon Dioxide into Cyclic Carbonates. ACS Sustainable Chemistry & Engineering, 11 (6): (2634–2646). [10.1021/acssuschemeng.2c06976] |
| 4. Sheng Zhan, Yuwei Duan, Zhike Liu, Lu Yang, Kun He, Yuhang Che, Wenjing Zhao, Yu Han, Shaomin Yang, Guangtao Zhao, Ningyi Yuan, Jianning Ding, Shengzhong (Frank) Liu. (2022) Stable 24.29%-Efficiency FA0.85MA0.15PbI3 Perovskite Solar Cells Enabled by Methyl Haloacetate-Lead Dimer Complex. Advanced Energy Materials, 12 (27): (2200867). [10.1002/aenm.202200867] |
| 5. Yao Jian, Gui Lun, Yin Shaocheng. (2021) A novel esterase from a soil metagenomic library displaying a broad substrate range. AMB Express, 11 (1): (1-10). [PMID:33666762] [10.1186/s13568-021-01198-5] |
| 6. Guangbin Ji, Fei Yang, Yanzhao Yang, Jingjing Wei, Zhijie Yang. (2021) Dynamic emulsion droplets enabled by interfacial assembly of azobenzene-functionalized nanoparticles under light and magnetic field. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 583 (586). [PMID:33038608] [10.1016/j.jcis.2020.09.058] |
| 7. Saisai Yan, Zhinong Gao, Jia Han, Zhengqin Zhang, Fei Niu, Yingfang Zhang. (2019) Controllable fabrication of stimuli-responsive fluorescent silica nanoparticles using a tetraphenylethene-functionalized carboxylate gemini surfactant. Journal of Materials Chemistry C, 7 (40): (12588-12600). [10.1039/C9TC03732B] |
| 8. Siming Yu, Rong Wen, Haiyang Wang, Yongchao Zha, Lin Qiu, Bo Li, Wei Xue, Dong Ma. (2019) Chitosan-graft-Poly(l-lysine) Dendron-Assisted Facile Self-Assembly of Au Nanoclusters for Enhanced X-ray Computer Tomography Imaging and Precise MMP-9 Plasmid shRNA Delivery. CHEMISTRY OF MATERIALS, 31 (11): (3992–4007). [10.1021/acs.chemmater.9b00507] |
| 9. Guowei Li, Siming Yu, Wei Xue, Dong Ma, Wu Zhang. (2018) Chitosan-graft-PAMAM loading nitric oxide for efficient antibacterial application. CHEMICAL ENGINEERING JOURNAL, 347 (923). [10.1016/j.cej.2018.04.159] |
| 10. Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing. (2015) Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids. CHINESE JOURNAL OF CATALYSIS, 36 (408). [10.1016/S1872-2067(14)60227-8] |
| 1. Yasameen K Al-Majedy, Abdul Amir H Kadhum, Ahmed A Al-Amiery, Abu Bakar Mohamad,. (2014-08-12) Synthesis and characterization of some new 4-hydroxy-coumarin derivatives.. Molecules (Basel, Switzerland), 19 ((8)): ( 11791-11799 ). [PMID:25105917] |
| 2. Chaoji Xiong, Hao Wang, Lihua Deng, Kun Liang, Chunhua Wu, Wei Wu, Qian Chen. (2024) Novel triazine-based sulfur-containing polyamides: Preparation, adsorption efficiency and mechanism for mercury ions. EUROPEAN POLYMER JOURNAL, 202 (16): (112588). [PMID:27481942] [10.1016/j.eurpolymj.2023.112588] |
| 3. Kaibo Pan, Zhicheng Zhu, Chongming Liu, Songyuan Tao, Xiaoduo Tang, Xiaoyu Wei, Bai Yang. (2023) Flexible Transparent Hydrophobic Coating Films with Excellent Scratch Resistance Using Si-Doped Carbonized Polymer Dots as Building Blocks. ACS Applied Materials & Interfaces, 15 (21): (26060–26068). [PMID:37209113] [10.1021/acsami.3c05078] |
| 4. Yunlong Yang, Yuanlong Guo, Chengtao Gao, Michael North, Jili Yuan, Haibo Xie, Qiang Zheng. (2023) Fabrication of Carboxylic Acid and Imidazolium Ionic Liquid Functionalized Porous Cellulosic Materials for the Efficient Conversion of Carbon Dioxide into Cyclic Carbonates. ACS Sustainable Chemistry & Engineering, 11 (6): (2634–2646). [10.1021/acssuschemeng.2c06976] |
| 5. Sheng Zhan, Yuwei Duan, Zhike Liu, Lu Yang, Kun He, Yuhang Che, Wenjing Zhao, Yu Han, Shaomin Yang, Guangtao Zhao, Ningyi Yuan, Jianning Ding, Shengzhong (Frank) Liu. (2022) Stable 24.29%-Efficiency FA0.85MA0.15PbI3 Perovskite Solar Cells Enabled by Methyl Haloacetate-Lead Dimer Complex. Advanced Energy Materials, 12 (27): (2200867). [10.1002/aenm.202200867] |
| 6. Yao Jian, Gui Lun, Yin Shaocheng. (2021) A novel esterase from a soil metagenomic library displaying a broad substrate range. AMB Express, 11 (1): (1-10). [PMID:33666762] [10.1186/s13568-021-01198-5] |
| 7. Guangbin Ji, Fei Yang, Yanzhao Yang, Jingjing Wei, Zhijie Yang. (2021) Dynamic emulsion droplets enabled by interfacial assembly of azobenzene-functionalized nanoparticles under light and magnetic field. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 583 (586). [PMID:33038608] [10.1016/j.jcis.2020.09.058] |
| 8. Saisai Yan, Zhinong Gao, Jia Han, Zhengqin Zhang, Fei Niu, Yingfang Zhang. (2019) Controllable fabrication of stimuli-responsive fluorescent silica nanoparticles using a tetraphenylethene-functionalized carboxylate gemini surfactant. Journal of Materials Chemistry C, 7 (40): (12588-12600). [10.1039/C9TC03732B] |
| 9. Siming Yu, Rong Wen, Haiyang Wang, Yongchao Zha, Lin Qiu, Bo Li, Wei Xue, Dong Ma. (2019) Chitosan-graft-Poly(l-lysine) Dendron-Assisted Facile Self-Assembly of Au Nanoclusters for Enhanced X-ray Computer Tomography Imaging and Precise MMP-9 Plasmid shRNA Delivery. CHEMISTRY OF MATERIALS, 31 (11): (3992–4007). [10.1021/acs.chemmater.9b00507] |
| 10. Guowei Li, Siming Yu, Wei Xue, Dong Ma, Wu Zhang. (2018) Chitosan-graft-PAMAM loading nitric oxide for efficient antibacterial application. CHEMICAL ENGINEERING JOURNAL, 347 (923). [10.1016/j.cej.2018.04.159] |
| 11. Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing. (2015) Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids. CHINESE JOURNAL OF CATALYSIS, 36 (408). [10.1016/S1872-2067(14)60227-8] |
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