计算溶液所需的质量、体积或浓度。
为什么选择此级别
提供 ≥95% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。
储存与运输
室温,充氩。常规运输 。请查阅批次 COA 获取详细规格。
质量文档
SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。
文献证明
在色谱分析、有机合成和交叉偶联反应领域已被 20 篇同行评审文献引用。
概述
产品介绍
次磷酸钠水合物可用作：
作为自由基前体，在乙醚（Et3B）引发剂存在下，与烯烃发生自由基反应合成单烷基膦酸。
作为重氮盐还原试剂。
作为转移氢化反应中的氢供体。
作为酯化反应的催化剂。
也可用于配制将光引发剂（二苯甲酮）固定在棉织物上的整理液。
Sodium hypophosphite hydrate can be used as:
A radical precursor to synthesize mono alkyl phosphinic acids via radical reaction with alkenes in the presence of Et3B as the initiator.
A reagent for the reduction of the diazonium salt.
A hydrogen donor in the transfer-hydrogenation reactions.
A catalyst in the esterification reaction.
It can also be used to compose the finishing solutions for the immobilization of photo-initiator (benzophenone ) onto cotton fabrics.
规格
别名
次亚磷酸钠 水合物
英文别名
Sodium phosphinate hydrate | DTXSID40143243 | Sodium hypophosphite hydrate | Sodium phosphenite hydrate | Sodium hypophosphite monohydrate | AKOS015911117 | SODIUM HYPOPHOSPHITE, MONOHYDRATE | FT-0653627 | AKOS015912627 | SODIUM PHOSPHINATE MONOHYDRATE
规格或纯度
≥95%
英文名称
Sodium hypophosphite hydrate
储存条件
室温,充氩
运输条件
常规运输
纯度
≥95%
名称和识别符
PubChem SID
分子类型
小分子
INCHI
1S/Na.HO2P.H2O/c;1-3-2;/h;(H,1,2);1H2/q+1;;/p-1
InChi Key
ACUGTEHQOFWBES-UHFFFAOYSA-M
Smiles
O.[Na+].OP[O-]
Isomeric SMILES
O.[O-]P=O.[Na+]
关联CAS
PubChem CID
分子量
87.98 (anhydrous basis)
技术文档
高级数据
系统学分类
分类树（Taxonomy Tree）
-
界（kingdom)
无机化合物
-
超类（Superclass)
混合金属/非金属化合物
-
类（Class)
碱金属含氧阴离子化合物
- 亚类（Subclass） 碱金属次磷酸盐
-
类（Class)
碱金属含氧阴离子化合物
-
超类（Superclass)
混合金属/非金属化合物
| 界（kingdom) | 无机化合物 |
|---|---|
| 超类（Superclass) | 混合金属/非金属化合物 |
| 类（Class) | 碱金属含氧阴离子化合物 |
| 亚类（Subclass） | 碱金属次磷酸盐 |
| 中间层级节点（Intermediate Tree Nodes） | 暂无 |
| 直接上位类(Direct Parent) | 碱金属次磷酸盐 |
| 其他上位类（Alternative Parents） | 无机钠盐 无机氧化物 |
| 分子骨架（Molecular Framework) | 暂无 |
| 取代基（Substituents） | 碱金属次磷酸盐 - 无机氧化物 - 无机盐 - 无机钠盐 |
| 描述（Description） | 该化合物属于无机化合物中的碱金属次磷酸盐类。这类化合物中最大的氧阴离子为次磷酸根，且非氧阴离子中的最重原子为碱金属。 |
| 外部描述符（External Descriptors） | 暂无 |
三维结构
交互式化学结构模型
化学和物理性质
敏感性
对湿度敏感
分子量
103.978 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count
1
氢键受体数Hydrogen Bond Acceptor Count
3
可旋转键计数Rotatable Bond Count
0
精确质量Exact Mass
103.964 Da
单同位素质量Monoisotopic Mass
103.964 Da
拓扑极表面积Topological Polar Surface Area
41.100 Ų
重原子数Heavy Atom Count
5
形式电荷Formal Charge
0
复杂度Complexity
13.500
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
3
安全和危险性（GHS）
WGK Germany
2
RIDADR
NONHforallmodesoftransport
质检证书（CoA,COO,BSE/TSE 和分析图谱)
C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:
通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！
| 批号(Lot Number) | 证书类型 | 货号 |
|---|---|---|
 G2617579 |
分析证书 | S486577 |
| G2617557 |
分析证书 | S486577 |
| G2617554 |
分析证书 | S486577 |
| C2309687 |
分析证书 | S486577 |
| G2531581 |
分析证书 | S486577 |
| G2531580 |
分析证书 | S486577 |
| K2412629 |
分析证书 | S486577 |
| K2412600 |
分析证书 | S486577 |
| K2412599 |
分析证书 | S486577 |
| A2516420 |
分析证书 | S486577 |
| A2516418 |
分析证书 | S486577 |
| A2516415 |
分析证书 | S486577 |
| H2429165 |
分析证书 | S486577 |
| H2429166 |
分析证书 | S486577 |
| H2429167 |
分析证书 | S486577 |
| C2429229 |
分析证书 | S486577 |
| C2429231 |
分析证书 | S486577 |
| C2429228 |
分析证书 | S486577 |
| C2429227 |
分析证书 | S486577 |
| C2309690 |
分析证书 | S486577 |
| C2309689 |
分析证书 | S486577 |
| I2311068 |
分析证书 | S486577 |
| K2314076 |
分析证书 | S486577 |
| K2314077 |
分析证书 | S486577 |
| A2409062 |
分析证书 | S486577 |
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技术文档和文章
此产品的引用文献
引用文献
| 1. Mojie sun, Bixue Gao, Shijie Wang, Chi Wang, Dongyao Lin, Xiaochen Song, Zhao Wang. (2023) Study on the Electrocatalytic Performance of Porous Conductive Materials Based on an In Situ Growth of Bimetal Phosphides with Plasma. International Journal of Electrochemical Science, [10.20964/2020.04.46] |
| 2. Shuaizhen Li, Zhibo Zheng, Siwei Liu, Zhenguo Chi, Yi Zhang, Jiarui Xu. (2023) Flexible graphite films with high cross-plane thermal conductivity prepared by graphitization of polyimide catalyzed by Ni-coated-CNTs. Journal of Materials Chemistry C, 11 (28): (9527-9538). [10.1039/D3TC01446K] |
| 3. Ben Chong, Mengyang Xia, Yang Lv, He Li, Xiaoqing Yan, Bo Lin, Guidong Yang. (2023) Hierarchical phosphorus-oxygen incorporated cobalt sulfide hollow micro/nano-reactor for highly-efficient electrocatalytic overall water splitting. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2023.142853] |
| 4. Nannan Ma, Chuanqi Fei, Jing Wang, Yinling Wang. (2022) Fabrication of NiFe-MOF/cobalt carbonate hydroxide hydrate heterostructure for a high-performance electrocatalyst of oxygen evolution reaction. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2022.165511] |
| 5. Keyu Tao, Huamei Dan, Yang Hai, Li Liu, Yun Gong. (2019) Ultrafine Co2P anchored on porous CoWO4 nanofiber matrix for hydrogen evolution: Anion-induced compositional/morphological transformation and interfacial electron transfer. ELECTROCHIMICA ACTA, [10.1016/j.electacta.2019.135123] |
| 6. Dongxu Wang, Wanfeng Mao, Lihong Zhao, Duo Meng, Jiaqi Tang, Tengfei Wu. (2024) Efficient Photocatalytic Removal of Aqueous Ammonia Nitrogen by g-C3N4/CoP Heterojunctions Under Visible Light Illumination. Nanomaterials, 14 (24): (1996). [PMID:39728532] [10.3390/nano14241996] |
| 7. Yanan Liu, Yu Zhang, Xiaogang Su, Yaqing Liu, Guizhe Zhao. (2025) Magnetic-dielectric synergistic cladding of hollow fly ash for excellent microwave absorption performance. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2025.179665] |
| 8. Mengjie Pan, Huachen Lin, Lin Sun, Yulong Ying, Hong Jia, Yu Liu. (2024) MnO2 nanosheets modified CoP/P-C core/shell nanotubes with vertically aligned channels for promoting supercapacitor performances. CHEMICAL ENGINEERING SCIENCE, [10.1016/j.ces.2024.121061] |
| 9. Bingrong Guo, Jianying Zhao, Yao Xu, Xinxin Wen, Xiaoqian Ren, Xiaoxiao Huang, Siqi Niu, Yulong Dai, Ruhai Gao, Ping Xu, Siwei Li. (2024) Noble Metal Phosphides Supported on CoNi Metaphosphate for Efficient Overall Water Splitting. ACS Applied Materials & Interfaces, [PMID:38334369] [10.1021/acsami.3c19077] |
| 10. Xiangyang Chen, Shun Gong, Biao Zhao, Kai Pan. (2024) Polyetheramine-Type Semi-Biobased Long-Chain Polyamide 1210 Elastomer: Synthesis, Structure, and Unique Thermal Behavior. MACROMOLECULAR MATERIALS AND ENGINEERING, [10.1002/mame.202300426] |
| 11. Shucan Qin, Qianqian Peng, Weizhen Kong, Rong Xue, Chongqing Xu, Jianming Shi, Yanrong Liu, Yunqian Ma. (2024) Self-supported bifunctional P–CoSe/NF electrodes for high efficiency and durability hydrogen production coupled with sulfion valorization. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, [10.1016/j.ijhydene.2024.11.153] |
| 12. Yapeng Zhang, Hean Zhu, Zeqi Nie, Huihuang Yu, Wen Zhang, Wenkai Yan, Yige Xiong, Mengqi Tian, Haipeng Wang, Guanhua Zhang. (2024) Three-dimensional high-aspect-ratio microarray thick electrodes for high-rate hybrid supercapacitors. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:38986324] [10.1016/j.jcis.2024.07.018] |
| 13. Chunyi Ye, Yang Yang, Shujing Chen, Chunhua Liu, Xiao-Qing Sun, Danni Liu, Jiujun Zhang, Jing-Li Luo, Xian-Zhu Fu. (2025) Cu nanowire arrays on electroless deposited cu foam for efficient electrocatalytic formaldehyde selective conversion to co-produce H2 and valuable chemicals. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2025.168224] |
| 14. Kun Zhang, Yunxia Liang, Shuangqian Liu, Long Wang, Guangtian Ji, Chengwei Yang, Jueming Yang, Jinli Zhang, Guixian Ge. (2025) Phosphorus doped self-grown multiphase molybdate compounds micrometer arrays for efficient HER and OER. FUEL, [10.1016/j.fuel.2025.134957] |
| 15. Chenglong Wan, Like Hou, Qing Hu, Zihe Zhao, Yanxia Yang, Biao Zhao, Jianping Deng, Kai Pan. (2025) Chain Length Regulation of PA66/PPO-PEO-PPO Multiblock Elastomers: Synthesis, Structure, and Property. MACROMOLECULAR CHEMISTRY AND PHYSICS, [10.1002/macp.202400458] |
| 16. Yaolin Hou, Jolla Kullgren, Lei Han, Pengyuan Qian, Wei Yuan, Jia Liu, Haiming Xie, Jiefang Zhu. (2025) NiO-Ni2P/C3N4 heterostructures with synergistic adsorption-electrocatalysis functions for suppressing polysulfide shuttle effect in lithium sulfur batteries. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:40414040] [10.1016/j.jcis.2025.137972] |
| 17. Ding Ding, Pengwei Li, Yuxiang Zhu, Kai Chen, Zhongxiong Fan, Yanyun Zhang, Qingchi Xu, Jun Xu. (2025) Dual electronic-ionic conductive 3D current collector for stable lithium metal anodes. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:40543315] [10.1016/j.jcis.2025.138132] |
| 18. Rui Xiao, Changgeng Li, Lu Wu, Lingzhi Huang, Wenchao Jia, Bing Wang, Xueru Sheng, Pedram Fatehi, Haiqiang Shi. (2025) Bio-degradable superhydrophobic cellulose-based paper straws fabricated through coating of citric acid-crosslinking CNF & stearic acid. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, [PMID:41407222] [10.1016/j.ijbiomac.2025.149612] |
| 19. Zhuming Mao, Yansong Zhou, Yina Guo, Yanjing Liu, Yang Liu, Minghui Cui, Qiongrong Ou, Shuyu Zhang. (2025) Dual Interfacial Engineering of Cracked NiCoP Electrode with Directed Bubbling for Efficient and Stable Hydrogen Evolution. Small, 21 (36): (2506058). [PMID:40643078] [10.1002/smll.202506058] |
| 20. Ayaz Muzammil, Rizwan Haider, Chenrui Zhang, Khizar Qureshi, Yifeng Feng, Ruiqu Deng, Liang Wu, Yijun He, Xianxia Yuan. (2026) Morphology-dependent surface-electronic coordination in bimetallic phosphides for enhanced water splitting kinetics. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2026.178723] |
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