(+)-10-樟脑磺酸

19篇引用文献

Moligand™

≥99%

CAS编号: 3144-16-9
分子式: C₁₀H₁₆O₄S
分子量: 232.3
Beilstein号: 2809675
EC号: 221-554-1
MDL号: MFCD00064157
PubChem编号: 65617
PubChem SID: 488183693

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货号 (SKU)	包装规格	是否现货
C106038-25g	25g	现货
C106038-100g	100g	现货
C106038-500g	500g	现货
C106038-1kg	1kg	期货

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基本描述

别名	右旋樟脑磺酸
英文别名	(R)-camphorsulfonic acid \| (s)-camphorsulfonic acid
规格或纯度	Moligand™, ≥99%
英文名称	(1S)-(+)-10-Camphorsulfonic acid
应用	可作为拆分剂，以及二肽偶联的催化剂。（1S）-（+）-10-樟脑磺酸可用作合成 10-碘樟脑的原料。它还可以用作掺杂剂以在聚苯胺的导带中诱导手性。（±）-S-甲基-S-苯基亚磺酰亚胺可以用它作为手性拆分剂拆分，形成高对映体纯度的（-）-形式。
储存温度	充氩
运输条件	常规运输
产品介绍	不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。可作为拆分剂，以及二肽偶联的催化剂。（1S）-（+）-10-樟脑磺酸可用作合成 10-碘樟脑的原料。它还可以用作掺杂剂以在聚苯胺的导带中诱导手性。（±）-S-甲基-S-苯基亚磺酰亚胺可以用它作为手性拆分剂拆分，形成高对映体纯度的（-）-形式。 Used as a resolving agent, as a catalyst for coupling dipeptides.

AI解读

名称和识别符

PubChem SID	488183693
EC号	221-554-1
分子类型	小分子
IUPAC Name	[(1S,4R)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonic acid
INCHI	InChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChi Key	MIOPJNTWMNEORI-GMSGAONNSA-N
Canonical SMILES	CC1(C2CCC1(C(=O)C2)CS(=O)(=O)O)C
Isomeric SMILES	CC1([C@@H]2CC[C@]1(C(=O)C2)CS(=O)(=O)O)C
WGK Germany	3
RTECS	ED1550000
PubChem CID	65617
UN Number	3261
分子量	232.3
Beilstein号	2809675
Reaxy-Rn	2809675

化学和物理性质

溶解性	可溶于水；不溶于乙醚
密度	1.331
敏感性	易吸潮
比旋光度	21.5 ° (C=5, H2O)
熔点	196-200°C
分子量	232.300 g/mol
XLogP3	0.500
氢键供体数Hydrogen Bond Donor Count	1
氢键受体数Hydrogen Bond Acceptor Count	4
可旋转键计数Rotatable Bond Count	2
精确质量Exact Mass	232.077 Da
单同位素质量Monoisotopic Mass	232.077 Da
拓扑极表面积Topological Polar Surface Area	79.800 Å²
重原子数Heavy Atom Count	15
形式电荷Formal Charge	0
复杂度Complexity	404.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	2
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS05
信号词	Danger
危险声明	H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤
预防措施声明	P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。
WGK Germany	3
RTECS	ED1550000
Reaxy-Rn	2809675
Merck Index	1734
个人防护装备	Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

技术规格说明书

Melting point	197-200（℃）
Loss on drying	0-2（%）
Purity(Neutralization titration)	98.5-101.5（%）
Specific Rotation [a]20/D(c=5 in H2O)	20-23（°）
Appearance（c106038)	White to Off-White Powder or Crystals
Proton NMR spectrum	Conforms to Structure
Solubility5% in H2O	Clear colorless to light yellow solution

技术规格说明书

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批号(Lot Number)	证书类型	日期	货号
B2512244	分析证书	25-01-13	C106038
B2512245	分析证书	25-01-13	C106038
B2512246	分析证书	25-01-13	C106038
L2424344	分析证书	24-12-27	C106038
L2424343	分析证书	24-12-27	C106038
L2424340	分析证书	24-12-27	C106038
H2421161	分析证书	24-08-14	C106038
E2423201	分析证书	24-05-09	C106038
F2403142	分析证书	24-04-01	C106038
F2421426	分析证书	24-04-01	C106038
F2421145	分析证书	24-04-01	C106038
F2403139	分析证书	24-04-01	C106038
F2403138	分析证书	24-04-01	C106038
D2402489	分析证书	24-03-16	C106038
D2402487	分析证书	24-03-16	C106038
D2402177	分析证书	24-03-16	C106038
D2402176	分析证书	24-03-16	C106038
L1919110	分析证书	23-10-20	C106038
B2308404	分析证书	23-02-20	C106038
A2405076	分析证书	22-06-14	C106038
G2222203	分析证书	22-06-14	C106038
G2222225	分析证书	22-06-14	C106038
G2222227	分析证书	22-06-14	C106038
G2222228	分析证书	22-06-14	C106038

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27. Man Zhou, Suting Xue, Qin Feng, Xuan Liang, Wangchen Wu, Yanli Zhou, Minmin Ni, Xudong Zheng, Song Xu, Jin Zhao, Zhongyu Li. (2023) Carbon layers on Pt/TiO2 induced dramatic promotion of photocatalytic H2 production: a combined experimental and computation study. Materials Today Energy, 34 (101294). [10.1016/j.mtener.2023.101294]
28. Kongsen Hu, Jiyuan Feng, Nan Lv, Wenbo Jiang, Zhiwei Lyu, Qing Hai. (2022) Novel flexible piezoelectric-conductive Janus nanofibers integrated membrane with enhanced pressure sensing performance. JOURNAL OF APPLIED POLYMER SCIENCE, 139 (20): (52180). [10.1002/app.52180]
29. Ting Huang, Huang-xian Zhang, Xiao-hua Zhang, Da-yong Peng, Xu-liang Nie, Jing Chen, Wan-ming Xiong. (2022) Preparation of functionalized diallylimidazole ionic liquid and its application in conversion of D-fructose into HMF. JOURNAL OF MOLECULAR LIQUIDS, 345 (118233). [10.1016/j.molliq.2021.118233]
30. Nan Lv, Wenbo Jiang, Kongsen Hu, Zhiwei Lyu. (2021) Synchronous Construction of Piezoelectric Elements and Nanoresistance Networks for Pressure Sensing Based on the Wheatstone Bridge Principle. ACS Applied Electronic Materials, 3 (9): (3936–3947). [10.1021/acsaelm.1c00509]
31. Yu Xia, Zegang Wang, Li-Ye Chen, Si-Wei Xiong, Pan Zhang, Pei-Gen Fu, Jing-Gang Gai. (2020) Nanoscale polyelectrolyte/metal ion hydrogel modified RO membrane with dual anti-fouling mechanism and superhigh transport property. DESALINATION, 488 (114510). [10.1016/j.desal.2020.114510]
32. Muhammad A. Shehzad, Xian Liang, Aqsa Yasmin, Xiaolin Ge, Xinle Xiao, Yuan Zhu, Zijuan Ge, Yang Wang, Liang Wu, Tongwen Xu. (2019) Angioplasty mimetic stented ion transport channels construct durable high-performance membranes. Journal of Materials Chemistry A, 7 (16): (10030-10040). [10.1039/C9TA01291E]
33. Shen Liang, Tian Lian, Zuo Jian, Zhang Xuan, Sun Shipeng, Wang Yan. (2019) Developing high-performance thin-film composite forward osmosis membranes by various tertiary amine catalysts for desalination. Advanced Composites and Hybrid Materials, 2 (1): (51-69). [10.1007/s42114-018-0070-1]
34. Ruiqi Li, Yudan Wang, Dan Zhou, Lijia Liu, Junqing Li, Yufa Li, Jijin Dai, Yushan Han. (2018) Handedness switch of synthesized helical polyaniline nanofibers featuring the use of a single enantiomeric acid and aniline oligomers. POLYMER, 159 (39). [10.1016/j.polymer.2018.10.011]
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