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1，3，5-三甲氧基苯

1，3，5-三甲氧基苯

规格或纯度: 98%

CAS编号: 621-23-8
分子式: C₉H₁₂O₃
分子量: 168.19
Beilstein号: 1307993
EC号: 210-673-4
MDL号: MFCD00008385
PubChem编号: 69301

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货号 (SKU)	包装规格	是否现货	价格	数量
T107286-5g	5g	现货
T107286-25g	25g	现货
T107286-100g	100g	现货
T107286-250g	250g	现货
T107286-500g	500g	现货

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含氧化合物醚

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基本描述

别名	均三甲氧基苯\|间苯三酚三甲基醚\|间苯三酚三甲醚
英文别名	1,3,5-Trimethoxybenzene\|621-23-8\|Phloroglucinol trimethyl ether\|sym-Trimethoxybenzene\|Benzene, 1,3,5-trimethoxy-\|1,3,5-Trimethyoxybenzene\|MFCD00008385\|00VJI3VG3D\|DTXSID0045963\|CHEBI:31038\|NSC-90060\|NCGC00095239-01\|DTXCID8025963\|1,3,5-Trimethoxybenzene (JA
规格或纯度	98%
英文名称	1,3,5-Trimethoxybenzene
应用	医药和有机合成中间体;1,3,5-三甲氧基苯用于研究1,2-苯并二亚苯基亚砜的光致脱氧反应。它被用作药物定量质子NMR光谱的二级标准品。
运输条件	常规运输
备注	10g、50g、250g卖完停产，不再备货
产品介绍	不溶于水；溶于大多数常规有机溶剂，溶于甲醇。 1,3,5-三甲氧基苯可有效地裂解各种醇和酸上的对甲氧基苄基保护基。它是中国玫瑰品种中的主要芳香化合物医药和有机合成中间体;1,3,5-三甲氧基苯用于研究1,2-苯并二亚苯基亚砜的光致脱氧反应。它被用作药物定量质子NMR光谱的二级标准品。 1,3,5-Trimethoxybenzene effectively cleaves p-methoxybenzyl protecting group on various alcohols and acids. It is the major scent compound present in Chinese rose species.

名称和标识符

PubChem SID	488184282
PubChem SID url	https://pubchem.ncbi.nlm.nih.gov/substance/488184282
EC号	210-673-4
IUPAC Name	1,3,5-trimethoxybenzene
INCHI	InChI=1S/C9H12O3/c1-10-7-4-8(11-2)6-9(5-7)12-3/h4-6H,1-3H3
InChi Key	LKUDPHPHKOZXCD-UHFFFAOYSA-N
Canonical SMILES	COC1=CC(=CC(=C1)OC)OC
Isomeric SMILES	COC1=CC(=CC(=C1)OC)OC
WGK Germany	3
RTECS	DC2810000
PubChem CID	69301
分子量	168.19
Beilstein号	1307993
Reaxy-Rn	1307993

数据库链接

PubChem SID	488184282

化学和物理性质

溶解性	Insoluble in water.
密度	1.041
闪点(℉)	186.8 °F
闪点(℃)	86 °C
沸点	255°C
熔点	50-53°C

安全和危险性（GHS）

象形图	Harmful
信号词	Warning
危险声明	H319: Causes serious eye irritation H302: Harmful if swallowed
预防措施声明	P305+P351+P338,P280,P501,P264,P270,P330,P264+P265,P301+P317,P337+P317
WGK Germany	3
RTECS	DC2810000
Reaxy-Rn	1307993
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

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参考文献

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9. Eino Mvula,Sergej Naumov,Clemens von Sonntag. (2009-09-15) Ozonolysis of lignin models in aqueous solution: anisole, 1,2-dimethoxybenzene, 1,4-dimethoxybenzene, and 1,3,5-trimethoxybenzene.. Environmental science & technology, 43 ((16)): (6275-6282). [PMID:19746725]
10. Robert A Moss,Lei Wang,Christina M Odorisio,Min Zhang,Karsten Krogh-Jespersen. (2009-11-03) Solvation of dichlorocarbene: complexation with aryl ethers.. The journal of physical chemistry. A, 114 ((1)): (209-217). [PMID:19877654]
11. Martin A Fascione,Nicola J Webb,Colin A Kilner,Stuart L Warriner,W Bruce Turnbull. (2011-12-28) Stereoselective glycosylations using oxathiane spiroketal glycosyl donors.. Carbohydrate research, 348 (): (6-13). [PMID:22200482]
12. Torgny Rundlöf,Ian McEwen,Monika Johansson,Torbjörn Arvidsson. (2013-11-12) Use and qualification of primary and secondary standards employed in quantitative ¹H NMR spectroscopy of pharmaceuticals.. Journal of pharmaceutical and biomedical analysis, 93 (): (111-117). [PMID:24206940]
13. E Lucien,A Greer. (2001-06-26) Electrophilic oxidant produced in the photodeoxygenation of 1,2-benzodiphenylene sulfoxide.. The Journal of organic chemistry, 66 ((13)): (4576-4579). [PMID:11421776]
14. Shuiqin Wu,Naoharu Watanabe,Satoru Mita,Hideo Dohra,Yoshihiro Ueda,Masaaki Shibuya,Yutaka Ebizuka. (2004-05-04) The key role of phloroglucinol O-methyltransferase in the biosynthesis of Rosa chinensis volatile 1,3,5-trimethoxybenzene.. Plant physiology, 135 ((1)): (95-102). [PMID:15122041]
15. Xichen Cai,Masanori Sakamoto,Mamoru Fujitsuka,Tetsuro Majima. (2007-02-14) One-electron oxidation of alcohols by the 1,3,5-trimethoxybenzene radical cation in the excited state during two-color two-laser flash photolysis.. The journal of physical chemistry. A, 111 ((10)): (1788-1791). [PMID:17295459]
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