基本描述

别名	叔丁基甲基醚 \| MTBE
英文别名	tert-Butyl methyl ether \| Methyl tert-butyl ether \| 1634-04-4 \| MTBE \| 2-Methoxy-2-methylpropane \| Methyl t-butyl ether \| Propane, 2-methoxy-2-methyl- \| T-BUTYL METHYL ETHER \| Methyl-tert-butyl ether \| Methyl-t-butyl ether \| 2-Methyl-2-methoxypropane \| Methyl tertiary-butyl et
规格或纯度	PureSpectra™, ACS, 光谱纯, ≥99.8%(GC)
英文名称	tert-Butyl methyl ether
应用	溶剂。色谱中尤其是高压液相色谱中用作脱剂。有机合成。无铅汽油中辛烷传爆剂。
运输条件	常规运输
产品介绍	具有醚样气味。酸性溶液中不稳定。易溶于乙醇和乙醚，溶于(4.8g/100g)。水溶于叔丁基甲基醚：1.5g/100g。半数致死量(小鼠，15分钟)1.6mmol/L。易燃。对眼睛、呼吸系统和皮肤有刺激性。溶剂。色谱中尤其是高压液相色谱中用作脱剂。有机合成。无铅汽油中辛烷传爆剂。叔丁基甲基醚（甲基叔丁醚，MTBE）是一种汽油添加剂。丙烷氧化细菌菌株对其进行氧化降解已经过测定。其热介导的生物降解的动力学已经在多种反应条件下进行了研究。其生物降解遵循伪一级衰变模型，并且其伪一级速率常数已经过测定。其水中的提取物已通过使用有机聚合化合物Nafion进行研究。MTBE可以通过甲醇和异丁烯之间的酸催化反应合成。一项研究表明，MTBE的加入通过停流法增加了丙烯聚合过程中活性位点的数量。该溶剂符合ACS（美国化学学会）规范，可用于需要严格质量条件的工艺，如分析测试。应用叔甲基醚（甲基叔丁醚，MTBE）可用于：作为混合微生物菌群中的唯一碳和能量来源。从生物液体中提取脂质用于鸟枪法谱分析。在超临界条件下，在不存在催化剂的情况下通过菜籽油的酯交换，合成脂肪酸甲酯（FAME）和甘油叔丁醚。

AI解读

作用机制

作用机制	Action Type	target ID	Target Name	Target Type	Target Organism	Binding Site Name	参考文献

名称和识别符

EC号	216-653-1
分子类型	小分子
IUPAC Name	2-methoxy-2-methylpropane
INCHI	InChI=1S/C5H12O/c1-5(2,3)6-4/h1-4H3
InChi Key	BZLVMXJERCGZMT-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)OC
Isomeric SMILES	CC(C)(C)OC
WGK Germany	1
RTECS	KN5250000
PubChem CID	15413
UN Number	2398
Packing Group	II
分子量	88.15
Beilstein号	1730942
Reaxy-Rn	1730942

化学和物理性质

溶解性	不溶于水。
密度	0.74
折光率	1.3689
闪点(℉)	-18.4℉
闪点(℃)	-28℃
沸点	55.2°C
熔点	-109°C
分子量	88.150 g/mol
XLogP3	0.900
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	88.0888 Da
单同位素质量Monoisotopic Mass	88.0888 Da
拓扑极表面积Topological Polar Surface Area	9.200 Å²
重原子数Heavy Atom Count	6
形式电荷Formal Charge	0
复杂度Complexity	33.700
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS07, GHS02
信号词	Danger
危险声明	H315: 引起皮肤刺激 H225: 高度易燃的液体和蒸气
预防措施声明	P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。
WGK Germany	1
RTECS	KN5250000
Reaxy-Rn	1730942
Class	3
Merck Index	6032
个人防护装备	Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US)

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批号(Lot Number)	证书类型	日期	货号
A2503033	分析证书	25-01-07	B108119
G2405125	分析证书	24-07-12	B108119
F2401067	分析证书	24-06-05	B108119
J2318241	分析证书	23-10-26	B108119
H2314372	分析证书	23-08-31	B108119
K2226259	分析证书	22-11-29	B108119
K2217031	分析证书	22-11-22	B108119
F2213021	分析证书	22-06-14	B108119

此产品的引用文献

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