计算溶液所需的质量、体积或浓度。
有很强吸湿性,650℃熔融,650℃以上升华,在空气中加热即释放出氯化氢气体并生成四氧化三锰。溶于水、醇,不溶于醚。通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构,在基态时具有 24 个不成对电子。1还用于形成可用于自由基环化反应的活性 Mn(0) 物质。
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state. Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.