基本描述

别名	氯化铂钾 \| 六氯铂酸钾 \| 六氯化铂 (IV) 钾, 六氯化铂二钾, 六氯铂酸二钾 \| 铂氯化钾
英文别名	Dipotassium hexachloroplatinate \| Platinic potassium chloride \| Dipotassium platinum hexachloride \| Potassium platinic chloride \| Potassium chloroplatinate \| Potassium platinum(IV) hexachoride
规格或纯度	≥99.9% metals basis
英文名称	Potassium hexachloroplatinate(IV)
应用	制备贵金属催化剂和贵金属涂镀。六氯铂酸钾 (IV) 可作为反应物合成氯五胺铂 (IV) 、三硒化铂、反式 -二氯（乙二胺- N 、 N ′-二-3-丙氧基）铂 (IV) 和四氯（ O , O -二烷基-乙二胺- N , N ′-二-3-丙氧基）铂 (IV) 配合物。
储存温度	充氩
运输条件	常规运输
产品介绍	微溶于冷水(Water Solubility 50 g/l ,95°C),不溶于乙醇、醚，溶于盐酸（10%）溶液。制备贵金属催化剂和贵金属涂镀。六氯铂酸钾 (IV) 可作为反应物合成氯五胺铂 (IV) 、三硒化铂、反式 -二氯（乙二胺- N 、 N ′-二-3-丙氧基）铂 (IV) 和四氯（ O , O -二烷基-乙二胺- N , N ′-二-3-丙氧基）铂 (IV) 配合物。 Potassium hexachloroplatinate(IV) can be used as a reactant to synthesize compounds such as chloropentaammineplatinum(IV), platinum triselenide, trans-dichloro(ethylenediamine-N,N′-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N′-di-3-propanoato)platinum(IV) complexes.

AI解读

名称和识别符

PubChem SID	504753811
EC号	240-979-3
IUPAC Name	dipotassium;hexachloroplatinum(2-)
INCHI	InChI=1S/6ClH.2K.Pt/h61H;;;/q;;;;;;2+1;+4/p-6
InChi Key	DPAIVKJGTXERIM-UHFFFAOYSA-H
Canonical SMILES	Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]
Isomeric SMILES	Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.[K+].[K+]
WGK Germany	1
RTECS	TP1650000
关联CAS	16921-30-5
PubChem CID	61856
分子量	485.99

化学和物理性质

溶解性	Soluble in hot water. Slightly soluble in cold water. Practically insoluble in alcoholSoluble in hot water. Slightly soluble in cold water. Insoluble in alcohol.
密度	3.499
敏感性	对湿度敏感
熔点	250°C
分子量	486.000 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	484.702 Da
单同位素质量Monoisotopic Mass	482.705 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	9
形式电荷Formal Charge	0
复杂度Complexity	62.700
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	3

安全和危险性（GHS）

象形图	GHS06, GHS08, GHS05, GHS07
信号词	Danger
危险声明	H301: 吞咽会中毒 H318: 造成严重的眼睛损伤 H317: 可能引起皮肤过敏反应 H334: 吸入可能引起过敏或哮喘病症状或呼吸困难
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P284: 如果通风不良，请佩戴呼吸防护装置。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P272: 被污染的工作服不允许离开工作场所 P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P330: 漱口 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P301+P316: 如果吞咽：立即寻求紧急医疗救助。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P342+P316: 如果出现呼吸道症状：立即寻求急救。
WGK Germany	1
RTECS	TP1650000
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

技术规格说明书

Platinum(Pt)(Gravimetric Analysis)	38-41（%）
Purity(Based On Trace Rare Earth Analysis)	99.9-100（%）
Trace Rare Earth Analysis	0-2000（ppm）
Appearance（P123846)	Yellow to Yellow-Orange Powder
ICP: Confirms K and Pt Component	Confirmed
X-Ray Diffraction	Conforms to Structure

技术规格说明书

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找到31个结果

批号(Lot Number)	证书类型	日期	货号
B2519486	分析证书	25-01-11	P123846
B2519487	分析证书	25-01-11	P123846
B2519488	分析证书	25-01-11	P123846
B2519501	分析证书	25-01-11	P123846
K2418391	分析证书	24-10-25	P123846
K2418390	分析证书	24-10-25	P123846
K2418389	分析证书	24-10-25	P123846
K2418388	分析证书	24-10-25	P123846
H2422492	分析证书	24-08-10	P123846
H2422491	分析证书	24-08-10	P123846
H2422483	分析证书	24-08-10	P123846
H2422482	分析证书	24-08-10	P123846
H2422481	分析证书	24-08-10	P123846
D2424382	分析证书	24-04-18	P123846
D2424383	分析证书	24-04-18	P123846
D2424384	分析证书	24-04-18	P123846
G2319692	分析证书	23-06-13	P123846
G2319694	分析证书	23-06-13	P123846
G2319691	分析证书	23-06-13	P123846
G2319642	分析证书	23-06-13	P123846
D2319853	分析证书	23-03-21	P123846
F23081067	分析证书	23-03-21	P123846
D23191078	分析证书	23-03-21	P123846
D23191040	分析证书	23-03-21	P123846
A2310426	分析证书	23-01-29	P123846
F2223313	分析证书	22-06-08	P123846
F2223312	分析证书	22-06-08	P123846
F2223311	分析证书	22-06-08	P123846
F2223310	分析证书	22-06-08	P123846
K2209101	分析证书	22-06-08	P123846
C2221045	分析证书	22-03-31	P123846

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48. Wenjuan Lei, Yongsheng Yu, Weiwei Yang, Ming Feng, Haibo Li. (2017) A general strategy for synthesizing high-coercivity L10-FePt nanoparticles. Nanoscale, 9 (35): (12855-12861). [PMID:28849847] [10.1039/C7NR04849A]
49. Dongting Yue, Xufang Qian, Miao Kan, Meng Ren, Yao Zhu, Lele Jiang, Yixin Zhao. (2017) Sulfurated [NiFe]-based layered double hydroxides nanoparticles as efficient co-catalysts for photocatalytic hydrogen evolution using CdTe/CdS quantum dots. APPLIED CATALYSIS B-ENVIRONMENTAL, 209 (155). [10.1016/j.apcatb.2017.02.075]
50. Zonggang Mu, Lei Jiao, Qin Wei, He Li. (2016) Ternary Pt@Pd@Ru nanodendrite-decorated graphene oxide for sensitive electrochemical immunoassy of CEA. RSC Advances, 6 (49): (42994-42999). [10.1039/C6RA07328J]
51. Lei Jiao, Zonggang Mu, Chengzhou Zhu, Qin Wei, He Li, Dan Du, Yuehe Lin. (2016) Graphene loaded bimetallic Au@Pt nanodendrites enhancing ultrasensitive electrochemical immunoassay of AFP. SENSORS AND ACTUATORS B-CHEMICAL, 231 (513). [10.1016/j.snb.2016.03.034]
52. Yan Dai, Wenji Zheng, Xiangcun Li, Bo Chen, Le Wang, Gaohong He. (2016) Highly active catalysis–membrane system: Enhanced recyclability, durability and longevity properties for H2 generation. CHEMICAL ENGINEERING JOURNAL, 293 (252). [10.1016/j.cej.2016.02.065]
53. Tao Yang, Guojian Cao, Qingli Huang, Yanxia Ma, Sheng Wan, Hong Zhao, Na Li, Xia Sun, Fujun Yin. (2015) Surface-Limited Synthesis of Pt Nanocluster Decorated Pd Hierarchical Structures with Enhanced Electrocatalytic Activity toward Oxygen Reduction Reaction. ACS Applied Materials & Interfaces, 7 (31): (17162–17170). [PMID:26181191] [10.1021/acsami.5b04021]
54. Yangliao Hu, Xiangheng Niu, Hongli Zhao, Jie Tang, Minbo Lan. (2015) Enzyme-Free Amperometric Detection of Glucose on Platinum-Replaced Porous Copper Frameworks. ELECTROCHIMICA ACTA, 165 (383). [10.1016/j.electacta.2015.03.036]
55. Shaochun Tang, Sascha Vongehr, Yongguang Wang, Juan Cui, Xiangyu Wang, Xiangkang Meng. (2014) Versatile synthesis of high surface area multi-metallic nanosponges allowing control over nanostructure and alloying for catalysis and SERS detection. Journal of Materials Chemistry A, 2 (10): (3648-3660). [10.1039/C3TA14541G]
56. Xinyu Wang, Yincong Zhang, Tianfu Li, Wende Tian, Qiang Zhang, Yiyun Cheng. (2013) Generation 9 Polyamidoamine Dendrimer Encapsulated Platinum Nanoparticle Mimics Catalase Size, Shape, and Catalytic Activity. LANGMUIR, 29 (17): (5262–5270). [PMID:23544351] [10.1021/la3046077]
57. Shaochun Tang, Sascha Vongehr, Zhou Zheng, Hanjin Liu, Xiangkang Meng. (2010) Silver Doping Mediated Route to Bimetallically Doped Carbon Spheres with Controllable Nanoparticle Distributions. Journal of Physical Chemistry C, 114 (43): (18338–18346). [10.1021/jp105871w]
58. Jingming Gong, Lianyi Wang, Xingju Miao, Lizhi Zhang. (2010) Efficient stripping voltammetric detection of organophosphate pesticides using NanoPt intercalated Ni/Al layered double hydroxides as solid-phase extraction. ELECTROCHEMISTRY COMMUNICATIONS, 12 (1658). [10.1016/j.elecom.2010.09.021]
59. Yichang Ma,Jianxian Zeng,Yajie Zeng,Hu Zhou,Guoqing Liu,Yuan Liu,Lingwei Zeng,Jian Jian,Zhengqiu Yuan. (2019-10-04) Preparation and performance of poly(4-vinylpyridine)-b-polysulfone-b-poly(4-vinylpyridine) triblock copolymer/polysulfone blend membrane for separation of palladium (II) from electroplating wastewaters.. Journal of hazardous materials, 384 (121277-121277). [PMID:31581018]

参考文献

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49. Dongting Yue, Xufang Qian, Miao Kan, Meng Ren, Yao Zhu, Lele Jiang, Yixin Zhao. (2017) Sulfurated [NiFe]-based layered double hydroxides nanoparticles as efficient co-catalysts for photocatalytic hydrogen evolution using CdTe/CdS quantum dots. APPLIED CATALYSIS B-ENVIRONMENTAL, 209 (155). [10.1016/j.apcatb.2017.02.075]
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51. Lei Jiao, Zonggang Mu, Chengzhou Zhu, Qin Wei, He Li, Dan Du, Yuehe Lin. (2016) Graphene loaded bimetallic Au@Pt nanodendrites enhancing ultrasensitive electrochemical immunoassay of AFP. SENSORS AND ACTUATORS B-CHEMICAL, 231 (513). [10.1016/j.snb.2016.03.034]
52. Yan Dai, Wenji Zheng, Xiangcun Li, Bo Chen, Le Wang, Gaohong He. (2016) Highly active catalysis–membrane system: Enhanced recyclability, durability and longevity properties for H2 generation. CHEMICAL ENGINEERING JOURNAL, 293 (252). [10.1016/j.cej.2016.02.065]
53. Tao Yang, Guojian Cao, Qingli Huang, Yanxia Ma, Sheng Wan, Hong Zhao, Na Li, Xia Sun, Fujun Yin. (2015) Surface-Limited Synthesis of Pt Nanocluster Decorated Pd Hierarchical Structures with Enhanced Electrocatalytic Activity toward Oxygen Reduction Reaction. ACS Applied Materials & Interfaces, 7 (31): (17162–17170). [PMID:26181191] [10.1021/acsami.5b04021]
54. Yangliao Hu, Xiangheng Niu, Hongli Zhao, Jie Tang, Minbo Lan. (2015) Enzyme-Free Amperometric Detection of Glucose on Platinum-Replaced Porous Copper Frameworks. ELECTROCHIMICA ACTA, 165 (383). [10.1016/j.electacta.2015.03.036]
55. Shaochun Tang, Sascha Vongehr, Yongguang Wang, Juan Cui, Xiangyu Wang, Xiangkang Meng. (2014) Versatile synthesis of high surface area multi-metallic nanosponges allowing control over nanostructure and alloying for catalysis and SERS detection. Journal of Materials Chemistry A, 2 (10): (3648-3660). [10.1039/C3TA14541G]
56. Xinyu Wang, Yincong Zhang, Tianfu Li, Wende Tian, Qiang Zhang, Yiyun Cheng. (2013) Generation 9 Polyamidoamine Dendrimer Encapsulated Platinum Nanoparticle Mimics Catalase Size, Shape, and Catalytic Activity. LANGMUIR, 29 (17): (5262–5270). [PMID:23544351] [10.1021/la3046077]
57. Shaochun Tang, Sascha Vongehr, Zhou Zheng, Hanjin Liu, Xiangkang Meng. (2010) Silver Doping Mediated Route to Bimetallically Doped Carbon Spheres with Controllable Nanoparticle Distributions. Journal of Physical Chemistry C, 114 (43): (18338–18346). [10.1021/jp105871w]
58. Jingming Gong, Lianyi Wang, Xingju Miao, Lizhi Zhang. (2010) Efficient stripping voltammetric detection of organophosphate pesticides using NanoPt intercalated Ni/Al layered double hydroxides as solid-phase extraction. ELECTROCHEMISTRY COMMUNICATIONS, 12 (1658). [10.1016/j.elecom.2010.09.021]
59. Yichang Ma,Jianxian Zeng,Yajie Zeng,Hu Zhou,Guoqing Liu,Yuan Liu,Lingwei Zeng,Jian Jian,Zhengqiu Yuan. (2019-10-04) Preparation and performance of poly(4-vinylpyridine)-b-polysulfone-b-poly(4-vinylpyridine) triblock copolymer/polysulfone blend membrane for separation of palladium (II) from electroplating wastewaters.. Journal of hazardous materials, 384 (121277-121277). [PMID:31581018]

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