铑粉

  • ≥99.95% metals basis
有货

库存信息

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库存信息

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
R109242-50mg
50mg 期货 Stock Image
R109242-250mg
250mg 现货 Stock Image
R109242-1g
1g 现货 Stock Image

基本描述

别名 铑黑 | 铑碳
英文别名 Rh Black | R024050000 | RHODIUM [HSDB] | Rhodium on alumina, extent of labeling: 0.5 wt. % loading, pellets, 3.2 mm | HSDB 2534 | Rhodium atomic absorption standard | Rhodium powder, -60 mesh | HSDB 7121 | Rhodium Internal Standard: Rh @ 10 microg/mL in 2
规格或纯度 ≥99.95% metals basis
英文名称 Rhodium
应用 可用作电器仪表、化工及制造精密合金等的原料。
运输条件 常规运输
产品介绍

纯净、无肉眼可见夹杂物及氧化色。耐蚀性较高, 甚至不溶于沸腾的王水。但是氢溴酸微腐蚀铑,潮湿的碘和次氯酸钠也能腐蚀铑。

Product class
PGM Blacks


Chemical properties

Chemical formula

Rh

Empirical formula

Rh

Molecular weight

102.91

Metal

Rh

Theoretical metal content

95

Physical state

powder

Color
Metal purity

grey black

99.95

AI解读

名称和识别符

EC号 231-125-0
IUPAC Name rhodium
INCHI InChI=1S/Rh
InChi Key MHOVAHRLVXNVSD-UHFFFAOYSA-N
Canonical SMILES [Rh]
Isomeric SMILES [Rh]
WGK Germany 3
RTECS VI9069000
UN Number 3089
Packing Group II
分子量 102.91
Reaxy-Rn 4122948

化学和物理性质

密度 12.41
沸点 130° C at 1013 hPa
熔点 1966°C
分子量 102.905 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 0
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 102.905 Da
单同位素质量Monoisotopic Mass 102.905 Da
拓扑极表面积Topological Polar Surface Area 0.000 Ų
重原子数Heavy Atom Count 1
形式电荷Formal Charge 0
复杂度Complexity 0.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

象形图 GHS02
信号词 Warning
危险声明

H228: 易燃固体

预防措施声明

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P370+P378: 火灾时:使用干砂、干粉或抗醇泡沫灭火。

P210: 远离热源,热表面,火花,明火和其他点火源。 - 禁止抽烟。

P240: 地面/粘结容器和接收设备

P241: 使用防爆的[电气/通风/照明/.../]设备。

WGK Germany 3
RTECS VI9069000
Reaxy-Rn 4122948
Class 4.1
个人防护装备 Eyeshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RIDADR UN 3089 4.1 / PGII

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
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找到3个结果

批号(Lot Number) 证书类型 日期 货号
L2420107 分析证书 24-12-27 R109242
H2421030 分析证书 23-12-15 R109242
L2308037 分析证书 23-12-15 R109242

此产品的引用文献

1. Fei Peng, Jing Liu, Junjie Chen, Weiwei Wu, Yujun Zhang, Guoyan Zhao, Yi Kang, Deying Gong, Liu He, Jing Wang, Wensheng Zhang, Feng Qiu.  (2023)  Nanocrystals Slow-Releasing Ropivacaine and Doxorubicin to Synergistically Suppress Tumor Recurrence and Relieve Postoperative Pain.  ACS Nano,  17  (20): (20135–20152).  [PMID:37805931] [10.1021/acsnano.3c05831]
2. Wensheng Shen, Xiangrong Liu, Chen Shi, Jie Yang, Shunsheng Zhao, Zaiwen Yang, Dan Wang.  (2023)  Influences of Four Kinds of Surfactants on Biodegradations of Tar-Rich Coal in the Ordos Basin by Bacillus bicheniformis.  Microorganisms,  11  (10): (2397).  [PMID:37894055] [10.3390/microorganisms11102397]
3. Zongpeng Wang, Zhiping Lin, Yinglan Wang, Shijie Shen, Qinghua Zhang, Jiacheng Wang, Wenwu Zhong.  (2023)  Nontrivial Topological Surface States in Ru3Sn7 toward Wide pH-Range Hydrogen Evolution Reaction.  ADVANCED MATERIALS,  35  (25): (2302007).  [PMID:36994807] [10.1002/adma.202302007]
4. Jie Shi, Qintao Sun, Wenxiang Zhu, Tao Cheng, Fan Liao, Mengjie Ma, Junjun Yang, Hao Yang, Zhenglong Fan, Mingwang Shao.  (2023)  Lattice stain dominated hydrazine oxidation reaction in single-metal-element nanosheet.  CHEMICAL ENGINEERING JOURNAL,  463  (142385).  [10.1016/j.cej.2023.142385]
5. Chen Shi, Xiangrong Liu, Shun-Sheng Zhao, Zaiwen Yang.  (2023)  Additions of esterase and rhamnolipid promote the degradation of Inner Mongolia coal by Pseudomonas japonica.  FUEL,  340  (127640).  [10.1016/j.fuel.2023.127640]
6. Lulin Wang, Guangyi Li, Yu Cong, Aiqin Wang, Xiaodong Wang, Tao Zhang, Ning Li.  (2021)  Direct synthesis of a jet fuel range dicycloalkane by the aqueous phase hydrodeoxygenation of polycarbonate.  GREEN CHEMISTRY,  23  (10): (3693-3699).  [10.1039/D1GC00353D]
7. Shaoqi Yang, Guangming Cai, Xingmei Lu, Chenguang Wang, Mi Feng, Junli Xu, Qing Zhou, Jiayu Xin, Longlong Ma.  (2020)  Selective Deoxygenation of Lignin-Derived Phenols and Dimeric Ethers with Protic Ionic Liquids.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  59  (11): (4864–4871).  [10.1021/acs.iecr.9b05984]
8. Shihan Wang, Jinyu Dai, Zhiqiang Shi, Zeshan Xiong, Zongtao Zhang, Shilun Qiu, Runwei Wang.  (2020)  Hollow Nano-Mesosilica Spheres Containing Rhodium Nanoparticles Supported on Nitrogen-Doped Carbon: An Efficient Catalyst for the Reduction of Nitroarenes under Mild Conditions.  ChemPlusChem,  85  (1): (247-253).  [PMID:31950673] [10.1002/cplu.201900657]
9. Yan Yan, Qi Wang, Zeyang Xiang, Yanzhao Yang.  (2018)  Separation of Pt(IV), Pd(II), Ru(III), and Rh(III) from chloride medium using liquid–liquid extraction with mixed imidazolium-based ionic liquids.  SEPARATION SCIENCE AND TECHNOLOGY,  [10.1080/01496395.2018.1440304]
10. Lele Jin, Wenzhi Li, Qiying Liu, Jindong Wang, Yuanshuai Zhu, Zhenhang Xu, Xiangqian Wei, Qi Zhang.  (2018)  Liquefaction of kraft lignin over the composite catalyst HTaMoO6 and Rh/C in dioxane-water system.  FUEL PROCESSING TECHNOLOGY,  178  (62).  [10.1016/j.fuproc.2018.05.014]
11. Fuhai Li, Hanqin Weng, Yun Shang, Zuoming Ding, Zheng Yang, Sheng Cheng, Mingzhang Lin.  (2017)  Environmentally friendly and facile synthesis of Rh nanoparticles at room temperature by alkaline ethanol solution and their application for ethanol electrooxidation.  RSC Advances,  (6): (3161-3169).  [10.1039/C6RA26591J]
12. Jing Yang, Liang Zhao, Shaotong Liu, Yuanyuan Wang, Liyi Dai.  (2016)  High-quality bio-oil from one-pot catalytic hydrocracking of kraft lignin over supported noble metal catalysts in isopropanol system.  BIORESOURCE TECHNOLOGY,  212  (302).  [PMID:27123643] [10.1016/j.biortech.2016.04.029]
13. Meng-Yuan Chen, Yao-Bing Huang, Huan Pang, Xin-Xin Liu, Yao Fu.  (2015)  Hydrodeoxygenation of lignin-derived phenols into alkanes over carbon nanotube supported Ru catalysts in biphasic systems.  GREEN CHEMISTRY,  17  (3): (1710-1717).  [10.1039/C4GC01992J]
14. Lei Hu, Xing Tang, Jiaxing Xu, Zhen Wu, Lu Lin, Shijie Liu.  (2014)  Selective Transformation of 5-Hydroxymethylfurfural into the Liquid Fuel 2,5-Dimethylfuran over Carbon-Supported Ruthenium.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  53  (8): (3056–3064).  [10.1021/ie404441a]

参考文献

1. I Haiduc,C Silvestru.  (1989-07-01)  Rhodium, iridium, copper and gold antitumor organometallic compounds (review)..  In vivo (Athens, Greece),  ((4)): (285-293).  [PMID:2519867]
2. Jan Meine Ernsting,Sander Gaemers,Cornelis J Elsevier.  (2004-08-13)  103Rh NMR spectroscopy and its application to rhodium chemistry..  Magnetic resonance in chemistry : MRC,  42  ((9)): (721-736).  [PMID:15307053]
3. Kazuyuki Sato.  (2006-08-02)  [Development of new reactions of fluorine compounds using a rhodium catalyst]..  Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan,  126  ((8)): (597-605).  [PMID:16880718]
4. Jerzy Klosin,Clark R Landis.  (2007-11-14)  Ligands for practical rhodium-catalyzed asymmetric hydroformylation..  Accounts of chemical research,  40  ((12)): (1251-1259).  [PMID:17997526]
5. Vladimir V Grushin.  (2009-10-01)  The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination..  Accounts of chemical research,  43  ((1)): (160-171).  [PMID:19788304]
6. Huw M L Davies,Daniel Morton.  (2011-03-02)  Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes..  Chemical Society reviews,  40  ((4)): (1857-1869).  [PMID:21359404]
7. Feng Shi,Richard C Larock.  (2010-01-01)  Remote C-H activation via through-space palladium and rhodium migrations..  Topics in current chemistry,  292  (123-164).  [PMID:21500405]
8. Jean Bouffard,Kenichiro Itami.  (2010-01-01)  Rhodium-catalyzed C-H bond arylation of arenes..  Topics in current chemistry,  292  (231-280).  [PMID:21500409]
9. Raffaello Lazzaroni,Roberta Settambolo.  (2011-08-23)  Synthesis of indolizidines from optically pure α-amino acids via stereocontrolled rhodium-catalyzed hydroformylation of N-allylpyrroles..  Chirality,  23  ((9)): (730-735).  [PMID:21858877]
10. Nicolas P E Barry,Peter J Sadler.  (2012-02-07)  Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium: biological relevance and synthetic strategies..  Chemical Society reviews,  41  ((8)): (3264-3279).  [PMID:22307021]
11. Pablo Etayo,Anton Vidal-Ferran.  (2012-11-08)  Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs..  Chemical Society reviews,  42  ((2)): (728-754).  [PMID:23132556]
12. Simon Duttwyler,Shuming Chen,Michael K Takase,Kenneth B Wiberg,Robert G Bergman,Jonathan A Ellman.  (2013-02-09)  Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis..  Science (New York, N.Y.),  339  ((6120)): (678-682).  [PMID:23393259]
13. Gavin Chit Tsui,Nina M Ninnemann,Akihito Hosotani,Mark Lautens.  (2013-02-12)  Expedient synthesis of chiral oxazolidinone scaffolds via rhodium-catalyzed asymmetric ring-opening with sodium cyanate..  Organic letters,  15  ((5)): (1064-1067).  [PMID:23394120]
14. Nicolai Cramer.  (2013-02-12)  Teaching enantioselectivity to C-H bond functionalizations: initial steps of a rather long shot..  Chimia,  66  ((11)): (869-872).  [PMID:23394245]
15. Lei Ren,Xiao-Lei Lian,Liu-Zhu Gong.  (2013-02-13)  Brønsted acid/rhodium(II) cooperative catalytic asymmetric three-component aldol-type reaction for the synthesis of 3-amino oxindoles..  Chemistry (Weinheim an der Bergstrasse, Germany),  19  ((10)): (3315-3318).  [PMID:23401186]
16. Shengkun Li,Kexuan Huang,Jiwen Zhang,Wenjun Wu,Xumu Zhang.  (2013-02-16)  Cascade synthesis of fenpiprane and related pharmaceuticals via rhodium-catalyzed hydroaminomethylation..  Organic letters,  15  ((5)): (1036-1039).  [PMID:23410073]
17. Marcella Lemos Brettas Carneiro,Raphael C A Peixoto,Graziela A Joanitti,Ricardo G S Oliveira,Luis A M Telles,Ana L Miranda-Vilela,Anamélia L Bocca,Leonora M S Vianna,Izabel C R da Silva,Aparecido R de Souza,Zulmira G M Lacava,Sônia N Báo.  (2013-02-19)  Antitumor effect and toxicity of free rhodium (II) citrate and rhodium (II) citrate-loaded maghemite nanoparticles in mice bearing breast cancer..  Journal of nanobiotechnology,  11  (4-4).  [PMID:23414068]
18. Juliane Keilitz,Stephen G Newman,Mark Lautens.  (2013-02-21)  Enantioselective Rh-catalyzed domino transformations of alkynylcyclohexadienones with organoboron reagents..  Organic letters,  15  ((5)): (1148-1151).  [PMID:23421491]
19. Casi M Schienebeck,Patrick J Robichaux,Xiaoxun Li,Lianqing Chen,Weiping Tang.  (2013-02-26)  Effect of ester on rhodium-catalyzed intermolecular [5+2] cycloaddition of 3-acyloxy-1,4-enynes and alkynes..  Chemical communications (Cambridge, England),  49  ((26)): (2616-2618).  [PMID:23435501]
20. Angèle Monney,Flavia Nastri,Martin Albrecht.  (2013-02-27)  Peptide-tethered monodentate and chelating histidylidene metal complexes: synthesis and application in catalytic hydrosilylation..  Dalton transactions (Cambridge, England : 2003),  42  ((16)): (5655-5660).  [PMID:23440059]
21. Alex McSkimming,Mohan M Bhadbhade,Stephen B Colbran.  (2013-02-27)  Bio-inspired catalytic imine reduction by rhodium complexes with tethered Hantzsch pyridinium groups: evidence for direct hydride transfer from dihydropyridine to metal-activated substrate..  Angewandte Chemie (International ed. in English),  52  ((12)): (3411-3416).  [PMID:23441069]
22. Vutukuri Prakash Reddy,Renhua Qiu,Takanori Iwasaki,Nobuaki Kambe.  (2013-02-28)  Rhodium-catalyzed intermolecular oxidative cross-coupling of (hetero)arenes with chalcogenophenes..  Organic letters,  15  ((6)): (1290-1293).  [PMID:23441905]
23. Xinfang Xu,Xichen Xu,Peter Y Zavalij,Michael P Doyle.  (2013-02-28)  Dirhodium(II)-catalyzed formal [3+2+1]-annulation of azomethine imines with two molecules of a diazo ketone..  Chemical communications (Cambridge, England),  49  ((27)): (2762-2764).  [PMID:23443271]
24. Vera Marinova,Ren Chung Liu,Shiuan Huei Lin,Ming-Syuan Chen,Yi Hsin Lin,Ken Yuh Hsu.  (2013-03-05)  Near-infrared properties of Rh-doped Bi12TiO20 crystals for photonic applications..  Optics letters,  38  ((4)): (495-497).  [PMID:23455114]
25. Xian-Ying Shi,Chao-Jun Li.  (2013-03-09)  Synthesis of indene frameworks via rhodium-catalyzed cascade cyclization of aromatic ketone and unsaturated carbonyl compounds..  Organic letters,  15  ((7)): (1476-1479).  [PMID:23470191]
26. Stepan Chuprakov,Sen Wai Kwok,Valery V Fokin.  (2013-03-13)  Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes..  Journal of the American Chemical Society,  135  ((12)): (4652-4655).  [PMID:23477345]
27. Rakesh Kumar Gupta,Rampal Pandey,Gunjan Sharma,Ritika Prasad,Biplob Koch,Saripella Srikrishna,Pei-Zhou Li,Qiang Xu,Daya Shankar Pandey.  (2013-03-13)  DNA binding and anti-cancer activity of redox-active heteroleptic piano-stool Ru(II), Rh(III), and Ir(III) complexes containing 4-(2-methoxypyridyl)phenyldipyrromethene..  Inorganic chemistry,  52  ((7)): (3687-3698).  [PMID:23477351]
28. Yu Qian,Peter J Zavalij,Wenhao Hu,Michael P Doyle.  (2013-03-13)  Bicyclic pyrazolidinone derivatives from diastereoselective catalytic [3 + 3]-cycloaddition reactions of enoldiazoacetates with azomethine imines..  Organic letters,  15  ((7)): (1564-1567).  [PMID:23477672]
29. Brendan T Parr,Samantha A Green,Huw M L Davies.  (2013-03-13)  Rhodium-catalyzed conversion of furans to highly functionalized pyrroles..  Journal of the American Chemical Society,  135  ((12)): (4716-4718).  [PMID:23477809]
30. Inmaculada Arribas,Miguel Rubio,Patryk Kleman,Antonio Pizzano.  (2013-03-15)  Rhodium phosphine-phosphite catalysts in the hydrogenation of challenging N-(3,4-dihydronaphthalen-2-yl) amide derivatives..  The Journal of organic chemistry,  78  ((8)): (3997-4005).  [PMID:23485121]
31. Francois Grillet,Kay M Brummond.  (2013-03-15)  Enantioselective synthesis of 5,7-bicyclic ring systems from axially chiral allenes using a Rh(I)-catalyzed cyclocarbonylation reaction..  The Journal of organic chemistry,  78  ((8)): (3737-3754).  [PMID:23485149]
32. Wolfgang Kandioller,Evelyn Balsano,Samuel M Meier,Ute Jungwirth,Simone Göschl,Alexander Roller,Michael A Jakupec,Walter Berger,Bernhard K Keppler,Christian G Hartinger.  (2013-03-19)  Organometallic anticancer complexes of lapachol: metal centre-dependent formation of reactive oxygen species and correlation with cytotoxicity..  Chemical communications (Cambridge, England),  49  ((32)): (3348-3350).  [PMID:23505633]
33. Xiaocong Xie,Yi Li,Joseph M Fox.  (2013-03-22)  Selective syntheses of Δ(α,β) and Δ(β,γ) butenolides from allylic cyclopropenecarboxylates via tandem ring expansion/[3,3]-sigmatropic rearrangements..  Organic letters,  15  ((7)): (1500-1503).  [PMID:23514430]
34. P Andrew Evans,Phillip A Inglesby,Kathryn Kilbride.  (2013-04-02)  A concise total synthesis of pyrovellerolactone using a rhodium-catalyzed [(3 + 2) + 2] carbocyclization reaction..  Organic letters,  15  ((8)): (1798-1801).  [PMID:23540706]
35. Wei Hou,Bing Zhou,Yaxi Yang,Huijin Feng,Yuanchao Li.  (2013-04-09)  Rh(III)-catalyzed addition of alkenyl C-H bond to isocyanates and intramolecular cyclization: direct synthesis 5-ylidenepyrrol-2(5H)-ones..  Organic letters,  15  ((8)): (1814-1817).  [PMID:23560588]
36. Yicheng Xu,Yanhua Wang,Kaoxue Li,Mingming Niu,Yan Zeng,Jingyang Jiang,Zilin Jin.  (2013-08-02)  Rh nanoparticle catalyzed hydroaminomethylation of 1-octene in thermoregulated ionic liquid and organic biphasic system..  Journal of nanoscience and nanotechnology,  13  ((7)): (5048-5052).  [PMID:23901529]
37. Yi Dong,Gang Liu.  (2013-08-02)  Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes..  Chemical communications (Cambridge, England),  49  ((73)): (8066-8068).  [PMID:23903664]
38. Tao Wang,Xin-Qi Hao,Juan-Juan Huang,Jun-Long Niu,Jun-Fang Gong,Mao-Ping Song.  (2013-08-14)  Chiral bis(imidazolinyl)phenyl NCN pincer rhodium(III) catalysts for enantioselective allylation of aldehydes and carbonyl-ene reaction of trifluoropyruvates..  The Journal of organic chemistry,  78  ((17)): (8712-8721).  [PMID:23937230]
39. Ana Cajaraville,Susana López,Jesús A Varela,Carlos Saá.  (2013-08-24)  Rh(III)-catalyzed tandem C-H allylation and oxidative cyclization of anilides: a new entry to indoles..  Organic letters,  15  ((17)): (4576-4579).  [PMID:23968552]
40. Dongbing Zhao,Corinna Nimphius,Matthew Lindale,Frank Glorius.  (2013-08-27)  Phosphoryl-related directing groups in rhodium(III) catalysis: a general strategy to diverse P-containing frameworks..  Organic letters,  15  ((17)): (4504-4507).  [PMID:23971502]
41. Kathryn M Chepiga,Yan Feng,Nicholas A Brunelli,Christopher W Jones,Huw M L Davies.  (2013-11-21)  Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions..  Organic letters,  15  ((24)): (6136-6139).  [PMID:24251986]
42. Bing Zhou,Juanjuan Du,Yaxi Yang,Huijin Feng,Yuanchao Li.  (2013-11-28)  Rhodium-catalyzed direct addition of aryl C-H bonds to nitrosobenzenes at room temperature..  Organic letters,  15  ((24)): (6302-6305).  [PMID:24274057]
43. David M Guptill,Carolyn M Cohen,Huw M L Davies.  (2013-11-29)  Rhodium(II)-catalyzed stereoselective synthesis of allylsilanes..  Organic letters,  15  ((24)): (6120-6123).  [PMID:24283585]
44. Jing Zheng,Yan Zhang,Sunliang Cui.  (2014-06-25)  Rh(III)-catalyzed selective coupling of N-methoxy-1H-indole-1-carboxamides and aryl boronic acids..  Organic letters,  16  ((13)): (3560-3563).  [PMID:24959967]
45. Vania B Rezende,Fernando Barbosa,Ana C Palei,Ricardo C Cavalli,Jose E Tanus-Santos,Valeria C Sandrim.  (2014-07-24)  Correlations among antiangiogenic factors and trace elements in hypertensive disorders of pregnancy..  Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements (GMS),  29  (130-135).  [PMID:25053574]
46. Yang Chen,Ravinder M Reddy,Michael A McLaughlin,Fadwa Al-Taher,Ramesh R Yettella,Steffen Uhlig,Christian Bläul.  (2014-08-26)  Method validation and proficiency testing for determination of total arsenic in apple juice by inductively coupled plasma/ mass spectrometry..  Journal of AOAC International,  97  ((4)): (1143-1150).  [PMID:25145150]
47. Guorong Sheng,Kai Huang,Zhihao Chi,Hualong Ding,Yanpeng Xing,Ping Lu,Yanguang Wang.  (2014-09-12)  Preparation of 3-diazoindolin-2-imines via cascade reaction between indoles and sulfonylazides and their extensions to 2,3-diaminoindoles and imidazo[4,5-b]indoles..  Organic letters,  16  ((19)): (5096-5099).  [PMID:25211289]
48. Yang Yang,Yukako Komaki,Susana Y Kimura,Hong-Ying Hu,Elizabeth D Wagner,Benito J Mariñas,Michael J Plewa.  (2014-09-16)  Toxic impact of bromide and iodide on drinking water disinfected with chlorine or chloramines..  Environmental science & technology,  48  ((20)): (12362-12369).  [PMID:25222908]
49. Pablo E Guzmán,Yajing Lian,Huw M L Davies.  (2014-10-01)  Reversal of the regiochemistry in the rhodium-catalyzed [4+3] cycloaddition between vinyldiazoacetates and dienes..  Angewandte Chemie (International ed. in English),  53  ((48)): (13083-13087).  [PMID:25266984]
50. Hua-Dong Xu,Zhi-Hong Jia,Ke Xu,Hao Zhou,Mei-Hua Shen.  (2014-12-17)  One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay..  Organic letters,  17  ((1)): (66-69).  [PMID:25496025]
51. Songjie Yu,Boshun Wan,Xingwei Li.  (2014-12-18)  Rh(III)-catalyzed selenylation of arenes with selenenyl chlorides/diselenides via C-H activation..  Organic letters,  17  ((1)): (58-61).  [PMID:25515149]
52. Angela Kaltenbach,Janine Noordmann,Volker Görlitz,Carola Pape,Silke Richter,Heinrich Kipphardt,Gernot Kopp,Reinhard Jährling,Olaf Rienitz,Bernd Güttler.  (2014-12-19)  Gravimetric preparation and characterization of primary reference solutions of molybdenum and rhodium..  Analytical and bioanalytical chemistry,  407  ((11)): (3093-3102).  [PMID:25519725]
53. Clark R Landis.  (2015-01-03)  Organic chemistry. Construction and deconstruction of aldehydes by transfer hydroformylation..  Science (New York, N.Y.),  347  ((6217)): (29-30).  [PMID:25554776]
54. Malene Outzen,Anne Tjønneland,Erik H Larsen,Klaus K Andersen,Jane Christensen,Kim Overvad,Anja Olsen.  (2015-01-20)  The effect on selenium concentrations of a randomized intervention with fish and mussels in a population with relatively low habitual dietary selenium intake..  Nutrients,  ((1)): (608-624).  [PMID:25599275]
55. María Garrido,José Luis Abad,Gemma Fabriàs,Josefina Casas,Antonio Delgado.  (2015-02-14)  Azide-tagged sphingolipids: new tools for metabolic flux analysis..  Chembiochem : a European journal of chemical biology,  16  ((4)): (641-650).  [PMID:25676480]
56. Lung Wa Chung,W M C Sameera,Romain Ramozzi,Alister J Page,Miho Hatanaka,Galina P Petrova,Travis V Harris,Xin Li,Zhuofeng Ke,Fengyi Liu,Hai-Bei Li,Lina Ding,Keiji Morokuma.  (2015-04-09)  The ONIOM Method and Its Applications..  Chemical reviews,  115  ((12)): (5678-5796).  [PMID:25853797]
57. Andreas Reisch,Anne Runser,Youri Arntz,Yves Mély,Andrey S Klymchenko.  (2015-04-22)  Charge-controlled nanoprecipitation as a modular approach to ultrasmall polymer nanocarriers: making bright and stable nanoparticles..  ACS nano,  ((5)): (5104-5116).  [PMID:25894117]
58. Xiangyang Bi,Zhonggen Li,Guangyi Sun,Jinling Liu,Zhixuan Han.  (2015-05-11)  In vitro bioaccessibility of lead in surface dust and implications for human exposure: A comparative study between industrial area and urban district..  Journal of hazardous materials,  297  (191-197).  [PMID:25958267]
59. C Afonso,S Costa,C Cardoso,R Oliveira,H M Lourenço,A Viula,I Batista,I Coelho,M L Nunes.  (2015-05-13)  Benefits and risks associated with consumption of raw, cooked, and canned tuna (Thunnus spp.) based on the bioaccessibility of selenium and methylmercury..  Environmental research,  143  ((Pt B)): (130-137).  [PMID:25962922]
60. Anna V Vologzhanina,Alexander S Belov,Valentin V Novikov,Alexander V Dolganov,Galina V Romanenko,Victor I Ovcharenko,Alexander A Korlyukov,Mikhail I Buzin,Yan Z Voloshin.  (2015-05-29)  Synthesis and Temperature-Induced Structural Phase and Spin Transitions in Hexadecylboron-Capped Cobalt(II) Hexachloroclathrochelate and Its Diamagnetic Iron(II)-Encapsulating Analogue..  Inorganic chemistry,  54  ((12)): (5827-5838).  [PMID:26017024]
61. Thibault Cavey,Martine Ropert,Marie de Tayrac,Edouard Bardou-Jacquet,Marie-Laure Island,Patricia Leroyer,Claude Bendavid,Pierre Brissot,Olivier Loréal.  (2015-06-05)  Mouse genetic background impacts both on iron and non-iron metals parameters and on their relationships..  Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine,  28  ((4)): (733-743).  [PMID:26041486]
62. Kara Strickland,Elise Miner,Qingying Jia,Urszula Tylus,Nagappan Ramaswamy,Wentao Liang,Moulay-Tahar Sougrati,Frédéric Jaouen,Sanjeev Mukerjee.  (2015-06-11)  Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal-nitrogen coordination..  Nature communications,  (7343-7343).  [PMID:26059552]
63. D Sirbu,C Turta,E A Gibson,A C Benniston.  (2015-07-28)  The ferrocene effect: enhanced electrocatalytic hydrogen production using meso-tetraferrocenyl porphyrin palladium(II) and copper(II) complexes..  Dalton transactions (Cambridge, England : 2003),  44  ((33)): (14646-14655).  [PMID:26213204]
64. Dong Jin Lee,Donguk Ko,Eun Jeong Yoo.  (2015-09-18)  Rhodium(II)-Catalyzed Cycloaddition Reactions of Non-classical 1,5-Dipoles for the Formation of Eight-Membered Heterocycles..  Angewandte Chemie (International ed. in English),  54  ((46)): (13715-13718).  [PMID:26376924]
65. Scott R Pollack,David J Schenk.  (2015-09-19)  Site selective syntheses of [(3)H]omeprazole using hydrogen isotope exchange chemistry..  Journal of labelled compounds & radiopharmaceuticals,  58  ((11-12)): (433-441).  [PMID:26380956]
66. Chumin Zhao,Jerzy Kanicki,Anastasios C Konstantinidis,Tushita Patel.  (2015-11-02)  Large area CMOS active pixel sensor x-ray imager for digital breast tomosynthesis: Analysis, modeling, and characterization..  Medical physics,  42  ((11)): (6294-6308).  [PMID:26520722]
67. Yong-Qiang Kang,Qi Xue,Yue Zhao,Xi-Fei Li,Pu-Jun Jin,Yu Chen.  (2018-06-09)  Selective Etching Induced Synthesis of Hollow Rh Nanospheres Electrocatalyst for Alcohol Oxidation Reactions..  Small (Weinheim an der Bergstrasse, Germany),  (e1801239-e1801239).  [PMID:29882268]
68. N Katsaros,A Anagnostopoulou.  (2002-06-07)  Rhodium and its compounds as potential agents in cancer treatment..  Critical reviews in oncology/hematology,  42  ((3)): (297-308).  [PMID:12050021]
69. Andreja Bakac.  (2006-03-21)  Aqueous rhodium(III) hydrides and mononuclear rhodium(II) complexes..  Dalton transactions (Cambridge, England : 2003),  (13)  ((13)): (1589-1596).  [PMID:16547532]
70. Huw M L Davies,Simon J Hedley.  (2007-06-20)  Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids..  Chemical Society reviews,  36  ((7)): (1109-1119).  [PMID:17576478]
71. Denise A Colby,Robert G Bergman,Jonathan A Ellman.  (2009-05-15)  Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation..  Chemical reviews,  110  ((2)): (624-655).  [PMID:19438203]
72. Albert Padwa.  (2009-10-23)  Domino reactions of rhodium(II) carbenoids for alkaloid synthesis..  Chemical Society reviews,  38  ((11)): (3072-3081).  [PMID:19847342]
73. G Pótári,D Madarász,L Nagy,B László,A Sápi,A Oszkó,A Kukovecz,A Erdőhelyi,Z Kónya,J Kiss.  (2013-02-08)  Rh-induced support transformation phenomena in titanate nanowire and nanotube catalysts..  Langmuir : the ACS journal of surfaces and colloids,  29  ((9)): (3061-3072).  [PMID:23387804]
74. Kazunori Sakai,Takuya Kochi,Fumitoshi Kakiuchi.  (2013-02-13)  Rhodium-catalyzed intermolecular [2 + 2] cycloaddition of terminal alkynes with electron-deficient alkenes..  Organic letters,  15  ((5)): (1024-1027).  [PMID:23398205]
75. Erica E Schultz,Richmond Sarpong.  (2013-03-13)  Application of in situ-generated Rh-bound trimethylenemethane variants to the synthesis of 3,4-fused pyrroles..  Journal of the American Chemical Society,  135  ((12)): (4696-4699).  [PMID:23477843]
76. Marc Presset,Daniel Oehlrich,Frederik Rombouts,Gary A Molander.  (2013-03-19)  Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: preparation and use of 4-trifluoroboratotetrahydroisoquinolones..  Organic letters,  15  ((7)): (1528-1531).  [PMID:23496033]
77. Ji-Rong Huang,Qian-Ru Zhang,Chuan-Hua Qu,Xun-Hao Sun,Lin Dong,Ying-Chun Chen.  (2013-03-30)  Rhodium(III)-catalyzed direct selective C(5)-H oxidative annulations of 2-substituted imidazoles and alkynes by double C-H activation..  Organic letters,  15  ((8)): (1878-1881).  [PMID:23537406]
78. Jing Li,Justin S Cisar,Cong-Ying Zhou,Brunilda Vera,Howard Williams,Abimael D Rodríguez,Benjamin F Cravatt,Daniel Romo.  (2013-05-23)  Simultaneous structure-activity studies and arming of natural products by C-H amination reveal cellular targets of eupalmerin acetate..  Nature chemistry,  ((6)): (510-517).  [PMID:23695633]
79. Jingjing Wang,Sujing Zuo,Weiqiang Chen,Xinrui Zhang,Kaixin Tan,Yun Tian,Jianhui Wang.  (2013-06-08)  Catalytic formation of ketones from unactivated esters through rhodium chelation-assisted C-O bond activation..  The Journal of organic chemistry,  78  ((17)): (8217-8231).  [PMID:23742024]
80. Ramya Sambasivan,Zachary T Ball.  (2013-06-12)  Studies of asymmetric styrene cyclopropanation with a rhodium(II) metallopeptide catalyst developed with a high-throughput screen..  Chirality,  25  ((9)): (493-497).  [PMID:23749505]
81. Fen Wang,Zisong Qi,Jiaqiong Sun,Xuelin Zhang,Xingwei Li.  (2013-11-28)  Rh(III)-catalyzed coupling of benzamides with propargyl alcohols via hydroarylation-lactonization..  Organic letters,  15  ((24)): (6290-6293).  [PMID:24274184]
82. Tao Zhang,Lamei Wu,Xingwei Li.  (2013-11-28)  Rh(III)-catalyzed olefination of N-sulfonyl imines: synthesis of ortho-olefinated benzaldehydes..  Organic letters,  15  ((24)): (6294-6297).  [PMID:24279350]
83. Ming Zhou,Tang-Lin Liu,Min Cao,Zejian Xue,Hui Lv,Xumu Zhang.  (2014-06-17)  Highly enantioselective synthesis of chiral cyclic allylic amines via Rh-catalyzed asymmetric hydrogenation..  Organic letters,  16  ((13)): (3484-3487).  [PMID:24932772]
84. Stephen K Murphy,Jung-Woo Park,Faben A Cruz,Vy M Dong.  (2015-01-03)  Organic chemistry. Rh-catalyzed C-C bond cleavage by transfer hydroformylation..  Science (New York, N.Y.),  347  ((6217)): (56-60).  [PMID:25554782]
85. Fei Peng, Jing Liu, Junjie Chen, Weiwei Wu, Yujun Zhang, Guoyan Zhao, Yi Kang, Deying Gong, Liu He, Jing Wang, Wensheng Zhang, Feng Qiu.  (2023)  Nanocrystals Slow-Releasing Ropivacaine and Doxorubicin to Synergistically Suppress Tumor Recurrence and Relieve Postoperative Pain.  ACS Nano,  17  (20): (20135–20152).  [PMID:37805931] [10.1021/acsnano.3c05831]
86. Wensheng Shen, Xiangrong Liu, Chen Shi, Jie Yang, Shunsheng Zhao, Zaiwen Yang, Dan Wang.  (2023)  Influences of Four Kinds of Surfactants on Biodegradations of Tar-Rich Coal in the Ordos Basin by Bacillus bicheniformis.  Microorganisms,  11  (10): (2397).  [PMID:37894055] [10.3390/microorganisms11102397]
87. Zongpeng Wang, Zhiping Lin, Yinglan Wang, Shijie Shen, Qinghua Zhang, Jiacheng Wang, Wenwu Zhong.  (2023)  Nontrivial Topological Surface States in Ru3Sn7 toward Wide pH-Range Hydrogen Evolution Reaction.  ADVANCED MATERIALS,  35  (25): (2302007).  [PMID:36994807] [10.1002/adma.202302007]
88. Jie Shi, Qintao Sun, Wenxiang Zhu, Tao Cheng, Fan Liao, Mengjie Ma, Junjun Yang, Hao Yang, Zhenglong Fan, Mingwang Shao.  (2023)  Lattice stain dominated hydrazine oxidation reaction in single-metal-element nanosheet.  CHEMICAL ENGINEERING JOURNAL,  463  (142385).  [10.1016/j.cej.2023.142385]
89. Chen Shi, Xiangrong Liu, Shun-Sheng Zhao, Zaiwen Yang.  (2023)  Additions of esterase and rhamnolipid promote the degradation of Inner Mongolia coal by Pseudomonas japonica.  FUEL,  340  (127640).  [10.1016/j.fuel.2023.127640]
90. Lulin Wang, Guangyi Li, Yu Cong, Aiqin Wang, Xiaodong Wang, Tao Zhang, Ning Li.  (2021)  Direct synthesis of a jet fuel range dicycloalkane by the aqueous phase hydrodeoxygenation of polycarbonate.  GREEN CHEMISTRY,  23  (10): (3693-3699).  [10.1039/D1GC00353D]
91. Shaoqi Yang, Guangming Cai, Xingmei Lu, Chenguang Wang, Mi Feng, Junli Xu, Qing Zhou, Jiayu Xin, Longlong Ma.  (2020)  Selective Deoxygenation of Lignin-Derived Phenols and Dimeric Ethers with Protic Ionic Liquids.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  59  (11): (4864–4871).  [10.1021/acs.iecr.9b05984]
92. Shihan Wang, Jinyu Dai, Zhiqiang Shi, Zeshan Xiong, Zongtao Zhang, Shilun Qiu, Runwei Wang.  (2020)  Hollow Nano-Mesosilica Spheres Containing Rhodium Nanoparticles Supported on Nitrogen-Doped Carbon: An Efficient Catalyst for the Reduction of Nitroarenes under Mild Conditions.  ChemPlusChem,  85  (1): (247-253).  [PMID:31950673] [10.1002/cplu.201900657]
93. Yan Yan, Qi Wang, Zeyang Xiang, Yanzhao Yang.  (2018)  Separation of Pt(IV), Pd(II), Ru(III), and Rh(III) from chloride medium using liquid–liquid extraction with mixed imidazolium-based ionic liquids.  SEPARATION SCIENCE AND TECHNOLOGY,  [10.1080/01496395.2018.1440304]
94. Lele Jin, Wenzhi Li, Qiying Liu, Jindong Wang, Yuanshuai Zhu, Zhenhang Xu, Xiangqian Wei, Qi Zhang.  (2018)  Liquefaction of kraft lignin over the composite catalyst HTaMoO6 and Rh/C in dioxane-water system.  FUEL PROCESSING TECHNOLOGY,  178  (62).  [10.1016/j.fuproc.2018.05.014]
95. Fuhai Li, Hanqin Weng, Yun Shang, Zuoming Ding, Zheng Yang, Sheng Cheng, Mingzhang Lin.  (2017)  Environmentally friendly and facile synthesis of Rh nanoparticles at room temperature by alkaline ethanol solution and their application for ethanol electrooxidation.  RSC Advances,  (6): (3161-3169).  [10.1039/C6RA26591J]
96. Jing Yang, Liang Zhao, Shaotong Liu, Yuanyuan Wang, Liyi Dai.  (2016)  High-quality bio-oil from one-pot catalytic hydrocracking of kraft lignin over supported noble metal catalysts in isopropanol system.  BIORESOURCE TECHNOLOGY,  212  (302).  [PMID:27123643] [10.1016/j.biortech.2016.04.029]
97. Meng-Yuan Chen, Yao-Bing Huang, Huan Pang, Xin-Xin Liu, Yao Fu.  (2015)  Hydrodeoxygenation of lignin-derived phenols into alkanes over carbon nanotube supported Ru catalysts in biphasic systems.  GREEN CHEMISTRY,  17  (3): (1710-1717).  [10.1039/C4GC01992J]
98. Lei Hu, Xing Tang, Jiaxing Xu, Zhen Wu, Lu Lin, Shijie Liu.  (2014)  Selective Transformation of 5-Hydroxymethylfurfural into the Liquid Fuel 2,5-Dimethylfuran over Carbon-Supported Ruthenium.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  53  (8): (3056–3064).  [10.1021/ie404441a]

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