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在色谱分析、有机合成和交叉偶联反应领域已被 68 篇同行评审文献引用。
有α-和β-两种晶体。溶于氢氟酸。不溶于水。为共价键化合物,结合非常稳定。在空气中被加热至1450~1550℃时仍稳定。强度高。硬度大。硅粉在氮气氛中于高温下制得。也可由卤化硅与氨气经二氧化碳气激光束照射,生成无定形氮化硅,再在1450℃电炉、氮气氛中加热制得高纯度氮化硅粉末。 主要用作功能陶瓷材料原料,非铁金属的耐熔材料,飞机引擎,燃气输机喷嘴、轴承等高温结构材料和耐热涂层以及研磨、切削、电炉等的材料。
Silicon nitride based ceramics possess high fracture toughness, hardness and wear resistance, resistance to corrosion, thermal stability. Two known polymorphs of silicon nitride exist, alpha and beta Si3N4, both have hexagonal structure. A study shows that a third state, cubic spinel structure, has also been synthesized.
分类树(Taxonomy Tree)
| 界(kingdom) | 无机化合物 |
|---|---|
| 超类(Superclass) | 混合金属/非金属化合物 |
| 类(Class) | 类金属有机体 |
| 亚类(Subclass) | 准金属氮化物 |
| 中间层级节点(Intermediate Tree Nodes) | 暂无 |
| 直接上位类(Direct Parent) | 准金属氮化物 |
| 其他上位类(Alternative Parents) | 准金属盐 无机盐 无机氮化物 |
| 分子骨架(Molecular Framework) | 暂无 |
| 取代基(Substituents) | 无机类金属盐 - 无机氮化物 - 无机盐 - 类金属氮化物 |
| 描述(Description) | 该化合物属于类金属氮化物类无机化合物。这类化合物中氮的数式氧化态为-3,且最重金属原子为类金属元素。 |
| 外部描述符(External Descriptors) | 暂无 |
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| 2. Zehao Zhang, Xiang Liu, Youjun Lu, Haibo Li. (2023) Exploration of the lithium ions storage performance and mechanism of ZrN@reduced graphene oxide composite. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2023.170448] |
| 3. Zhou Yongjun, Zhang Yuanya, Liu Meng, Wang Yanling, Yuan Junya, Men Xuehu. (2023) Synergistically assembled RGO/Si3N4 whiskers hybrid aerogels to endow epoxy composites with excellent thermal and tribological performance. Friction, 11 (11): (2091-2106). [10.1007/s40544-022-0722-6] |
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| 8. Boshu Jiang, Bachirou Guene Lougou, Hao Zhang, Boxi Geng, Lianxuan Wu, Yong Shuai. (2022) Preparation and solar thermochemical properties analysis of NiFe2O4@SiC/ @Si3N4 for high-performance CO2-splitting. APPLIED ENERGY, [10.1016/j.apenergy.2022.120057] |
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| 15. Bing Liu, Chun-miao Du, Yong-zhen Zheng, Gui-yong Xiao, Chuan-zhong Chen, Yu-peng Lu. (2021) Improved microstructure and physiochemical properties of hopeite conversion coating by Si3N4 nanoparticles doping. Journal of Materials Research and Technology-JMR&T, [10.1016/j.jmrt.2021.09.083] |
| 16. Shengjun Liao, Lijuan Zhou, Changxi Jiang, Jianjun Wang, Yinghua Zhuang, Shuang Li. (2021) Thermal conductivity and mechanical properties of Si3N4 ceramics with binary fluoride sintering additives. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, [10.1016/j.jeurceramsoc.2021.07.035] |
| 17. Nannan Zhang, Daoping Xiang. (2021) Self-assembling of versatile Si3N4@SiO2 nanofibre sponges by direct nitridation of photovoltaic silicon waste. JOURNAL OF HAZARDOUS MATERIALS, [PMID:34175705] [10.1016/j.jhazmat.2021.126385] |
| 18. Rao Wei-dong, Liu Yao, Cheng Li-jing, Liu Shao-jun. (2021) Densification mechanism of stereolithographical dense Si3N4 ceramics with CeO2 as sintering additive by field assisted sintering. Journal of Central South University, 28 (4): (1233-1243). [10.1007/s11771-021-4631-z] |
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| 21. Ying-Nan Song, Mao-Qin Lei, Lu-Feng Deng, Jun Lei, Zhong-Ming Li. (2020) Hybrid Metamaterial Textiles for Passive Personal Cooling Indoors and Outdoors. ACS Applied Polymer Materials, [10.1021/acsapm.0c00234] |
| 22. Wenguang Jiang, Xiangguo Li, Yang Lv, Dongbing Jiang, Zhuolin Liu, Chenhao He. (2019) Mechanical and hydration properties of low clinker cement containing high volume superfine blast furnace slag and nano silica. CONSTRUCTION AND BUILDING MATERIALS, [10.1016/j.conbuildmat.2019.117683] |
| 23. Yong Dai, Han Guo, Linyang Chu, Zihao He, Minqi Wang, Shuhong Zhang, Xifu Shang. (2019) Promoting osteoblasts responses in vitro and improving osteointegration in vivo through bioactive coating of nanosilicon nitride on polyetheretherketone. Journal of Orthopaedic Translation, [PMID:33101971] [10.1016/j.jot.2019.10.011] |
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