基本描述

别名	叔丁基氯二甲基硅烷 \| 叔丁基(氯)二甲基硅烷
英文别名	TBDMCl \| TBDMSCl \| Tert-Butyldimethylsilyl chloride \| tert-Butyldimethylchlorosilane \| tert-Butylchlorodimethylsilane \| t-Butyldimethylchlorosilane \| TBDMS chloride \| tert-Butyl(chloro)dimethylsilane \| Silane, chloro(1,1-dimethylethyl)dimethyl- \| TBSCl \|
规格或纯度	≥97%
英文名称	tert-Butyldimethylsilyl chloride
应用	硅烷化剂。有机合成中作为羟基保护剂,衍生化试剂用于分析和制备。保护叔醇类。与醇类反应形成硅醚。测定胆固醇衍生物的构象。合成前列腺素，某些抗生素、降血脂药洛弗斯汀(Lovastatin)和新弗斯汀(Simvastatin)的辅助原料。胺、酰胺，尤其是醇的多功能保护试剂。在 t-BuPh2Si 保护醇存在的条件下，可被选择性除去。用于由 α-溴硝基烷制备异噁唑啉 N-氧化物。
储存温度	充氩
运输条件	常规运输
产品介绍	对湿敏感。易燃。有腐蚀性。和水反应，溶于醚和烃，和醇、有机酸和胺反应。硅烷化剂。有机合成中作为羟基保护剂,衍生化试剂用于分析和制备。保护叔醇类。与醇类反应形成硅醚。测定胆固醇衍生物的构象。合成前列腺素，某些抗生素、降血脂药洛弗斯汀(Lovastatin)和新弗斯汀(Simvastatin)的辅助原料。胺、酰胺，尤其是醇的多功能保护试剂。在 t-BuPh2Si 保护醇存在的条件下，可被选择性除去。用于由 α-溴硝基烷制备异噁唑啉 N-氧化物。 Versatile protecting reagent for amines, amides, and especially alcohols, among others.Can be selectively removed in the presence of a t-BuPh2Si-protected alcohol.Used in a preparatrion of isoxazoline N-oxides from α-bromonitroalkanes.

AI解读

名称和识别符

EC号	242-042-4
IUPAC Name	tert-butyl-chloro-dimethylsilane
INCHI	InChI=1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
InChi Key	BCNZYOJHNLTNEZ-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)[Si](C)(C)Cl
Isomeric SMILES	CC(C)(C)[Si](C)(C)Cl
WGK Germany	2
RTECS	VV2000000
PubChem CID	28928
UN Number	2925
分子量	150.72
Beilstein号	505999
Reaxy-Rn	505999

化学和物理性质

溶解性	Soluble in chloroform and ethyl acetate. Insoluble in water.
密度	0.87
敏感性	对湿度敏感
闪点(℉)	71.6 °F
闪点(℃)	22℃
沸点	125°C
熔点	89°C
分子量	150.720 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	150.063 Da
单同位素质量Monoisotopic Mass	150.063 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	8
形式电荷Formal Charge	0
复杂度Complexity	81.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS05, GHS07, GHS02
信号词	Danger
危险声明	H335: 可能引起呼吸道刺激 H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤 H228: 易燃固体
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	2
RTECS	VV2000000
Reaxy-Rn	505999

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