氯化钯

规格或纯度: Pd 59-60%

CAS编号: 7647-10-1
分子式: PdCl₂
分子量: 177.33
EC号: 231-115-6
MDL号: MFCD00003558
PubChem编号: 24290

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货号 (SKU)	包装规格	是否现货
P105196-500mg	500mg	现货
P105196-1g	1g	现货
P105196-5g	5g	现货
P105196-25g	25g	现货

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元素分类的化合物钯催化剂

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基本描述

别名	氯化钯(II)\|PdCl2\|二氯化钯
英文别名	Palladium(II) chloride\|Palladium chloride\|7647-10-1\|Dichloropalladium\|Palladium dichloride\|Palladous chloride\|Palladium (II) chloride\|PdCl2\|Palladium(2+) chloride\|Cl2Pd\|Enplate activator 440\|Palladium chloride (PdCl2)\|Palladium II Chloride\|NCI-C60184\|CCRI
规格或纯度	Pd 59-60%
英文名称	Palladium chloride
法律信息	Product of Umicore
储存温度	充氩
运输条件	常规运输
产品介绍	有潮解性，易溶于稀盐酸，能溶于水、乙醇、丙酮和氢溴酸。 1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。 2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。 3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。 4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。 Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol. Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1 Product class PGM Solids, Chlorides Reaction type Cross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Oxidation Chemical properties Chemical formula Cl2Pd Empirical formula PdCl2 Molecular weight 177.31 Metal Pd Theoretical metal content 60 Physical state powder Color red brown Applications & references Efficient oxidative carboxylation of benzylic C-H bonds via nondirected C(sp³)-H activation forming substituted 2-phenylacetic acid esters and derivatives starting from inexpensive, commercially available starting materials. Reference: J. Am. Chem. Soc. 2012, 134, 9902 (DOI: 10.1021/ja3036459) Efficient Palladium catalyzed hydroformylation of aryl and enol trifluoromethanesulfonates providing α,β-unsaturated aldehydes. Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246) Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups. Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

名称和标识符

EC号	231-115-6
IUPAC Name	dichloropalladium
INCHI	InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChi Key	PIBWKRNGBLPSSY-UHFFFAOYSA-L
Canonical SMILES	Cl[Pd]Cl
Isomeric SMILES	Cl[Pd]Cl
PubChem CID	24290
UN Number	3290
Packing Group	I
分子量	177.33

化学和物理性质

溶解性	Soluble in dilute mineral acids, aqueous metal halides
密度	1.06
敏感性	易吸潮
沸点	2970°C
熔点	678-680 °C

安全和危险性（GHS）

象形图	Harmful
信号词	Warning
危险声明	H319: Causes serious eye irritation H317: May cause an allergic skin reaction H303: May be harmful if swallowed H316: Causes mild skin irritation
预防措施声明	P261,P501,P264
Class	6.1, 8
Merck Index	6990
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

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参考文献

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氯化钯

库存信息

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全和危险性（GHS）

质检证书(COA)

质检报告(COA)

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