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2-氯-4,6-二甲氧基-1,3,5-三嗪

规格或纯度: 97%
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货号 (SKU) 包装规格 是否现货 价格 数量
C123027-5g
 5g 现货 Stock Image
C123027-25g
 25g 现货 Stock Image
C123027-100g
 100g 现货 Stock Image
C123027-500g
 500g 现货 Stock Image
C123027-1kg
 1kg 期货 Stock Image
C123027-2.5kg
 2.5kg 现货 Stock Image
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三嗪类 卤代杂环砌块
main product photo

基本描述

英文别名 2-Chloro-4,6-dimethoxy-1,3,5-triazine|3140-73-6|CDMT|1,3,5-Triazine, 2-chloro-4,6-dimethoxy-|MFCD00075607|6KB2H8FE5Q|2-CHLORO-4,6-DIMETHOXY-S-TRIAZINE|NSC-46520|2-Chloro-4,6-dimethoxy-[1,3,5]triazine|2-Chloro-4,6-dimethoxy-1,3,5-triazine (CDMT)|NSC46520|E
规格或纯度 97%
英文名称 2-Chloro-4,6-dimethoxy-1,3,5-triazine
储存温度 充氩
运输条件 常规运输
备注 5g卖完停产，不再备货
产品介绍

产品介绍

2-氯-4,6-二甲氧基-1,3,5-三嗪是一种稳定但高度活性的肽偶联剂。它被报道为多肽纯化的有效偶联试剂。已报道 2-氯-4,6-二甲氧基-1,3,5-三嗪的催化酰胺化反应。已报道制备多千克 2-氯-4,6-二甲氧基-1,3,5-三嗪的方法。


用途
2-氯-4,6-二甲氧基-1,3,5-三嗪可用于以下研究：
• 亲和标记的模块化方法 (MoAL) 对链霉亲和素的特异性标记。
• 通过与 2-羟基-4,6-二甲氧基-1,3,5-三嗪-2-基）醚反应制备双（4,6-二甲氧基-1,3,5-三嗪-2-基）醚。
• 通过与多种叔胺反应制备 2-（4,6-二甲氧基-1,3,5-三嗪基）三烷基铵盐。
• 在四氢呋喃中与 N -甲基吗啉偶联合成 4-（4,6-二甲氧基-1,3,5-三嗪-2-基）-4-甲基吗啉氯化物。
一种稳定并且具高反应性的肽偶联剂。

Product Introduction

2-chloro-4,6-dimethoxy-1,3,5-triazine is a stable but highly active peptide coupling agent. It has been reported as an effective coupling reagent for peptide purification. The amidation of 2-chloro-4,6-dimethoxy-1,3,5-triazine has been reported. A method for the preparation of multi kilogram 2-chloro-4,6-dimethoxy-1,3,5-triazine has been reported.


Application

2-chloro-4,6-dimethoxy-1,3,5-triazine can be used in the following studies

· specific labeling of streptavidin by moal.

· bis (4,6-dimethoxy-1,3,5-triazine-2-yl) ether was prepared by reaction with 2-hydroxy-4,6-dimethoxy-1,3,5-triazine-2-yl) ether.

Preparation of 2 - (4,6-dimethoxy-1,3,5-triazinyl) trialkylammonium salt by reaction with various tertiary amines.

4 - (4,6-dimethoxy-1,3,5-triazin-2-yl) - 4-methylmorpholine chloride was synthesized by coupling with N-Methylmorpholine in tetrahydrofuran.

A stable and highly reactive peptide coupling agent.

名称和标识符

PubChem SID 488182473
EC号 221-541-0
IUPAC Name 2-chloro-4,6-dimethoxy-1,3,5-triazine
INCHI InChI=1S/C5H6ClN3O2/c1-10-4-7-3(6)8-5(9-4)11-2/h1-2H3
InChi Key GPIQOFWTZXXOOV-UHFFFAOYSA-N
Canonical SMILES COC1=NC(=NC(=N1)Cl)OC
Isomeric SMILES COC1=NC(=NC(=N1)Cl)OC
WGK Germany 3
关联CAS 3140-73-6
PubChem CID 18450
NSC Number 46520
MeSH Entry Terms 4-chloro-methandienone;CDMT;D-4-chloro-17 beta-hydroxy-3-oxo-17 alpha-methylandrosta-1,4-diene;dehydrochlormethyltestosterone;Oral Turinabol;Turinabol-oral
分子量 175.57
Beilstein号 148988
Reaxy-Rn 148988

化学和物理性质

溶解性 Soluble in water, chloroform and methanol.
敏感性 易吸潮
沸点 99-100°C/1mmHg
熔点 76.0-80.0°C

安全和危险性（GHS）

象形图
ghs09

Environmental Hazard

ghs05

Corrosive

ghs07

Harmful
信号词 Danger
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H411: Toxic to aquatic life with long lasting effects
H302: Harmful if swallowed
H318: Causes serious eye damage
H317: May cause an allergic skin reaction
预防措施声明 P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P272,P333+P313,P362+P364,P391,P330,P264+P265,P301+P317,P305+P354+P338,P317,P337+P317,P332+P317,P319
WGK Germany 3
Reaxy-Rn 148988
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

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参考文献

1. Shuichi Nakanishi,Hiroyuki Tanaka,Kazuhito Hioki,Kohei Yamada,Munetaka Kunishima.  (2010-10-16)  Labeling study of avidin by modular method for affinity labeling (MoAL)..  Bioorganic & medicinal chemistry letters,  20  ((23)):  (7050-7053).  [PMID:20947347]
2. Munetaka Kunishima,Daiki Kato,Shuichi Nakanishi,Masanori Kitamura,Kohei Yamada,Keiji Terao,Tomoya Asano.  (2014-11-05)  Specific labeling of streptavidin for better understanding of ligand modification in modular method for affinity labeling (MoAL)..  Chemical & pharmaceutical bulletin,  62  ((11)):  (1146-1150).  [PMID:25366318]
3. Ahmed M Shabana,Utpal K Mondal,Md Raqibul Alam,Taylor Spoon,Codee Alicia Ross,Muniswamy Madesh,Claudiu T Supuran,Marc A Ilies.  (2018-05-08)  pH-Sensitive Multiligand Gold Nanoplatform Targeting Carbonic Anhydrase IX Enhances the Delivery of Doxorubicin to Hypoxic Tumor Spheroids and Overcomes the Hypoxia-Induced Chemoresistance..  ACS applied materials & interfaces,  10  ((21)):  (17792-17808).  [PMID:29733576]
4. Benedetta Del Secco,Luca Ravotto,Tatiana V Esipova,Sergei A Vinogradov,Damiano Genovese,Nelsi Zaccheroni,Enrico Rampazzo,Luca Prodi.  (2019-04-24)  Optimized synthesis of luminescent silica nanoparticles by a direct micelle-assisted method..  Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology,  18  ((9)):  (2142-2149).  [PMID:31011734]
5. Dmitry V Klinov,Anna D Protopopova,Dmitry S Andrianov,Rustem I Litvinov,John W Weisel.  (2020-08-26)  An Improved Substrate for Superior Imaging of Individual Biomacromolecules with Atomic Force Microscopy..  Colloids and surfaces. B, Biointerfaces,  196  ():  (111321-111321).  [PMID:32841787]
6. Munetaka Kunishima,Takae Ujigawa,Yoshie Nagaoka,Chiho Kawachi,Kazuhito Hioki,Motoo Shiro.  (2012-10-13)  Study on 1,3,5-triazine chemistry in dehydrocondensation: gauche effect on the generation of active triazinylammonium species..  Chemistry (Weinheim an der Bergstrasse, Germany),  18  ((49)):  (15856-15867).  [PMID:23059753]
7. Konrad Jastrzabek,Przemyslaw Bednarek,Beata Kolesinska,Zbigniew J Kaminski.  (2013-05-18)  Bis(4,6-dimethoxy-1,3,5-triazin-2-yl) ether as coupling reagent for peptide synthesis..  Chemistry & biodiversity,  10  ((5)):  (952-961).  [PMID:23681736]
8. Tatiana V Esipova,Matthew J P Barrett,Eva Erlebach,Artëm E Masunov,Bruno Weber,Sergei A Vinogradov.  (2019-01-29)  Oxyphor 2P: A High-Performance Probe for Deep-Tissue Longitudinal Oxygen Imaging..  Cell metabolism,  29  ((3)):  (736-744).  [PMID:30686745]
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