1-丁基-3-甲基咪唑六氟磷酸盐(BMIMPF6)

概述规格名称和识别符技术文档高级数据系统学分类三维结构质检证书（CoA,COO,BSE/TSE 和分析图谱) 化学和物理性质安全和危险性（GHS）此产品的引用文献技术文档和文章引用文献溶液计算器常见问题

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为什么选择此级别

提供 ≥97% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。

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储存与运输

室温,充氩,干燥。常规运输。请查阅批次 COA 获取详细规格。

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质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 108 篇同行评审文献引用。

概述

产品介绍
丁基-3-甲基咪唑六氟磷酸盐是一种基于咪唑的疏水性室温离子液体 (RTIL)。可由 1-甲基咪唑与氯丁烷反应制得。气态氢氟碳化合物 (HFCs) 如氟甲烷、氟乙烷和 1,1,2,2-四氟乙烷可溶于 BMIMPF 6离子液体,用在许多环保型的反应中。

用途
离子液体,用在许多环保型的反应中。 1-丁基-3-甲基咪唑六氟磷酸盐是一种在许多环保型反应中使用的离子液体。它也可以作为反应的介质，例如：二烯和烯炔底物在新型可回收钌卡宾配合物存在下的关环复分解反应。乙酰丙酮镍 (II) 催化芳香醛氧化为相应的的酸，氧化剂为双氧水。脂肪酶催化烯丙醇的对映选择性酰化反应。用四烯丙基锡烷对醛进行烯丙基化，生成高烯丙基醇。

1-Butyl-3-methylimidazolium hexafluorophosphate is a high-purity ionic liquid (HPIL) with low water and halogen content, which makes it an effective solvent for transition-metal-catalyzed reactions. Some of its other advantageous properties include hydrophobicity and lack of vapor pressure. 1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL).It can be prepared by reacting 1-methylimidazole with chlorobutane.Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6
Ionic liquid employed in many environmentally friendly reactions

规格

别名

1-丁基-3-甲基六氟磷酸盐咪唑鎓 | 1-正-丁基-3-甲基咪唑鎓六氟磷酸盐

英文别名

1-Butyl-3-methylimidazolium hexafluorophosphate, for catalysis, >=98.5% (T) | 1-n-Butyl-3-methylimidazolium hexafluorophosphate | 1-Butyl-3-methylimidazolium hexafluorophosphate | DTXCID7027887 | 1-Butyl-3-methyl-1H-imidazol-3-iumhexafluorophosphate(V) |

规格或纯度

≥97%

英文名称

BMIMPF6

储存条件

室温,充氩,干燥

运输条件

常规运输

纯度

≥97%

名称和识别符

PubChem SID

488192495

EC号

678-095-9

分子类型

小分子

IUPAC Name

1-butyl-3-methylimidazol-3-ium;hexafluorophosphate

INCHI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

InChi Key

IXQYBUDWDLYNMA-UHFFFAOYSA-N

Smiles

CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F

Isomeric SMILES

CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F

PubChem CID

2734174

分子量

284.18

Reaxy-Rn

8026031

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

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✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

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📊 产品数据表

产品规格和应用的快速参考摘要。

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🔬 规格说明书

该级别的完整质量属性和验收标准。

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高级数据

系统学分类

分类树（Taxonomy Tree）

界（kingdom) 有机化合物
- 超类（Superclass) 有机杂环化合物
  - 类（Class) 唑类
    - 亚类（Subclass）咪唑类
      - 第5级 (level 5) 取代咪唑
        第6级 (level 6) N-取代咪唑

界（kingdom)	有机化合物
超类（Superclass)	有机杂环化合物
类（Class)	唑类
亚类（Subclass）	咪唑类
中间层级节点（Intermediate Tree Nodes）	取代咪唑
直接上位类(Direct Parent)	N-取代咪唑
其他上位类（Alternative Parents）	杂芳族化合物氮杂环化合物有机光子化合物有机氮化合物有机盐碳氢化合物衍生物
分子骨架（Molecular Framework)	芳香族杂单环化合物
取代基（Substituents）	芳香族杂单环化合物 - 氮杂环 - 杂芳香族化合物 - 烃衍生物 - N-取代咪唑 - 有机硝基化合物 - 有机盐 - 有机氮化合物 - 有机氮化合物
描述（Description）	该化合物属于有机化合物中的N-取代咪唑类。这类杂环化合物在咪唑环1位存在取代基。
外部描述符（External Descriptors）	暂无

三维结构

交互式化学结构模型

球棍
棍棒
线框模型
空间填充
显示氢气
动画

化学和物理性质

溶解性

Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.

密度

1.38

敏感性

易吸潮

折光率

1.411

沸点

>350°C

熔点

6.5°C

分子量

284.180 g/mol

XLogP3

氢键供体数Hydrogen Bond Donor Count

氢键受体数Hydrogen Bond Acceptor Count

可旋转键计数Rotatable Bond Count

精确质量Exact Mass

284.088 Da

单同位素质量Monoisotopic Mass

284.088 Da

拓扑极表面积Topological Polar Surface Area

8.800 Å²

重原子数Heavy Atom Count

形式电荷Formal Charge

复杂度Complexity

156.000

同位素原子数Isotope Atom Count

定义的原子立体中心计数Defined Atom Stereocenter Count

未定义的原子立体中心计数Undefined Atom Stereocenter Count

定义的键立体中心计数Defined Bond Stereocenter Count

未定义的键立体中心计数Undefined Bond Stereocenter Count

所有立体化学键的总数The total count of all stereochemical bonds

共价键合单元计数Covalently-Bonded Unit Count

安全和危险性（GHS）

象形图

GHS07

信号词

警告

危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激

预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理（请参阅此标签上的...）。

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P337+P317: 如果眼睛刺激持续：寻求医疗帮助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。

WGK Germany

Merck Index

1581

个人防护装备

Eyeshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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找到55个结果

批号(Lot Number)	证书类型	货号
A2622250	分析证书	B107646
A2622251	分析证书	B107646
A2622249	分析证书	B107646
H2617049	分析证书	B107646
F2601132	分析证书	B107646
H2508024	分析证书	B107646
F2527275	分析证书	B107646
F2527281	分析证书	B107646
F2530366	分析证书	B107646
D2516355	分析证书	B107646
D2516354	分析证书	B107646
D2516353	分析证书	B107646
D2516352	分析证书	B107646
L2418636	分析证书	B107646
L2418623	分析证书	B107646
L2418630	分析证书	B107646
L2418635	分析证书	B107646
I2425134	分析证书	B107646
I2425133	分析证书	B107646
I2425132	分析证书	B107646
G2424185	分析证书	B107646
G2424184	分析证书	B107646
G2424183	分析证书	B107646
G2429159	分析证书	B107646
G2429158	分析证书	B107646
G2429157	分析证书	B107646
G2429156	分析证书	B107646
G2409231	分析证书	B107646
G2409230	分析证书	B107646
G2409232	分析证书	B107646
G2409233	分析证书	B107646
D2429165	分析证书	B107646
D2429164	分析证书	B107646
D2429151	分析证书	B107646
D2429149	分析证书	B107646
D2429150	分析证书	B107646
D2417002	分析证书	B107646
L2318347	分析证书	B107646
L2318348	分析证书	B107646
L2318440	分析证书	B107646
C2303406	分析证书	B107646
L2301161	分析证书	B107646
C2303402	分析证书	B107646
C2303407	分析证书	B107646
C2303450	分析证书	B107646
C2303410	分析证书	B107646
C2303409	分析证书	B107646
C2303408	分析证书	B107646
I2202267	分析证书	B107646
G2307557	分析证书	B107646
I2202266	分析证书	B107646
I2202265	分析证书	B107646
B2223300	分析证书	B107646
B2223296	分析证书	B107646
B2223275	分析证书	B107646

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技术文档和文章

戴斯-马丁试剂（DMP）

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探索主题:

化学合成氧化剂 DMP 戴斯-马丁氧化

2-碘酰基苯甲酸 (IBX)

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氧化剂有机反应工具箱氧化反应高价碘试剂 IBX

2-Iodylbenzoic Acid (IBX)

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探索主题:

Organic Reaction Toolbox Oxidation Reagents Oxidation Reaction IBX Hypervalent Iodine

离子液体是什么：核心概念、应用地图与选型工作流（附阿拉丁代表产品分类汇总表）

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离子液体 ILs

What Are Ionic Liquids? Core Concepts, Application Map, and a Selection Workflow (with a Summary Table of Representative Aladdin Product Categories)

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Ionic liquids ILs

咪唑类杂环构件的调控逻辑：双氮位点与取代/盐型/并环如何调控电荷、氢键与配位（附表A–E）

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Tuning Logic of Imidazole Heteroaromatic Building Blocks: How Dual Nitrogen Sites and Substitution / Salt Forms / Ring Fusion Modulate Charge, Hydrogen Bonding, and Coordination (with Tables A–E)

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Dess-Martin periodinane (DMP)

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Chemical synthesis OxidizingAgents DMP Dess-MartinOxidation

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站? 引用文献检索

引用文献

1. Wen Deng, Chengcheng Yang, Mengting Gong, Zhaohui Zhang, Hui Li. (2023) Preparation of rutin imprinted monolith (RIM) by using porogen containing ion liquid [BMIM]PF6 and its molecular recognition. JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, [PMID:38181708] [10.1016/j.jchromb.2023.123986]
2. Ju Wang, Jun-Qin Qiao, Wei-Juan Zheng, Hong-Zhen Lian. (2023) Effect of ionic liquids as mobile phase additives on retention behaviors of G-quadruplexes in reversed-phase high performance liquid chromatography. JOURNAL OF CHROMATOGRAPHY A, [PMID:38176351] [10.1016/j.chroma.2023.464604]
3. Yan Gao, Shumin Zhao, Miao Yan, Yongxia Li, Jianshe Zhao. (2023) High efficiency extraction oxidation desulfurization of model liquid fuel catalyzed by MIL-101(Fe) supported peroxo-polyoxometalates. MICROPOROUS AND MESOPOROUS MATERIALS, [10.1016/j.micromeso.2023.112857]
4. Qiang Sun, Jia Xiong, Hongxia Gao, Wilfred Olson, Zhiwu Liang. (2023) Energy-efficient regeneration of amine-based solvent with environmentally friendly ionic liquid catalysts for CO2 capture. CHEMICAL ENGINEERING SCIENCE, [10.1016/j.ces.2023.119380]
5. Gao Qiuyue, Li Guoru, Kofie Gideon, Chen Biaohua, Yin Fengxiang. (2023) Ionic liquid/ZIF-67 derived Co9S8-SNC catalyst for oxygen reduction reaction in alkaline electrolyte. Carbon Letters, [10.1007/s42823-023-00622-z]
6. Xingyun Gao, Yongzhen Wang, Mengjie Wu, Chao Zhi, Jiaguang Meng, Lan Zhang. (2023) Multicolor electrochromic fabric with a simple structure of PEDOT:PSS/DMSO. DYES AND PIGMENTS, [10.1016/j.dyepig.2023.111642]
7. Xiaofeng Lai, Song Wang, Ying Xie, Binghang Liu, Jianhui Sun, Yuxin Li, Haitao Yu, Kai Pan. (2023) Recycling and Recovery of Deactivated CsPbBr3 Perovskite after Photocatalytic CO2 Reduction Reaction. ACS Applied Materials & Interfaces, [PMID:37403581] [10.1021/acsami.3c07922]
8. Yuxiu Fu, Xiaoli Song, Yaming Pang, Yinan Zheng, Liguo Gao. (2023) Extraction of quinoline from toluene solution of wash oil using 1‑butyl‑3-methylimidazolium hexafluorophosphate ([BMIM] [PF6]): Experimental and molecular dynamics simulations. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2023.136000]
9. Kang Yang, Yongping Niu, Yang Li, Xiaowei Wang, Sanming Du, Yongzhen Zhang. (2023) Preparation of double-core microcapsules and tribological properties of epoxy composites. TRIBOLOGY INTERNATIONAL, [10.1016/j.triboint.2023.108597]
10. Xiangfei Xiao, Haidong Zhao, Penji Yan, Hengfei Zhang, Xinghuan Liu, Xin Jia, Shuping Jin. (2023) A sticky, thermal tolerant, tough BP@PVP ionogel for epidermal sensors. Journal of Materials Chemistry C, 11 (20): (6616-6626). [10.1039/D3TC00978E]
11. Yan Gao, Yu Chen, Cuiying Wang, Aiping Yin, Hailong Li, Jianshe Zhao. (2023) Polyoxometalates Encapsulated into Hollow Periodic Mesoporous Organosilica as Nanoreactors for Extraction Oxidation Desulfurization. Catalysts, 13 (4): (747). [10.3390/catal13040747]
12. Yue Shen, Chun Chen, Zidan Zou, Zhi Hu, Zhen Fu, Wenchao Li, Shenglong Pan, Yunxia Zhang, Haimin Zhang, Zhixin Yu, Huijun Zhao, Guozhong Wang. (2023) Geometric and electronic effects of Co@NPC catalyst in chemoselective hydrogenation: Tunable activity and selectivity via N,P co-doping. JOURNAL OF CATALYSIS, [10.1016/j.jcat.2023.03.013]
13. Tian Xiuzhi, Bai Haozhe, Chen Ting, Sang Shen, Deng Haibo, Jiang Xue. (2023) Poly(lactic acid)/poly (butylene succinate)/boron nitride nanosheet composites with high thermal conductivity: a novel biodegradable electronic packaging material. POLYMER BULLETIN, 80 (12): (13243-13261). [10.1007/s00289-023-04689-6]
14. Xiaojing Lv, Haofei Xu, Yuanyuan Yang, Mi Ouyang, Minao Xia, Chunyan Liu, Dominic S. Wright, Cheng Zhang. (2023) Flexible laterally-configured electrochromic supercapacitor with feasible patterned display. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2023.141453]
15. Xiaochun Deng, Xueting Lin, Huaxu Zhou, Jiyang Liu, Hongliang Tang. (2023) Equipment of Vertically-Ordered Mesoporous Silica Film on Electrochemically Pretreated Three-Dimensional Graphene Electrodes for Sensitive Detection of Methidazine in Urine. Nanomaterials, 13 (2): (239). [PMID:36677991] [10.3390/nano13020239]
16. Wenqing Wang, Hao Li, Xinmin Ma, Jianming Pan. (2022) Construction of ionic liquid-filled silica shell microcapsules based on emulsion template and evaluation of their adsorption properties toward 3,4,5-trichlorophenol after various surface functionalization. SEPARATION AND PURIFICATION TECHNOLOGY, [10.1016/j.seppur.2022.123020]
17. Yaoyao Zhu, Liling Wang, Meixu Chen, Yifeng Zhou, Jun Huang. (2022) Simultaneous Extraction and Determination of Characteristic Steroidal Saponins and Homoisoflavonoids in Zhejiang Ophiopogon japonicus. MOLECULES, 27 (21): (7380). [PMID:36364204] [10.3390/molecules27217380]
18. Zheng Weiran, Su Ruobing, Lin Xingyu, Liu Jiyang. (2022) Nanochannel array modified three-dimensional graphene electrode for sensitive electrochemical detection of 2,4,6-trichlorophenol and prochloraz. Frontiers in Chemistry, [PMID:36157037] [10.3389/fchem.2022.954802]
19. Junyuan Hua, Xiaohua Ma, Wenhui Ji, Quan Li, Benqiao He, Zhenyu Cui, Xiaoping Liang, Feng Yan, Jianxin Li. (2022) Unveiling the mechanism of liquid-liquid extraction separation of Li+/Mg2+ using tributyl phosphate/ionic liquid mixed solvents. JOURNAL OF MOLECULAR LIQUIDS, [10.1016/j.molliq.2022.120080]
20. Yan Gao, Miao Yan, Jianshe Zhao. (2022) Metal–organic framework (UIO-66-NH2)-encapsulated peroxophosphotungstate (PW4) loaded on graphene oxide (GO) as catalyst for desulfurization of fuel. MICROPOROUS AND MESOPOROUS MATERIALS, [10.1016/j.micromeso.2022.112105]
21. Pan Hongwei, Wang Zhaokun, Wei Zhaoyang, Zhang Jiaping, Xu Minghan, Zong Chengzhong, Cao Lan, Wang Qingfu. (2022) Sandwiched-resistive sensors based on the 3D printing of TPU/CNTs–ILs. JOURNAL OF MATERIALS SCIENCE, 57 (20): (9187-9201). [10.1007/s10853-022-07226-4]
22. Hu Lihua, Chen Chen, Wang Xiao, Hu Kairan, Xu Zhihao, Xu Wei. (2022) ZIF-8 prepared in ionic liquid microemulsions for efficient capture of phosphate from water. JOURNAL OF CHEMICAL SCIENCES, 134 (2): (1-9). [10.1007/s12039-022-02058-w]
23. He Yang, Tingting Qin, Xinyan Zhou, Yu Feng, Zizhun Wang, Xin Ge, Nailin Yue, Dabing Li, Wei Zhang, Weitao Zheng. (2022) Boosting the kinetics of PF6− into graphitic layers for the optimal cathode of dual-ion batteries: The rehearsal of pre-intercalating Li+. Journal of Energy Chemistry, [10.1016/j.jechem.2022.04.009]
24. Haolin Li, Lin Ma, Ping Wen, Yunyan Han, Rui Dong, Mingjin Fan. (2022) Molecular structure insight into the tribological behavior of sulfonate ionic liquids as lubricants for titanium alloys. JOURNAL OF MOLECULAR LIQUIDS, [10.1016/j.molliq.2022.119082]
25. Zhi Hu, Aidi Xie, Chun Chen, Zidan Zou, Yue Shen, Zhen Fu, Yunxia Zhang, Haimin Zhang, Huijun Zhao, Guozhong Wang. (2022) Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural. FUEL, [10.1016/j.fuel.2022.123815]
26. Zhengxian Wang, Jiankang Lu, Chengyi Wu, Youmeng Dan, Guoxiang Li, Deyong Wu, Sheng Hu. (2022) Efficient reclamation phosphate by alginate-g-BMOF using poly(N-isopropyl acrylamide-co-acrylamide) as coating for temperature-responsive slow-release P-fertilizer. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, [PMID:35041885] [10.1016/j.ijbiomac.2022.01.061]
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