概述规格名称和识别符技术文档高级数据系统学分类三维结构质检证书（CoA,COO,BSE/TSE 和分析图谱) 化学和物理性质安全和危险性（GHS）此产品的引用文献技术文档和文章引用文献溶液计算器

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为什么选择此级别

，适用于对基线干扰要求严格的色谱和分析工作流程。

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储存与运输

室温。DG运输。请查阅批次 COA 获取详细规格。

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质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 68 篇同行评审文献引用。

概述

应用

Powerful reducing agent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry 反应物或试剂用于：由油酸制备热塑性聚酯聚酰胺锂聚合物电池宝石 -二氟亚甲基衍生物的加氢脱氟不对称羟醛反应具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成 LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应['2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.3 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Reactant or reagent for: The preparation of thermoplastic polyester polyamides from oleic acid Lithium-polymer batteries Hydrodefluorination of gem -difluoromethylene derivatives Asymmetric aldol reactions Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols Powerful reducing agent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

规格

别名

四氢铝酸锂, LAH, 丙氨酸锂

英文别名

规格或纯度

2.3 M in 2-methyltetrahydrofuran

英文名称

Lithium aluminum hydride solution(LAH)

储存条件

室温

运输条件

DG运输

名称和识别符

EC号

240-877-9

分子类型

小分子

IUPAC Name

aluminum;lithium;hydride

INCHI

1S/Al.Li.4H/q+3;+1;4*-1

InChi Key

BJKLPLABXHXMIM-UHFFFAOYSA-N

Smiles

[H-].[H-].[H-].[H-].[Li+].[Al+3]

Isomeric SMILES

[H-].[H-].[H-].[H-].[Li+].[Al+3]

PubChem CID

21226445

UN Number

1410

Packing Group

分子量

37.95

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

下载 SDS →

✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

查询 COA →

📊 产品数据表

产品规格和应用的快速参考摘要。

查看数据表 →

🔬 规格说明书

该级别的完整质量属性和验收标准。

查看规格说明 →

高级数据

系统学分类

分类树（Taxonomy Tree）

界（kingdom) 无机化合物
- 超类（Superclass) 混合金属/非金属化合物
  - 类（Class) 后过渡金属有机物
    - 亚类（Subclass）后过渡金属氢化物

界（kingdom)	无机化合物
超类（Superclass)	混合金属/非金属化合物
类（Class)	后过渡金属有机物
亚类（Subclass）	后过渡金属氢化物
中间层级节点（Intermediate Tree Nodes）	暂无
直接上位类(Direct Parent)	后过渡金属氢化物
其他上位类（Alternative Parents）	后过渡金属盐无机锂盐无机氢化物
分子骨架（Molecular Framework)	暂无
取代基（Substituents）	无机氢化物 - 无机氰化物 - 无机过渡金属盐 - 无机盐 - 后过渡金属氢化物
描述（Description）	该化合物属于无机化合物中的后过渡金属氢化物类。这类无机氢化物中，最重金属原子为后过渡金属。
外部描述符（External Descriptors）	暂无

三维结构

交互式化学结构模型

球棍
棍棒
线框模型
空间填充
显示氢气
动画

化学和物理性质

密度

0.883g/mLat 25°C

分子量

38.000 g/mol

XLogP3

氢键供体数Hydrogen Bond Donor Count

氢键受体数Hydrogen Bond Acceptor Count

可旋转键计数Rotatable Bond Count

精确质量Exact Mass

38.0288 Da

单同位素质量Monoisotopic Mass

38.0288 Da

拓扑极表面积Topological Polar Surface Area

0.000 Å²

重原子数Heavy Atom Count

形式电荷Formal Charge

复杂度Complexity

0.000

同位素原子数Isotope Atom Count

定义的原子立体中心计数Defined Atom Stereocenter Count

未定义的原子立体中心计数Undefined Atom Stereocenter Count

定义的键立体中心计数Defined Bond Stereocenter Count

未定义的键立体中心计数Undefined Bond Stereocenter Count

所有立体化学键的总数The total count of all stereochemical bonds

共价键合单元计数Covalently-Bonded Unit Count

安全和危险性（GHS）

一般危化品

象形图

GHS02, GHS05, GHS07, GHS08

信号词

危险

危险声明

H224: 极易燃液体和蒸气

H260: 与水接触会释放出可自燃的易燃气体

H302: 吞食有害

H315: 引起皮肤刺激

H318: 造成严重的眼睛损伤

H336: 可能引起嗜睡或头晕

预防措施声明

P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。

P223: 不允许与水接触

P233: 保持容器密闭。

P240: 地面/粘结容器和接收设备

P241: 使用防爆的[电气/通风/照明/.../]设备。

P242: 仅使用无火花的工具。

P243: 采取防静电措施

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时，请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P231+P232: 在惰性气体中操作。防潮。

P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。

P332+P313: 如发生皮肤刺激：求医/就诊。

P335+P334: 掸掉皮肤上的细小颗粒。浸入冷水中/用湿绷带包扎。

P370+P380: 着火时：疏散区域。

P405: 密闭存放

P402+P404: 存放于干燥处。存放于密闭的容器中。

P403+P233: 存放在通风良好的地方。保持容器密闭。

P403+P235: 存放在通风良好的地方。保持低温。

P501: 将内容物/容器处理到。。。

P301+P312+P330: 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口

P304+P340+P312: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

WGK Germany

Class

4.3

Merck Index

350

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

输入批号以搜索分析图谱:

技术文档和文章

科研常用盐类选型：碱金属盐 & 碱土金属盐的任务地图（含产品表1–表6）

目录：技术文章

探索主题:

碱金属盐碱土金属盐

Selection of Common Research Salts: A Task Map for Alkali Metal Salts & Alkaline Earth Metal Salts (with Product Tables 1–6)

目录：技术文章

探索主题:

Alkali Metal Salts Alkaline Earth Metal Salts

小分子合成中的反应选择：从转化类型判断到实验路径筛选

目录：技术文章

探索主题:

小分子合成

Reaction Selection in Small-Molecule Synthesis: From Transformation-Type Assessment to Experimental Route Screening

目录：技术文章

探索主题:

Small-Molecule Synthesis

什么是多胺？结构特点、分类与代表物、应用及合成策略

目录：技术文章

探索主题:

有机化学药物化学多胺含氮有机化合物多个胺型氮原子

What Are Polyamines? Structural Features, Classification and Representative Compounds, Applications, and Synthetic Strategies

目录：技术文章

探索主题:

Organic chemistry Medicinal Chemistry Polyamine Multiple amine nitrogen atoms Nitrogen-containing organic compounds

从多类酮到三维螺环砌块：[1.1.1]Propellane 参与的酮环扩张反应设计

目录：技术文章

探索主题:

螺环砌块酮类化合物

From Diverse Ketones to Three-Dimensional Spirocyclic Building Blocks: Reaction Design of [1.1.1]Propellane-Involved Ketone Ring Expansion

目录：技术文章

探索主题:

Spiral ring block Ketone compounds

氮杂三环烷烃的张力释放：三维氮杂桥环的桥位模块化官能团化与立体控制

目录：技术文章

探索主题:

ABCAs 氮杂双环[x.1.1]烷烃

Strain Release of Azatricycloalkanes: Modular Bridge-Position Functionalization and Stereochemical Control of Three-Dimensional Bridged Aza Scaffolds

目录：技术文章

探索主题:

ABCAs azabicyclo[x.1.1]alkanes

含氟3,3-二取代氧杂环丁烷砌块的设计逻辑：结构构建及胺碱性、亲脂性与代谢稳定性调节

目录：技术文章

探索主题:

分子砌块含氟氧杂环丁烷 3,3-二取代氧杂环丁烷胺碱性 pKₐ logP logD 微粒体稳定性匹配分子对

Design Logic of Fluorinated 3,3-Disubstituted Oxetane Building Blocks: Structural Construction and Modulation of Amine Basicity, Lipophilicity, and Metabolic Stability

目录：技术文章

探索主题:

pKₐ logP logD fluorinated oxetane 3,3-disubstituted oxetane molecular building block amine basicity microsomal stability matched molecular pair

硫醇合成的路线选择：C—S键构建、硫源形式与巯基释放

目录：技术文章

探索主题:

巯基硫醇 C—S键构建异硫脲盐硫代乙酸酯硅基硫源芳基硫醇脱羧硫醇化巯基释放路线选择

Route Selection for Thiol Synthesis: C–S Bond Construction, Sulfur Source Forms, and Thiol Release

目录：技术文章

探索主题:

C–S bond construction Thiols Thiol Group Isothiouronium Salts Thioacetates Silyl Sulfur Sources Aryl Thiols Decarboxylative Thiolation Thiol Release Route Selection

MTAD介导的吡啶氧化脱芳构化：暂时性对位环加成、烯烃氧化与杂原子官能化

目录：技术文章

探索主题:

哌啶吡啶烯烃氧化

MTAD-Mediated Oxidative Dearomatization of Pyridines: Transient para-Cycloaddition, Alkene Oxidation, and Heteroatom Functionalization

目录：技术文章

探索主题:

Pyridines piperidines Alkene Oxidation

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站? 引用文献检索

引用文献

1. Zhuochao Wang, Wenxin Cao, Chunqiang Sun, Dongchao Ji, Kunlong Zhao, Gang Gao, Xingchun Xu, Yingqi Liu, Tianyu Zhang, Jiaqi Zhu, Jiecai Han. (2023) Nanodiamond reinforced self-healing and transparent poly(urethane–urea) protective coating for scratch resistance. International Journal of Smart and Nano Materials, [10.1080/19475411.2023.2289608]
2. Junyi Huang, Jianfeng Ding, Furui Tan, Yueyue Gao, Xiayao Lu, Chen Dong, Gentian Yue, Xiaobao Xu, Liming Ding. (2023) A hybrid quantum dot:MXene bulk heterojunction for an efficient infrared self-powered photodetector. Journal of Materials Chemistry C, 11 (48): (17106-17114). [10.1039/D3TC03254J]
3. Ying Sun, Qimeng Wu, Quanyou Fu, Hailin Cong, Youqing Shen, Bing Yu, Hao Hu. (2023) Reactive oxygen species-responsive polyprodrug micelles deliver cell cycle regulators for chemosensitization. TALANTA, [PMID:37801926] [10.1016/j.talanta.2023.125242]
4. Potao Sun, Zeyan Shi, Wenxia Sima, Xinyu Tang, Tao Yuan, Ming Yang, Hang Xu, Zhaoping Li. (2023) A UV-responsive mechanically robust insulating polymer that achieves intrinsic self-healing of electrical tree damage based on reversible anthracene photodimerization. Journal of Materials Chemistry C, 11 (41): (14217-14225). [10.1039/D3TC02671J]
5. Diqin Zhang, Yu Zhao, Bin Guo, Zhen Zhang, Dejiao Hu, Zhen Wang, Jianhua Zhu, Yan Ye, Yuxia Zhao. (2023) Acrylate dendritic monomers for fabricating holographic data storage media with high performance. EUROPEAN POLYMER JOURNAL, [10.1016/j.eurpolymj.2023.112436]
6. Hailiang Chen, Chenyu Liu, Simiao Yu, Hengjun Zhou, Farishta Shafiq, Weihong Qiao. (2023) αvβ3 Receptor-targeted acid-responsive controlled-release endosome escape doxorubicin-loaded liposomes for A549/ADR treatment. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, [10.1016/j.colsurfa.2023.131990]
7. Yang Chen, Zhiwei Fan, Yong Liu, Yiru Wang, Zeyu Wang, Rongchun Zhang, Bingxu Ma, Yiliu Liu, Wei Zhang, Liqun Tang, Taolin Sun. (2023) Highly stretchable and tough elastomers from cyclic polymers. GIANT, [10.1016/j.giant.2023.100177]
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9. Shi Bingyu, Liu Man, Chen Jiangang. (2023) N-doped Metallocene Catalysts for Synthesis of High Quality Lubricant Base Oils from Fishcher–Tropsch Synthesized α-Olefin. CATALYSIS LETTERS, [10.1007/s10562-023-04333-y]
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19. Abbas Daham, Abdeldjalil Zegaoui, Hamid Abdelhafid Ghouti, Mehdi Derradji, Wan-an Cai, Jun Wang, Wen-bin Liu, Jun-yi Wang, Zaoui Moussa. (2020) Structural, morphological and mechanical properties of hyperbranched polymers coated carbon fibers reinforced DCBA/BA-a composites. COMPOSITE INTERFACES, [10.1080/09276440.2019.1708672]
20. Qingyi Xie, Chao Liu, Xiaobin Lin, Chunfeng Ma, Guangzhao Zhang. (2020) Nanodiamond Reinforced Poly(dimethylsiloxane)-Based Polyurea with Self-Healing Ability for Fouling Release Coating. ACS Applied Polymer Materials, [10.1021/acsapm.0c00356]
21. Jinlong Sun, Jie Xu, Hui Jiang, Xinsheng Zhang, Dongfang Niu. (2020) Roles of Oxygen Functional Groups in Carbon Nanotubes-Supported Ag Catalysts for Electrochemical Conversion of CO2 to CO. ChemElectroChem, 7 (8): (1869-1876). [10.1002/celc.202000026]
22. Yongpeng Xia, Sheng Wei, Qiang Huang, Jianquan Li, Xinghua Cen, Huanzhi Zhang, Hailiang Chu, Lixian Sun, Fen Xu, Pengru Huang. (2020) Facile synthesis of NiCo2O4-anchored reduced graphene oxide nanocomposites as efficient additives for improving the dehydrogenation behavior of lithium alanate. Inorganic Chemistry Frontiers, 7 (5): (1257-1272). [10.1039/C9QI01451A]
23. Jianfeng Liu, Lu Shao, Xiu Feng, Sheng Xu, Puke Mi. (2019) Synthesis of pyrrole-bridged constrained geometry complexes and their application for olefin polymerization. JOURNAL OF APPLIED POLYMER SCIENCE, 137 (17): (48620). [10.1002/app.48620]
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26. Dongjun Shen, Yijuan Long, Jie Wang, Yuanyuan Yu, Jiangli Pi, Lili Yang, Huzhi Zheng. (2019) Tuning the fluorescence performance of carbon dots with a reduction pathway. Nanoscale, 11 (13): (5998-6003). [PMID:30882812] [10.1039/C8NR09587F]
27. Bingchuan Zhang, Zhiqiang Sun, Min Lv, Hui Xu. (2018) Semisynthesis of Matrinic Acid/Alcohol/Ester Derivatives, Their Pesticidal Activities, and Investigation of Mechanisms of Action against Tetranychus cinnabarinus. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, [PMID:30452245] [10.1021/acs.jafc.8b04965]
28. Jingang Xie, Mengmeng Song, Heqing Fu. (2018) Synthesis and properties of electrical conductive and antibacterial siloxane-modified carbon fiber–silver–acrylate nanocomposites. International Journal of Polymeric Materials and Polymeric Biomaterials, [10.1080/00914037.2017.1393817]
29. Qiangjun Li, Yongjie Yuan, Lifang He, Shenglan Liu, Hailiang Zhang. (2018) Preparation and characterization of a multistimuli-responsive photoluminescent monomer and its corresponding polymer. Polymer Chemistry, 9 (46): (5521-5530). [10.1039/C8PY01372A]
30. Lei Shang, Mengjie Zhang, Liu Liu, Linghan Xiao, Ming Li, Yuhui Ao. (2018) Improving the interfacial property of carbon fibre/epoxy resin composites by grafting amine-capped cross-linked poly-itaconic acid. SURFACE AND INTERFACE ANALYSIS, 51 (2): (199-209). [10.1002/sia.6565]
31. Xinfeng Cheng, Xiuping Ju, Hongmei Du, Yan Zhang, Jinsheng Zhao, Yu Xie. (2018) Synthesis and characterization of novel donor–acceptor type electrochromic polymers containing diketopyrrolopyrrole as an acceptor and propylenedioxythiophene or indacenodithiophene as a donor. RSC Advances, 8 (41): (23119-23129). [PMID:35540135] [10.1039/C8RA03570A]
32. Hao Zhong, Jun-Wei Wang, Bin-Bin Dong, Lin Li, Ming-Ye Yang, Jun-Ling Yu, Xu Xin, Simeon Agathopoulos. (2018) A simple way to prepare a hydrophobic Sr[LiAl3N4]:Eu2+ phosphor with improved moisture resistance. MATERIALS RESEARCH BULLETIN, [10.1016/j.materresbull.2018.05.009]
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