基本描述

别名	叔丁醇钠 \| 第三丁氧基钠
英文别名	2-Propanol, 2-methyl-, sodium salt (1:1) \| EC 212-741-9 \| t-butoxysodium \| (tert-butoxy)sodium \| tertiary butoxy sodium \| SH-003 \| sodium tbutoxide \| sodium t-butoxide \| Sodium tert-butoxide, 97% \| tert-butyl 4-formylpiperidine-1-carboxylate;N-BOC-PIPERID
规格或纯度	≥98%
英文名称	Sodium tert-butoxide
应用	叔丁醇钠可用作安全有效的氢化钠替代物，用于羟乙基腺嘌呤和二乙基p-对甲苯磺酰氧基甲基膦酸酯偶合生成9-[2-(二乙基磷酰甲氧基)乙烷]腺嘌呤(二乙基-PMEA), 这是制备阿德福韦酯的重要中间体。它还可以用于： · 在10-菲咯啉衍生物存在下，辅助卤代芳烃与苯衍生物偶合反应。 · 可以激活第一副族过渡金属预催化剂。 · 在一种新型环钯化预催化剂存在下，是芳基氯化物氨基化的一种碱。
储存温度	充氩
运输条件	常规运输
产品介绍	和水反应。叔丁醇钠可用作安全有效的氢化钠替代物，用于羟乙基腺嘌呤和二乙基p-对甲苯磺酰氧基甲基膦酸酯偶合生成9-[2-(二乙基磷酰甲氧基)乙烷]腺嘌呤(二乙基-PMEA), 这是制备阿德福韦酯的重要中间体。它还可以用于： · 在10-菲咯啉衍生物存在下，辅助卤代芳烃与苯衍生物偶合反应。 · 可以激活第一副族过渡金属预催化剂。 · 在一种新型环钯化预催化剂存在下，是芳基氯化物氨基化的一种碱。

名称和识别符

分子类型	小分子
IUPAC Name	sodium;2-methylpropan-2-olate
INCHI	InChI=1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChi Key	MFRIHAYPQRLWNB-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)[O-].[Na+]
Isomeric SMILES	CC(C)(C)[O-].[Na+]
WGK Germany	3
PubChem CID	23676156
分子量	96.1

化学和物理性质

溶解性	微溶于四氢呋喃
密度	1.104 g/cm3
敏感性	对空气敏感，对湿度敏感
折光率	1.413
闪点(℉)	57.2 °F
闪点(℃)	14 °C
熔点	270 °C
分子量	96.100 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	96.0551 Da
单同位素质量Monoisotopic Mass	96.0551 Da
拓扑极表面积Topological Polar Surface Area	23.100 Å²
重原子数Heavy Atom Count	6
形式电荷Formal Charge	0
复杂度Complexity	29.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	2

安全和危险性（GHS）

象形图	GHS05, GHS07, GHS02
信号词	Danger
危险声明	H335: 可能引起呼吸道刺激 H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤 H228: 易燃固体 H251: 自热；可能着火
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P271: 仅在室外或通风良好的地方使用。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P410: 防止阳光直射 P420: 分开存放。 P235: 保持凉爽 P407: 在堆垛或托盘之间保持气隙。 P413: 在不超过...°C / ...°F的温度下存储大于... kg / ... lbs的散装质量。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
个人防护装备	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

SDS英文版

技术规格说明书

Purity(NonaqueousTitration)	97.5-102.5（%）
Appearance（S109392)	white to pale yellow Powder, Crystals and/or Chunk
Infrared spectrum	Conforms to Structure
Proton NMR spectrum	Conforms to Structure
Free Alkali (as NaOH)	0-2（%）

技术规格说明书

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批号(Lot Number)	证书类型	日期	货号
F2511517	分析证书	25-05-26	S109392
F2511516	分析证书	25-05-26	S109392
B2514345	分析证书	25-01-20	S109392
B2514344	分析证书	25-01-20	S109392
B2514333	分析证书	25-01-20	S109392
J2423498	分析证书	24-09-24	S109392
J2423493	分析证书	24-09-24	S109392
J2423490	分析证书	24-09-24	S109392
A2508095	分析证书	24-09-24	S109392
A2513599	分析证书	24-07-10	S109392
A2513600	分析证书	24-07-10	S109392
A2425316	分析证书	24-01-10	S109392
A2425315	分析证书	24-01-10	S109392
A2425317	分析证书	24-01-10	S109392
A2425340	分析证书	24-01-10	S109392
G2424016	分析证书	23-08-24	S109392
J2418110	分析证书	23-08-24	S109392
I2311644	分析证书	23-08-24	S109392
I2311621	分析证书	23-08-24	S109392
I2311643	分析证书	23-08-24	S109392
B23211076	分析证书	23-02-06	S109392
B23211089	分析证书	23-02-06	S109392
B23211055	分析证书	23-02-06	S109392
B23211054	分析证书	23-02-06	S109392
K2221182	分析证书	22-11-30	S109392
H2324305	分析证书	22-07-09	S109392
H2217696	分析证书	22-07-09	S109392
H2217695	分析证书	22-07-09	S109392
H2217694	分析证书	22-07-09	S109392
H2217693	分析证书	22-07-09	S109392
F2307386	分析证书	22-07-09	S109392

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此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站?

1. Yuying Li, Junle Zhang, Yaxuan Shi, Yuancheng Zhang, Ge Shi, Xiaomeng Zhang, Zhe Cui, Peng Fu, Minying Liu, Xiaoguang Qiao, Yanjie He, Yudong Wang, Haitao Zhao, Wenjie Zhang, Xinchang Pang. (2023) Robust Strategy to Improve the Compatibility between Incorporated Upconversion Nanoparticles and the Bulk Transparent Polymer Matrix. ACS Omega, 8 (35): (32159–32167). [PMID:37692212] [10.1021/acsomega.3c04613]
2. Duanlian Tang, Minlei Yin, Xiaowei Du, Yuxin Duan, Jie Chen, Ting Qiu. (2023) Wettability tunable conjugated microporous poly(aniline)s for long-term, rapid and ppb level sequestration of Hg(II). CHEMICAL ENGINEERING JOURNAL, 474 (145527). [10.1016/j.cej.2023.145527]
3. Duanlian Tang, Xiaoying Lyu, Zhixian Huang, Renwei Xu, Jie Chen, Ting Qiu. (2023) Nitrogen-doped microporous carbons as highly efficient adsorbents for CO2 and Hg(II) capture. POWDER TECHNOLOGY, 427 (118769). [10.1016/j.powtec.2023.118769]
4. Xiaoyu Lou, Xiaoyan Chen, Duanlian Tang, Qiong Wang, Yukun Tian, Menghan Tu, Yupeng Wang, Changshen Ye, Jie Chen, Ting Qiu. (2022) Conjugated Microporous Poly(aniline) Enabled Hierarchical Porous Carbons for Hg(II) Adsorption. LANGMUIR, 38 (43): (13238–13247). [PMID:36260748] [10.1021/acs.langmuir.2c02240]
5. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang. (2022) Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells. ACS Applied Energy Materials, 5 (9): (10742–10750). [10.1021/acsaem.2c01470]
6. Tao Huang, Rongrong Zheng, Haiyang Chang, Di Ma, Haijun Niu. (2022) Sodium tert-butoxide as stable electrode material in aprotic electrolyte for high cycle stability organic sodium-ion batteries. JOURNAL OF POWER SOURCES, 532 (231361). [10.1016/j.jpowsour.2022.231361]
7. Xianqi Zhu, Lin Li, Jin Tang, Chunyu Yang, Hao Yu, Kunpeng Liu, Ziyan Zheng, Xinggui Gu, Qingsong Yu, Fu-Jian Xu, Zhihua Gan. (2022) Cascade-responsive nano-assembly for efficient photothermal-chemo synergistic inhibition of tumor metastasis by targeting cancer stem cells. BIOMATERIALS, 280 (121305). [PMID:34890970] [10.1016/j.biomaterials.2021.121305]
8. Yan-Xiong LIU, Long-Chun BIAN, Jie-Ren XIA, Qiu-E CAO. (2021) A Novel Ion-imprinted Polymer Based on Multi-walled Carbon Nanotubes for Solid Phase Extraction of Pd(II). CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 49 (e21170). [10.1016/S1872-2040(21)60114-7]
9. Jian Chen, Kai Chen, Baichuan Han, Yunting Xue, Wanjuan Chen, Zhenzhong Gao, Xianfeng Hou. (2020) A novel single-fluorophore-based ratiometric fluorescent probe for detection of formaldehyde in air. TETRAHEDRON, 76 (131681). [10.1016/j.tet.2020.131681]
10. Yue Yu, Lei Shi, Jianjun Guo, Xin Li, Wenbing Yang, Zhigang Zhang, Guangwen Xu. (2021) In-depth understanding of soluble base deactivation during the carbonate transesterification process. FUEL, 285 (119201). [10.1016/j.fuel.2020.119201]
11. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang. (2020) Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate. ACS Sustainable Chemistry & Engineering, 8 (27): (9968–9979). [10.1021/acssuschemeng.0c00430]
12. Xinming Wu, Bin Huang, Qiguan Wang, Yan Wang. (2019) Thermally chargeable supercapacitor using a conjugated conducting polymer: Insight into the mechanism of charge-discharge cycle. CHEMICAL ENGINEERING JOURNAL, 373 (493). [10.1016/j.cej.2019.05.075]
13. S. B. Tan, Y. F. Zhao, W. W. Zhang, P. Gao, W. W. Zhu, Z. C. Zhang. (2017) A light-mediated metal-free atom transfer radical chain transfer reaction for the controlled hydrogenation of poly(vinylidene fluoride-chlorotrifluoroethylene). Polymer Chemistry, 9 (2): (221-227). [10.1039/C7PY01870C]
14. Xue-Qi Zhang, Zhong-Xia Wang. (2014) Nickel-catalyzed cross-coupling of aryltrimethylammonium triflates and amines. ORGANIC & BIOMOLECULAR CHEMISTRY, 12 (9): (1448-1453). [PMID:24445564] [10.1039/C3OB41989D]
15. Long Tian, Xiaonan Song, Yi Liu, Churu Zhang, Lan Shi, Qinglin Chen, Yanyan Deng, Weigang Cui, Shaoyun Shan, Tianding Hu. (2024) Defect-engineering improves the activity of Metal-Organic frameworks for catalyzing hydroboration of Alkynes: A combination of experimental investigation and Density functional theory calculations. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 662 (263). [PMID:38354554] [10.1016/j.jcis.2024.02.067]
16. Xiaoming Li, Kun Li, Wei Zhao, Qiuhong Ouyang, Jimin Guo, Jianjun Zhang. (2024) Hollow Prussian Blue Nanoparticle-Based Controlled-Release Nanocapsules for Enhanced Tumor Antiangiogenesis Therapy. ACS Applied Nano Materials, 7 (24): (28338-28347). [10.1021/acsanm.4c05425]
17. Xiaoyu Lou, Duanlian Tang, Xuanjie Chen, Lanbin Mo, Yong Li, Changshen Ye, Jie Chen, Ting Qiu. (2025) Ketone-based conjugated microporous poly(aniline)s for the ultradeep separation of heavy metal ions. CHEMICAL ENGINEERING SCIENCE, 301 (120706). [10.1016/j.ces.2024.120706]
18. Jie Chen, Wen Zeng, Huiyao Huang, Xiaoyu Lou, Song Chen, Changshen Ye, Zhixian Huang, Ting Qiu. (2025) Tunable porosity and Hg (II) adsorption performance in dual heteroatom functionalized conjugated micro-mesoporous poly(aniline)s. SEPARATION AND PURIFICATION TECHNOLOGY, 363 (131997). [10.1016/j.seppur.2025.131997]

参考文献

1. Yuying Li, Junle Zhang, Yaxuan Shi, Yuancheng Zhang, Ge Shi, Xiaomeng Zhang, Zhe Cui, Peng Fu, Minying Liu, Xiaoguang Qiao, Yanjie He, Yudong Wang, Haitao Zhao, Wenjie Zhang, Xinchang Pang. (2023) Robust Strategy to Improve the Compatibility between Incorporated Upconversion Nanoparticles and the Bulk Transparent Polymer Matrix. ACS Omega, 8 (35): (32159–32167). [PMID:37692212] [10.1021/acsomega.3c04613]
2. Duanlian Tang, Minlei Yin, Xiaowei Du, Yuxin Duan, Jie Chen, Ting Qiu. (2023) Wettability tunable conjugated microporous poly(aniline)s for long-term, rapid and ppb level sequestration of Hg(II). CHEMICAL ENGINEERING JOURNAL, 474 (145527). [10.1016/j.cej.2023.145527]
3. Duanlian Tang, Xiaoying Lyu, Zhixian Huang, Renwei Xu, Jie Chen, Ting Qiu. (2023) Nitrogen-doped microporous carbons as highly efficient adsorbents for CO2 and Hg(II) capture. POWDER TECHNOLOGY, 427 (118769). [10.1016/j.powtec.2023.118769]
4. Xiaoyu Lou, Xiaoyan Chen, Duanlian Tang, Qiong Wang, Yukun Tian, Menghan Tu, Yupeng Wang, Changshen Ye, Jie Chen, Ting Qiu. (2022) Conjugated Microporous Poly(aniline) Enabled Hierarchical Porous Carbons for Hg(II) Adsorption. LANGMUIR, 38 (43): (13238–13247). [PMID:36260748] [10.1021/acs.langmuir.2c02240]
5. Hang Yu, Dewang Li, Huayu Bao, Zhenhu Zhang, Hongli Liu, Fei Zhang, Shirong Wang. (2022) Multifunctional Cross-Linked Hole Transporting Interfacial Layer for Efficient and Stable Perovskite Solar Cells. ACS Applied Energy Materials, 5 (9): (10742–10750). [10.1021/acsaem.2c01470]
6. Tao Huang, Rongrong Zheng, Haiyang Chang, Di Ma, Haijun Niu. (2022) Sodium tert-butoxide as stable electrode material in aprotic electrolyte for high cycle stability organic sodium-ion batteries. JOURNAL OF POWER SOURCES, 532 (231361). [10.1016/j.jpowsour.2022.231361]
7. Xianqi Zhu, Lin Li, Jin Tang, Chunyu Yang, Hao Yu, Kunpeng Liu, Ziyan Zheng, Xinggui Gu, Qingsong Yu, Fu-Jian Xu, Zhihua Gan. (2022) Cascade-responsive nano-assembly for efficient photothermal-chemo synergistic inhibition of tumor metastasis by targeting cancer stem cells. BIOMATERIALS, 280 (121305). [PMID:34890970] [10.1016/j.biomaterials.2021.121305]
8. Yan-Xiong LIU, Long-Chun BIAN, Jie-Ren XIA, Qiu-E CAO. (2021) A Novel Ion-imprinted Polymer Based on Multi-walled Carbon Nanotubes for Solid Phase Extraction of Pd(II). CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 49 (e21170). [10.1016/S1872-2040(21)60114-7]
9. Jian Chen, Kai Chen, Baichuan Han, Yunting Xue, Wanjuan Chen, Zhenzhong Gao, Xianfeng Hou. (2020) A novel single-fluorophore-based ratiometric fluorescent probe for detection of formaldehyde in air. TETRAHEDRON, 76 (131681). [10.1016/j.tet.2020.131681]
10. Yue Yu, Lei Shi, Jianjun Guo, Xin Li, Wenbing Yang, Zhigang Zhang, Guangwen Xu. (2021) In-depth understanding of soluble base deactivation during the carbonate transesterification process. FUEL, 285 (119201). [10.1016/j.fuel.2020.119201]
11. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang. (2020) Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate. ACS Sustainable Chemistry & Engineering, 8 (27): (9968–9979). [10.1021/acssuschemeng.0c00430]
12. Xinming Wu, Bin Huang, Qiguan Wang, Yan Wang. (2019) Thermally chargeable supercapacitor using a conjugated conducting polymer: Insight into the mechanism of charge-discharge cycle. CHEMICAL ENGINEERING JOURNAL, 373 (493). [10.1016/j.cej.2019.05.075]
13. S. B. Tan, Y. F. Zhao, W. W. Zhang, P. Gao, W. W. Zhu, Z. C. Zhang. (2017) A light-mediated metal-free atom transfer radical chain transfer reaction for the controlled hydrogenation of poly(vinylidene fluoride-chlorotrifluoroethylene). Polymer Chemistry, 9 (2): (221-227). [10.1039/C7PY01870C]
14. Xue-Qi Zhang, Zhong-Xia Wang. (2014) Nickel-catalyzed cross-coupling of aryltrimethylammonium triflates and amines. ORGANIC & BIOMOLECULAR CHEMISTRY, 12 (9): (1448-1453). [PMID:24445564] [10.1039/C3OB41989D]
15. Long Tian, Xiaonan Song, Yi Liu, Churu Zhang, Lan Shi, Qinglin Chen, Yanyan Deng, Weigang Cui, Shaoyun Shan, Tianding Hu. (2024) Defect-engineering improves the activity of Metal-Organic frameworks for catalyzing hydroboration of Alkynes: A combination of experimental investigation and Density functional theory calculations. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 662 (263). [PMID:38354554] [10.1016/j.jcis.2024.02.067]
16. Xiaoming Li, Kun Li, Wei Zhao, Qiuhong Ouyang, Jimin Guo, Jianjun Zhang. (2024) Hollow Prussian Blue Nanoparticle-Based Controlled-Release Nanocapsules for Enhanced Tumor Antiangiogenesis Therapy. ACS Applied Nano Materials, 7 (24): (28338-28347). [10.1021/acsanm.4c05425]
17. Xiaoyu Lou, Duanlian Tang, Xuanjie Chen, Lanbin Mo, Yong Li, Changshen Ye, Jie Chen, Ting Qiu. (2025) Ketone-based conjugated microporous poly(aniline)s for the ultradeep separation of heavy metal ions. CHEMICAL ENGINEERING SCIENCE, 301 (120706). [10.1016/j.ces.2024.120706]
18. Jie Chen, Wen Zeng, Huiyao Huang, Xiaoyu Lou, Song Chen, Changshen Ye, Zhixian Huang, Ting Qiu. (2025) Tunable porosity and Hg (II) adsorption performance in dual heteroatom functionalized conjugated micro-mesoporous poly(aniline)s. SEPARATION AND PURIFICATION TECHNOLOGY, 363 (131997). [10.1016/j.seppur.2025.131997]

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货号 (SKU)	包装规格	是否现货
S109392-100g	100g	现货
S109392-500g	500g	期货
S109392-2.5kg	2.5kg	现货

叔丁醇钠

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库存信息

基本描述

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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溶液计算器

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