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甲基叔丁基醚

规格或纯度: 色谱级,≥99.9% (GC)
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货号 (SKU) 包装规格 是否现货 价格 数量
B108115-100ml
100ml 现货 Stock Image
B108115-500ml
500ml 现货 Stock Image
B108115-1L
1L 现货 Stock Image
B108115-4L
4L 现货 Stock Image
B108115-12×500ml
12×500ml 现货 Stock Image
B108115-4×4L
4×4L 期货 Stock Image

基本描述

别名 叔丁基甲基醚
英文别名 2-Methoxy-2-methylpropane | Propane, 2-methoxy-2-methyl- | Methyl t-butyl ether | MTBE | Methyl tert-butyl ether | Methyl tertiary-butyl ether
规格或纯度 色谱级,≥99.9% (GC)
英文名称 tert-Butyl methyl ether
运输条件 常规运输
产品介绍

具有醚样气味 。酸性溶液中不稳定。易溶于乙醇和乙醚,溶于(4.8g/100g)。水溶于叔丁基甲基醚:1.5g/100g。半数致死量(小鼠,15分钟)1.6mmol/L。易燃。对眼睛、呼吸系统和皮肤有刺激性。 溶剂。色谱中尤其是高压液相色谱中用作脱剂。有机合成。无铅汽油中辛烷传爆剂。

叔丁基甲基醚(甲基叔丁醚,MTBE)是一种汽油添加剂。丙烷氧化细菌菌株对其进行氧化降解已经过测定。其热介导的生物降解的动力学已经在多种反应条件下进行了研究。其生物降解遵循伪一级衰变模型,并且其伪一级速率常数已经过测定。其水中的提取物已通过使用有机聚合化合物Nafion进行研究。MTBE可以通过甲醇和异丁烯之间的酸催化反应合成。一项研究表明,MTBE的加入通过停流法增加了丙烯聚合过程中活性位点的数量。该溶剂符合ACS(美国化学学会)规范,可用于需要严格质量条件的工艺,如分析测试。
应用
叔甲基醚(甲基叔丁醚,MTBE)可用于:
作为混合微生物菌群中的唯一碳和能量来源。
从生物液体中提取脂质用于鸟枪法谱分析。
在超临界条件下,在不存在催化剂的情况下通过菜籽油的酯交换,合成脂肪酸甲酯(FAME)和甘油叔丁醚。


名称和标识符

EC号 216-653-1
IUPAC Name 2-methoxy-2-methylpropane
INCHI InChI=1S/C5H12O/c1-5(2,3)6-4/h1-4H3
InChi Key BZLVMXJERCGZMT-UHFFFAOYSA-N
Canonical SMILES CC(C)(C)OC
Isomeric SMILES CC(C)(C)OC
WGK Germany 1
RTECS KN5250000
PubChem CID 15413
UN Number 2398
Packing Group II
分子量 88.15
Beilstein号 1730942
Reaxy-Rn 1730942

化学和物理性质

溶解性 不溶于水。
密度 0.74
折光率 1.3689
闪点(℉) -18.4℉
闪点(℃) -28℃
沸点 55.2°C
熔点 -109°C

安全和危险性(GHS)

一般危化品 一般危化品
象形图
ghs07

Harmful

ghs02

Flammable

信号词 Danger
危险声明 H315: Causes skin irritation
H225: Highly Flammable liquid and vapor
预防措施声明 P280,P370+P378,P210,P302+P352,P321,P501,P233,P240,P264,P403+P235,P303+P361+P353,P241,P362+P364,P242,P243,P332+P317
WGK Germany 1
RTECS KN5250000
Reaxy-Rn 1730942
Class 3
Merck Index 6032
个人防护装备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US)

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参考文献

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