氟化铯

CAS: 13400-13-0 货号: C755570 分子式: CsF 分子量: 151.9 EC号: 236-487-3
有货
级别和纯度: UltraBio™ ? UltraBio™ —— 阿拉丁面向分子生物学应用的系列。适用于分子流程中无核酸酶、高一致性的试剂。 ≥99%(F)
储存条件
室温
运输条件
DG运输
★
规格
库存
价格
数量
10g
C755570-10g
期货 Stock Image
¥982.90
250g
C755570-250g
期货 Stock Image
¥12,842.90
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为什么选择此级别

UltraBio™ 级 提供 ≥99%(F) 纯度,适用于对基线干扰要求严格的色谱和分析工作流程。

🌡

储存与运输

室温。DG运输 。请查阅批次 COA 获取详细规格。

📋

质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

📚

文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 61 篇同行评审文献引用。

概述

可作为反应物用于:制备合成氟烯丙基化合物过程中的合成砌块在中性pH下和缓冲的有机-水混合溶液中,通过水解烷基甲硅烷基醚来合成醇炔基碘鎓盐的亲核氟化,以形成氟代乙烯基化合物亲核芳香取代(SNAr)反应用于成功合成单晶Dion-Jacobson相CsLaTa2O7,其在光催化和超导性方面具有应用。

Reactant for:
  • Preparation of building blocks for synthesis of fluoroallylic compounds
  • Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
  • Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
  • Nucleophilic aromatic substitution (SNAr) reactions
Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa2O7, that has applications in photocatalysis and superconductivity.

规格

规格或纯度
UltraBio™, ≥99%(F)
英文名称
Cesium fluoride
储存条件
室温
运输条件
DG运输
纯度
≥99%(F)
名称和识别符
EC号
236-487-3
分子类型
小分子
IUPAC Name
cesium;fluoride
INCHI
1S/Cs.FH/h;1H/q+1;/p-1
InChi Key
XJHCXCQVJFPJIK-UHFFFAOYSA-M
Smiles
[F-].[Cs+]
Isomeric SMILES
[F-].[Cs+]
UN Number
Packing Group
III
分子量
151.9
Reaxy-Rn
6184400

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

下载 SDS →

✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

查询 COA →

📊 产品数据表

产品规格和应用的快速参考摘要。

查看数据表 →

🔬 规格说明书

该级别的完整质量属性和验收标准。

查看规格说明 →

高级数据

系统学分类

分类树(Taxonomy Tree)

界(kingdom) 无机化合物
超类(Superclass) 混合金属/非金属化合物
类(Class) 碱金属盐
亚类(Subclass) 碱金属氟化物
中间层级节点(Intermediate Tree Nodes) 暂无
直接上位类(Direct Parent) 碱金属氟化物
其他上位类(Alternative Parents) 无机盐  
分子骨架(Molecular Framework) 暂无
取代基(Substituents) 碱金属氟化物 - 无机盐
描述(Description) 该化合物属于无机化合物中的碱金属氟化物类。这类无机化合物中,最大卤素原子为氟,最重金属原子为碱金属。
外部描述符(External Descriptors) 暂无
三维结构
交互式化学结构模型





产品属性
pH 6.5-7.5 (25 °C, 3 M in H 2 O)
化学和物理性质
溶解性
H 2 O: 3 M at 20 °C, clear, colorless
密度
4.115 g/mL at 25 °C (lit.)
沸点
1251°C
熔点
682 °C
分子量
151.903 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count
0
氢键受体数Hydrogen Bond Acceptor Count
1
可旋转键计数Rotatable Bond Count
0
精确质量Exact Mass
151.904 Da
单同位素质量Monoisotopic Mass
151.904 Da
拓扑极表面积Topological Polar Surface Area
0.000 Ų
重原子数Heavy Atom Count
2
形式电荷Formal Charge
0
复杂度Complexity
2.000
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
2
安全和危险性(GHS)
一般危化品
一般危化品
象形图
GHS05,   GHS06,   GHS07,   GHS08
信号词
危险
危险声明

H301: 吞咽会中毒

H311: 皮肤接触有毒

H314: 造成严重的皮肤灼伤和眼睛损伤

H315: 引起皮肤刺激

H318: 造成严重的眼睛损伤

H331: 吸入会中毒

H361: 怀疑破坏生育力或未出生的孩子

H301+H311+H331: 吞咽、皮肤接触或吸入中毒。

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理(请参阅此标签上的...)。

P330: 漱口

P363: 再次使用之前,请清洗受污染的衣物。

P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。

P302+P352: 如皮肤沾染:用水充分清洗。

P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。

P361+P364: 立即脱掉所有沾染的衣服,清洗后方可重新使用。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P203: 使用前,获取、阅读并遵守所有安全说明。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P316: 如果吞咽:立即寻求紧急医疗救助。

P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟。取下隐形眼镜(如果有的话),并且操作简单。继续冲洗。

P318: 如果暴露或担心,请就医。

P317: 寻求紧急医疗救助。

P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。

P302+P361+P354: 如果接触皮肤:立即脱掉所有被污染的衣服。立即用水冲洗几分钟。

P316: 立即寻求紧急医疗救助。

WGK Germany
3
RTECS
FK9650000
Class
6.1
Merck Index
2012
个人防护装备
Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
RIDADR
UN 3288 6.1 / PGIII
质检证书(CoA,COO,BSE/TSE 和分析图谱)
C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:
技术文档和文章
UltraBio™:定义分子生物学应用的卓越性
UltraBio™: Defining Excellence in Molecular Biology Applications
一个原子也能“改命”:药物设计的原子级旋钮与官能团工具箱(甲基/卤素键/3D砌块/后期氟化及选型产品表)
One Atom Can Change a Drug’s Fate: Atom-Level Knobs and a Functional-Group Toolbox for Medicinal Chemistry (Methyl / Halogen Bonding / 3D Building Blocks / Late-Stage Fluorination + Product-Selection Tables)
后期氟化工具箱:给候选分子做“微创升级”:四类“氟旋钮”→ 亲电/亲核两大路线 → ¹⁸F-PET 示踪分线 → 选型导航与代表产品清单
Late-Stage Fluorination Toolbox: “Minimally Invasive Upgrades” for Lead Candidates: Four “Fluorine Knobs” → Two major routes (electrophilic vs nucleophilic) → An ¹⁸F-PET tracer branch → Selection navigation & representative product list
OSF/ASF 双通道工具箱:四元小环磺酰氟的分流反应、条件旋钮与选型导航
OSF/ASF Dual-Channel Toolbox: Divergent Reactions of Four-Membered Ring Sulfonyl Fluorides, Condition “Knobs,” and Selection Navigation
科研常用盐类选型:碱金属盐 & 碱土金属盐的任务地图(含产品表1–表6)
Selection of Common Research Salts: A Task Map for Alkali Metal Salts & Alkaline Earth Metal Salts (with Product Tables 1–6)
钙钛矿光伏/PeLED 前驱体指南:金属卤化物盐的选型、关键条件与可复现性能(含产品表1–表4及选型导航)
Perovskite PV/PeLED Precursor Guide: Selecting Metal Halide Salts, Key Conditions, and Reproducible Performance (including Product Tables 1–4 and a Selection Navigation Guide)
Suzuki–Miyaura 反应怎么做稳:定位瓶颈,锁定可复现窗口(含选型导航及产品表1–表5)
How to Make the Suzuki–Miyaura Reaction Robust: Pinpoint the Bottleneck and Lock in a Reproducible Operating Window (with Selection Navigation and Product Tables 1–5)
硅试剂助力多肽合成:未保护底物成肽的研究进展与方法价值
Silicon Reagent-Assisted Peptide Synthesis: Research Progress and Methodological Value of Peptide Bond Formation from Unprotected Substrates
TMSE、Teoc 与 SEM:三类 2-(三甲基硅基)乙基衍生保护体系的分工与选用逻辑
TMSE, Teoc, and SEM: Functional Roles and Selection Logic of Three 2-(Trimethylsilyl)ethyl-Derived Protecting Systems
Teoc 氨基保护基的选用逻辑:从氟离子触发脱保护到正交保护设计
Selection Logic for the Teoc Amino Protecting Group: From Fluoride-Triggered Deprotection to Orthogonal Protecting-Group Design
SEM-Cl 的实验选用:从 O/N-SEM 保护、杂环定向官能化到受保护 C1 片段引入
Experimental Selection of SEM-Cl: From O/N-SEM Protection and Directed Functionalization of N-Heterocycles to the Introduction of Protected C1 Fragments
4-[(叔丁基二甲基硅基)氧基]丁-1-醇:作为单保护 1,4-丁二醇构件和受保护 C4 连接臂的实验选型判断
4-[(tert-Butyldimethylsilyl)oxy]butan-1-ol: Experimental Selection Logic as a Monoprotected 1,4-Butanediol Building Block and a Protected C4 Linker
含氟3,3-二取代氧杂环丁烷砌块的设计逻辑:结构构建及胺碱性、亲脂性与代谢稳定性调节
Design Logic of Fluorinated 3,3-Disubstituted Oxetane Building Blocks: Structural Construction and Modulation of Amine Basicity, Lipophilicity, and Metabolic Stability
芳炔–四嗪三重串联反应的选择性机制:反应路径切换与中间体转化
Selectivity Mechanism of the Triple Aryne–Tetrazine Cascade Reaction: Reaction-Pathway Switching and Intermediate Transformations
此产品的引用文献
引用文献
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13. Runhai Chen, Yu Xia, Zhifang Ma, Yue Ke, Qiang Shi, Fazly I. Ataullakhanov, Mikhail Panteleev.  (2023)  H2O2-Responsive Polymeric Micelles of Biodegradable Aliphatic Poly(carbonate)s as Promising Therapeutic Agents for Inflammatory Diseases.  MACROMOLECULAR BIOSCIENCE,  [PMID:37975742] [10.1002/mabi.202300409]
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19. Wenhao Li, Zexuan Sui, Chunli Fan, Ci Wang, Yao Zhu, Jing Ren, Jianzhong Zhang.  (2023)  Intense radioluminescence from transparent CsGd2F7: Ce3+ nano-glass scintillator.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,  [10.1016/j.jeurceramsoc.2023.05.045]
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24. Song Qing, Xi Zhang, Tao Yang, Lingxiang Chu, Yayun Zhou, Jing Wan, Zhengliang Wang, Huaijun Tang, Qiang Zhou.  (2022)  Luminescence properties of Cr3+-doped near-infrared emissive fluoroyttrates for light-emitting diodes.  DALTON TRANSACTIONS,  51  (37): (14214-14220).  [PMID:36062936] [10.1039/D2DT02096C]
25. Ru-Ling Tang, Xin Lian, Xiao-Hui Li, Lei Huai, Wenlong Liu, Sheng-Ping Guo.  (2022)  From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**.  CHEMISTRY-A EUROPEAN JOURNAL,  28  (53): (e202201588).  [PMID:35726960] [10.1002/chem.202201588]
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