计算溶液所需的质量、体积或浓度。
为什么选择此级别
提供 ≥98% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。
储存与运输
室温,充氩。常规运输 。请查阅批次 COA 获取详细规格。
质量文档
SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。
文献证明
在色谱分析、有机合成和交叉偶联反应领域已被 72 篇同行评审文献引用。
概述
和水反应，溶于甲醇、乙醇。微溶于二乙醚、苯。可配成四氢呋喃或叔丁醇溶液使用。
用于酯类的绿色酰胺化。
叔丁醇辅助酯在绿色条件下的酰胺化反应
叔丁醇钾可作为碘芳烃分子内环化反应的一种碱，通过微波合成法合成苯并吡喃。
Used for green amidation of esters.
Amidation of tert-butanol-assisted ester under green conditions
Potassium tert-butoxide can be used as a base for the intramolecular cyclization of iodoaromatic hydrocarbons to synthesize benzopyrans by microwave synthesis.
规格
别名
叔丁醇钾 | 次丁氧基钾 | 第三丁氧基钾
英文别名
P1619 | potassium 2-methylpropan-2-olate | Potassium tert-butylate | potassium-tert-butoxide | Potassiumtert-butoxide | 09 - Organophosphorus Pesticides | potassium t-butanolate | Potassium tert. butoxide | potassium-t-butoxid | potassium-t-butylate | Pot
规格或纯度
≥98%
英文名称
Potassium tert-butoxide
储存条件
室温,充氩
运输条件
常规运输
纯度
≥98%
名称和识别符
EC号
212-740-3
分子类型
小分子
IUPAC Name
potassium;2-methylpropan-2-olate
INCHI
1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChi Key
LPNYRYFBWFDTMA-UHFFFAOYSA-N
Smiles
CC(C)(C)[O-].[K+]
Isomeric SMILES
CC(C)(C)[O-].[K+]
UN Number
Packing Group
I
分子量
112.21
Beilstein号
3556712
Reaxy-Rn
3556712
技术文档
高级数据
系统学分类
分类树（Taxonomy Tree）
| 界（kingdom) | 有机化合物 |
|---|---|
| 超类（Superclass) | 有机盐 |
| 类（Class) | 有机金属盐 |
| 亚类（Subclass） | 有机碱金属盐 |
| 中间层级节点（Intermediate Tree Nodes） | 暂无 |
| 直接上位类(Direct Parent) | 有机碱金属盐 |
| 其他上位类（Alternative Parents） | 有机两性离子 有机钾盐 有机氧化物 碳氢化合物衍生物 醇盐 |
| 分子骨架（Molecular Framework) | 脂肪族无环化合物 |
| 取代基（Substituents） | 脂肪族非环化合物 - 烷氧基 - 烃衍生物 - 有机碱金属盐 - 有机氧化物 - 有机氧化合物 - 有机钾盐 - 有机双性离子 - 有机氧化合物 |
| 描述（Description） | 该化合物属于有机碱金属盐类。此类化合物为碱金属的有机盐，其中碱金属原子通常以离子形式存在。 |
| 外部描述符（External Descriptors） | 暂无 |
三维结构
交互式化学结构模型
化学和物理性质
溶解性
可溶于六烷、甲苯、二乙醚和太古喃。
密度
0.82
敏感性
对空气、湿度敏感
闪点(℉)
53.6 °F
闪点(℃)
12 °C
沸点
275°C
熔点
256-258°C
分子量
112.210 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count
0
氢键受体数Hydrogen Bond Acceptor Count
1
可旋转键计数Rotatable Bond Count
0
精确质量Exact Mass
112.029 Da
单同位素质量Monoisotopic Mass
112.029 Da
拓扑极表面积Topological Polar Surface Area
23.100 Ų
重原子数Heavy Atom Count
6
形式电荷Formal Charge
0
复杂度Complexity
29.000
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
2
安全和危险性（GHS）
信号词
危险
危险声明
H228: 易燃固体
H252: 大量自加热； 可能着火
H302: 吞食有害
H314: 造成严重的皮肤灼伤和眼睛损伤
H318: 造成严重的眼睛损伤
预防措施声明
P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。
P235: 保持凉爽
P240: 地面/粘结容器和接收设备
P241: 使用防爆的[电气/通风/照明/.../]设备。
P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。
P264: 处理后要彻底洗手。
P270: 使用本产品时，请勿进食、饮水或吸烟。
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P321: 特殊处理（请参阅此标签上的...）。
P330: 漱口
P363: 再次使用之前，请清洗受污染的衣物。
P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。
P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P405: 密闭存放
P407: 在堆垛或托盘之间保持气隙。
P410: 防止阳光直射
P413: 在不超过...°C / ...°F的温度下存储大于... kg / ... lbs的散装质量。
P420: 分开存放。
P501: 将内容物/容器处理到。。。
P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。
P301+P317: 如果被吞咽：请寻求医疗帮助。
P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。
P317: 寻求紧急医疗救助。
P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。
P316: 立即寻求紧急医疗救助。
WGK Germany
1
Class
8(4.2)
个人防护装备
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RIDADR
UN 3131 8(4.3) / PGI
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引用文献
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| 3. Shiying Wu, Huaqing Zhang, Zhu Mao, Yaohui Liang, Jian-An Li, Pengtao Hu, Qingqing Zhang, Cong Liu, Suilian Luo, Yuhai Wang, Guang Shi, Bingjia Xu. (2023) Achieving Stable and Switchable Ultralong Room-Temperature Phosphorescence from Polymer-Based Luminescent Materials with Three-Dimensional Covalent Networks for Light-Manipulated Anticounterfeiting. ACS Applied Materials & Interfaces, [PMID:37555378] [10.1021/acsami.3c07900] |
| 4. Yixuan Xu, Changchang Teng, Huiping Dang, Dalong Yin, Lifeng Yan. (2023) Highly bright stable organic radicals encapsulated by amphiphilic polypeptide for efficient near-infrared phototheranostics. TALANTA, [PMID:37459788] [10.1016/j.talanta.2023.124948] |
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