计算溶液所需的质量、体积或浓度。
| 活性类型 | Relation | Activity value | Units | Action Type | 期刊 | PubMed Id | doi | Assay Aladdin ID |
|---|
有货
为什么选择此级别
精馏级 提供 ≥99.5% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。
储存与运输
室温。DG运输 。请查阅批次 COA 获取详细规格。
质量文档
SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。
文献证明
在色谱分析、有机合成和交叉偶联反应领域已被 42 篇同行评审文献引用。
概述
具有吸湿性和特殊的胺味，能以任何比例与水互溶，易溶于芳烃、醇、酮类、醚类和有机溶剂中，微溶于矿物油和脂肪族烃中，有轻微毒性。能随水蒸气挥发。吗啉与无机酸反应生成盐，与有机酸反应生成盐或酰胺。可进行烷基化反应，还可以与环氧乙烷、酮反应或进行Willgerodt反应。
规格
别名
吗啉
英文别名
C4H9NO | Drewamine | NCGC00256942-01 | J-522715 | 4-27-00-00015 (Beilstein Handbook Reference) | Diethyleneimide oxide | Tetrahydro-1,4-isoxazine | UNII-8B2ZCK305O | Tetrahydro-1, 4-isoxazine | TETRAHYDRO-2H-1, 4-OXAZINE | Tetrahydro-4H-1-4-oxazine | AI3-
规格或纯度
精馏级, ≥99.5%
英文名称
Morpholine
应用
吗啉与无机酸反应生成盐，与有机酸反应生成盐或酰胺。可进行烷基化反应，还可以与环氧乙烷、酮反应或进行Willgerodt反应。
储存条件
室温
运输条件
DG运输
纯度
≥99.5%
名称和识别符
PubChem SID
EC号
203-815-1
分子类型
小分子
IUPAC Name
morpholine
INCHI
1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2
InChi Key
YNAVUWVOSKDBBP-UHFFFAOYSA-N
Smiles
C1COCCN1
Isomeric SMILES
C1COCCN1
UN Number
Packing Group
I
分子量
87.12
Beilstein号
102549
Reaxy-Rn
102549
Reaxys-RN link address
https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=102549&ln=
技术文档
高级数据
系统学分类
分类树（Taxonomy Tree）
| 界（kingdom) | 有机化合物 |
|---|---|
| 超类（Superclass) | 有机杂环化合物 |
| 类（Class) | 噁嗪烷 |
| 亚类（Subclass） | 吗啉 |
| 中间层级节点（Intermediate Tree Nodes） | 暂无 |
| 直接上位类(Direct Parent) | 吗啉 |
| 其他上位类（Alternative Parents） | 氧环化合物 二烷基胺 二烷基醚 氮杂环化合物 有机光子化合物 碳氢化合物衍生物 |
| 分子骨架（Molecular Framework) | 脂肪族杂单环化合物 |
| 取代基（Substituents） | 脂肪族杂单环化合物 - 氨基酸 - 氮杂环 - 二烷基醚 - 乙醚 - 烃衍生物 - Morpholine - 有机硝基化合物 - 有机氧化合物 - 有机氮化合物 - 有机氧化合物 - 有机氮化合物 - 氧杂环 - 二级脂肪胺 - 醛基 |
| 描述（Description） | 该化合物属于有机化合物中的吗啉类。这类化合物含有吗啉结构单元，即由C4H9NO分子式构成的六元饱和脂肪环，其中氧原子与氮原子分别位于1位和4位。 |
| 外部描述符（External Descriptors） | morpholines - saturated organic heteromonocyclic parent |
三维结构
交互式化学结构模型
关联靶点（人）
CYP1B1
Tchem
Cytochrome P450 1B1
(1148 活性数据)
CYP1A1
Tchem
Cytochrome P450 1A1
(1169 活性数据)
作用机制
| 作用机制 | Action Type | target ID | Target Name | Target Type | Target Organism | Binding Site Name | 参考文献 |
|---|
化学和物理性质
溶解性
与水混溶，可混溶于多数有机溶剂。
密度
0.996
敏感性
易吸潮
折光率
1.4548
闪点(℉)
87.8 °F
闪点(℃)
35℃
沸点
128.3°C
熔点
-4.76°C
分子量
87.120 g/mol
XLogP3
-0.900
氢键供体数Hydrogen Bond Donor Count
1
氢键受体数Hydrogen Bond Acceptor Count
2
可旋转键计数Rotatable Bond Count
0
精确质量Exact Mass
87.0684 Da
单同位素质量Monoisotopic Mass
87.0684 Da
拓扑极表面积Topological Polar Surface Area
21.300 Ų
重原子数Heavy Atom Count
6
形式电荷Formal Charge
0
复杂度Complexity
34.500
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
1
安全和危险性（GHS）
一般危化品
一般危化品
信号词
危险
危险声明
H226: 易燃液体和蒸气
H311: 皮肤接触有毒
H314: 造成严重的皮肤灼伤和眼睛损伤
H401: 对水生生物有毒
H302+H332: 吞咽或吸入有害。
预防措施声明
P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。
P233: 保持容器密闭。
P240: 地面/粘结容器和接收设备
P241: 使用防爆的[电气/通风/照明/.../]设备。
P242: 仅使用无火花的工具。
P243: 采取防静电措施
P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾
P264: 处理后要彻底洗手。
P270: 使用本产品时，请勿进食、饮水或吸烟。
P271: 仅在室外或通风良好的地方使用。
P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P321: 特殊处理（请参阅此标签上的...）。
P330: 漱口
P363: 再次使用之前，请清洗受污染的衣物。
P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。
P302+P352: 如皮肤沾染：用水充分清洗。
P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。
P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。
P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P405: 密闭存放
P403+P235: 存放在通风良好的地方。保持低温。
P501: 将内容物/容器处理到。。。
P301+P317: 如果被吞咽：请寻求医疗帮助。
P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。
P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。
WGK Germany
1
RTECS
QD6475000
Class
8(3)
Merck Index
6277
个人防护装备
Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
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分析证书 | M109058 |
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分析证书 | M109058 |
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此产品的引用文献
引用文献
| 1. Jun-Tao Shi, Xian-Hui Chen, Yuan-Yuan Peng, Gui-Ping Wang, Guang-Yan Du, Quan Li. (2023) Tunable Fluorescence and Morphology of Aggregates Built from a Mechanically Bonded Amphiphilic Bistable [2]Rotaxane. CHEMISTRY-A EUROPEAN JOURNAL, 29 (59): (e202302132). [PMID:37526053] [10.1002/chem.202302132] |
| 2. Ke Wang, Liru An, Ganghui Lu, Jialu Zhang, Zilong Wang, Meiyu Si, Guiyan Liu, Yongfei Zeng. (2023) Effect of heterocyclic substituents on the thermo/pH/CO2-responsiveness of multistimuli-responsive homopolymers. POLYMER, [10.1016/j.polymer.2023.126039] |
| 3. Qiong Yao, Shouwu Yu. (2023) Preparation and characterisation of a triazine structure charring agent and its application in polypropylene. MATERIALS RESEARCH INNOVATIONS, [10.1080/14328917.2023.2212482] |
| 4. Siyuan Li, Xianrong Yu, Linlin Zeng, Yuhan Xu, Xiaolan Zhao, Wei Tang, Xinrui Duan. (2022) A Sensitive Fluorescent Probe with Large Stokes Shift for Real-Time Tracking Lysosomal pH Changes in Live Cells. ChemistrySelect, 7 (42): (e202202620). [10.1002/slct.202202620] |
| 5. Caiyun Lin, Yuying Li, Weishan Tang, Shufeng Zhou, Xiaoping Rao. (2021) Facile Construction of Bio-Based Supramolecular Hydrogels from Dehydroabietic Acid with a Tricyclic Hydrophenanthrene Skeleton and Stabilized Gel Emulsions. MOLECULES, 26 (21): (6526). [PMID:34770933] [10.3390/molecules26216526] |
| 6. Yingnan Liu, Yaqing Xiao, Minghui Shang, Yuting Zhuang, Li Wang. (2021) Smart fluorescent tag based on amine response for non-contact and visual monitoring of seafood freshness. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2021.132647] |
| 7. Jun Mou, Xingqi Fan, Fei Liu, Xiaodan Wang, Tianxiang Zhao, Peng Chen, Ziwei Li, Chunliang Yang, Jianxin Cao. (2021) CO2 hydrogenation to lower olefins over Mn2O3-ZnO/SAPO-34 tandem catalysts. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2021.129978] |
| 8. Faming Wang, Pengfei Ren, Katrien V. Bernaerts, Yifu Fu, Wanjun Hu, Naizhen Zhou, Tianzhu Zhang. (2020) Thermoresponsive Poly(2-propyl-2-oxazoline) Surfaces of Glass for Nonenzymatic Cell Harvesting. ACS Applied Bio Materials, [PMID:35021716] [10.1021/acsabm.0c00650] |
| 9. Shao-Lu Li, Pengfei Wu, Juntao Wang, Jing Wang, Yunxia Hu. (2019) Fabrication of high performance polyamide reverse osmosis membrane from monomer 4-morpholino-m-phenylenediamine and tailoring with zwitterions. DESALINATION, [10.1016/j.desal.2019.114169] |
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| 11. Song Wen-tao, Hu Yong-jun, Jin Shan, Li Yu-jian. (2019) Dissociative photoionization of heterocyclic molecule-morpholine under VUV synchrotron radiation. CHINESE JOURNAL OF CHEMICAL PHYSICS, 32 (2): (259-266). [10.1063/1674-0068/cjcp1904068] |
| 12. Yanhong Li, Jing Li, Meiri Wang, Yuanyuan Liu, Hongtao Cui. (2019) High rate performance and stabilized cycle life of Co2+-doped nickel sulfide nanosheets synthesized by a scalable method of solid-state reaction. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2019.02.066] |
| 13. Xinxin Li, Qingshan Zhao, Xiang Feng, Lei Pan, Zhuangzhuang Wu, Xiaocui Wu, Tianwen Ma, Jialiang Liu, Yuanyuan Pan, Yan Song, Mingbo Wu. (2019) Pyridinic Nitrogen-Doped Graphene Nanoshells Boost the Catalytic Efficiency of Palladium Nanoparticles for the N-Allylation Reaction. ChemSusChem, 12 (4): (858-865). [PMID:30600929] [10.1002/cssc.201802532] |
| 14. Wang Li, Li Jing, Wang Meiri, Liu Yuanyuan, Cui Hongtao. (2018) In situ synthesis of two-dimensional Co2+-doped β-Ni(OH)2 using nickel complex as template for application in supercapacitors. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 89 (2): (492-499). [10.1007/s10971-018-4880-y] |
| 15. Wu Hong, Wang Xianshu, Liu Fei, Cao Jianxin. (2018) Facile in situ hydrothermal crystallization synthesis of SAPO-34/ZSM-5 composite catalyst for methanol to olefin reaction. JOURNAL OF POROUS MATERIALS, 26 (3): (793-802). [10.1007/s10934-018-0676-2] |
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| 17. Huaqi Zhan, Yongjun Hu, Pengchao Wang, Jiaxin Chen. (2017) Molecular structures of gas-phase neutral morpholine and its monohydrated complexes: experimental and theoretical approaches. RSC Advances, 7 (11): (6179-6186). [10.1039/C6RA26582K] |
| 18. Ma Wenle, Feng Yongmei, Wang Li, Xue Junying, Cui Hongtao. (2016) Tailoring the size and electrochemical performance of Mn3O4 nanoparticles by controlling the precipitation process. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 80 (2): (326-332). [10.1007/s10971-016-4107-z] |
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| 20. Wenle Ma, Li Wang, Junying Xue, Hongtao Cui. (2015) Ultra-large scale synthesis of Co–Ni layered double hydroxides monolayer nanosheets by a solvent-free bottom-up strategy. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2015.12.065] |
| 21. Zhong Zheng, Yihu Song, Huilong Xu, Qiang Zheng. (2015) Thickening of the Immobilized Polymer Layer Using Trace Amount of Amine and Its Role in Promoting Gelation of Colloidal Nanocomposites. MACROMOLECULES, [10.1021/acs.macromol.5b02004] |
| 22. Ma Wenle, Xue Junying, Cui Hongtao. (2015) New insight on nanostructure assembling of high-performance electrode materials: synthesis of surface-modified hexagonal β-Ni(OH)2 nanosheets as an example. IONICS, 22 (4): (573-579). [10.1007/s11581-015-1570-4] |
| 23. Hongtao Cui, Junying Xue, Wanzhong Ren, Minmin Wang. (2015) Ultra-large scale synthesis of high electrochemical performance SnO2 quantum dots within 5 min at room temperature following a growth self-termination mechanism. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2015.05.015] |
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| 26. Ming-Hui He, Mei-Lin Su, Zhao-Hui Yu, Guang-Xue Chen, Zhao-Hua Zeng, Jian-Wen Yang. (2014) Benzoylformamides as new photocaged bases for photo-latent anion polymerization. CHINESE CHEMICAL LETTERS, [10.1016/j.cclet.2014.10.002] |
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| 28. Yan Liu, Zhenhu Cao, Yan Zhang, Zhengping Fang. (2013) Synthesis of Cerium N-Morpholinomethylphosphonic Acid and Its Flame Retardant Application in High Density Polyethylene. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, [10.1021/ie400259f] |
| 29. Min Xie, Guichi Zhu, Yongjun Hu, Huaimin Gu. (2011) Conformations of Morpholine in Liquid and Adsorbed on Gold Nanoparticles Explored by Raman Spectroscopy and Theoretical Calculations. Journal of Physical Chemistry C, [10.1021/jp206544a] |
| 30. Weidong Nie, Yuanyuan Liu, Jing Li, Meiri Wang, Kaihua Liu, Hongtao Cui. (2024) A new carbon modification strategy aimed to fully address the issues of NiO as an electrode material for supercapacitors. JOURNAL OF ALLOYS AND COMPOUNDS, [10.1016/j.jallcom.2024.174027] |
| 31. Yiwei Sun, Xiaoli Wei, Wei Zhang, Zhen Wang, Jianhai Jiang, Fangcao Liu, Bing Liu, Wenfeng Han. (2024) Carbon-Interacted AlF3 Clusters as Robust Catalyst for Dehydrofluorination Reaction with Enhanced Undercoordination and Stability. ACS Catalysis, [10.1021/acscatal.3c05921] |
| 32. Zhonggeng Wang, Luzhu Fang, Sensen Ma, Xuejing Zheng, Jianfeng Wang, Yanyu Yang, Wanjie Wang, Yanxia Cao. (2025) Dispersibility study of eight types of nanofibrillated cellulose and their Hansen solubility parameters. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, [PMID:40139590] [10.1016/j.ijbiomac.2025.142498] |
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